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Chemical Structure| 89981-01-1 Chemical Structure| 89981-01-1

Structure of 89981-01-1

Chemical Structure| 89981-01-1

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Product Details of [ 89981-01-1 ]

CAS No. :89981-01-1
Formula : C8H9BrS
M.W : 217.13
SMILES Code : CSC1=CC=CC=C1CBr

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Application In Synthesis of [ 89981-01-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 89981-01-1 ]

[ 89981-01-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 89981-01-1 ]
  • [ 82657-74-7 ]
YieldReaction ConditionsOperation in experiment
With oxone; In methanol; water; Step A 2-(Methylsulfonyl)benzylbromide To a solution of 124 mg (0.57 mmol) of 2-(methylthio)-benzylbromide in 8.0 mL of methanol was added a solution of 702 mg of oxone in 7.0 mL of water. The solution was stirred for 4.5 h, concentrated in vacuo and purified by silica gel flash chromatography, eluding with 10% ethyl acetate/hexane to give 105 mg of the title compound. mass spec 249(M+). NMR (CDCl3): delta 3.25 (s, 3H), 5.07 (s, 2H), 7.50 (m, 1H), 7.60 (m, 2H), 8.05 (d, 1H).
 

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