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Chemical Structure| 90003-09-1 Chemical Structure| 90003-09-1

Structure of 90003-09-1

Chemical Structure| 90003-09-1

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Product Details of [ 90003-09-1 ]

CAS No. :90003-09-1
Formula : C8H11ClO
M.W : 158.63
SMILES Code : CC1CCC(Cl)=C(C=O)C1
MDL No. :MFCD11207307

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Application In Synthesis of [ 90003-09-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 90003-09-1 ]

[ 90003-09-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 90003-09-1 ]
  • [ 60549-26-0 ]
YieldReaction ConditionsOperation in experiment
89% With oxygen; potassium carbonate; In N,N-dimethyl-formamide; at 80℃; for 20h; Cyclohexene la (0.2 g, 1.26 mmol), and K2C03 (0.34 g, 2.53 mmol) in DMF (7 mL) was placed in a two necked RB flask with continuous bubbling of air at 80 °C for 20 h. Purification by flash column chromatography (silica gel, 7:3 pet. ether/ethyl acetate) afforded the brown solid compound 2a (mp .= 78-80 °C, 0.15 g, 89percent yield). Rf 0.5 (30percent Ethyl acetate/pet. ether). 1H NMR (200 MHz, CDC13): delta 2.39 (s, 3H), 6.22 (brs, 1H), 6.91 - 7.00 (m, 1H), 7.15 - 7.20 (m, 1H), 7.21 - 7.25 (m, 1H), 9.89 (s, 1H); 13C NMR (50 MHz, CDC13+CC14+DMS0): delta 20.7, 1 12.3, 121.6, 122.2, 137.2, 139.5, 157.6, 191.8; GC- MS (EI): m/z =136 (M)+
 

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