Alternatived Products of [ 905718-45-8 ]
Product Details of [ 905718-45-8 ]
CAS No. : | 905718-45-8 |
MDL No. : | MFCD21608480 |
Formula : |
C13H9F3INO5S
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
475.18
|
Pubchem ID : | - |
Synonyms : |
|
Safety of [ 905718-45-8 ]
Application In Synthesis of [ 905718-45-8 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 905718-45-8 ]
- Downstream synthetic route of [ 905718-45-8 ]
- 1
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[ 905718-45-8 ]
-
[ 100-51-6 ]
-
[ 1145-76-2 ]
Yield | Reaction Conditions | Operation in experiment |
96% |
Stage #1: benzyl alcohol With sodium t-butanolate In toluene at 0 - 20℃; for 0.25h; Inert atmosphere;
Stage #2: [(4-nitrophenyl)(phenyl)iodonium trifluoromethanesulfonate] In toluene at 0 - 20℃; Inert atmosphere; chemoselective reaction; |
|
92% |
With sodium hydroxide In water at 20 - 50℃; for 3h; |
|
Reference:
[1]Ghosh, Raju; Lindstedt, Erik; Jalalian, Nazli; Olofsson, Berit
[ChemistryOpen, 2014, vol. 3, # 2, p. 54 - 57]
[2]Lindstedt, Erik; Ghosh, Raju; Olofsson, Berit
[Organic Letters, 2013, vol. 15, # 23, p. 6070 - 6073]
- 2
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[ 905718-45-8 ]
-
[ 108-95-2 ]
-
[ 620-88-2 ]
Yield | Reaction Conditions | Operation in experiment |
89% |
With sodium hydroxide In water at 20 - 50℃; for 3h; |
|
- 3
-
[ 905718-45-8 ]
-
[ 75-65-0 ]
-
[ 2109-72-0 ]
Yield | Reaction Conditions | Operation in experiment |
70% |
Stage #1: <i>tert</i>-butyl alcohol With sodium t-butanolate In toluene at 0 - 20℃; for 0.25h; Inert atmosphere;
Stage #2: [(4-nitrophenyl)(phenyl)iodonium trifluoromethanesulfonate] In toluene at 0 - 20℃; Inert atmosphere; chemoselective reaction; |
|
- 4
-
[ 905718-45-8 ]
-
[ 10576-12-2 ]
-
[ 83077-00-3 ]
- 5
-
[ 905718-45-8 ]
-
[ 865-48-5 ]
-
[ 2109-72-0 ]
Yield | Reaction Conditions | Operation in experiment |
80% |
In toluene at 20℃; for 24h; Inert atmosphere; |
|
- 6
-
[ 905718-45-8 ]
-
[ 14131-84-1 ]
-
[ 62398-07-6 ]
Yield | Reaction Conditions | Operation in experiment |
95% |
With potassium <i>tert</i>-butylate In toluene at 20℃; |
|
Reference:
[1]Tolnai, Gergely L.; Nilsson, Ulf J.; Olofsson, Berit
[Angewandte Chemie - International Edition, 2016, vol. 55, # 37, p. 11226 - 11230][Angew. Chem., 2016, vol. 128, # 37, p. 11392 - 11396]
- 7
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[ 905718-45-8 ]
-
[ 51166-71-3 ]
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heptakis(2,6-di-O-mehtyl-4-nitrophenyl)-β-cyclodextrin
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
57% |
Stage #1: [(4-nitrophenyl)(phenyl)iodonium trifluoromethanesulfonate]; heptakis(2,6-di-O-methyl)cyclomaltoheptaose With potassium <i>tert</i>-butylate In toluene for 2h;
Stage #2: [(4-nitrophenyl)(phenyl)iodonium trifluoromethanesulfonate] With potassium <i>tert</i>-butylate In toluene for 2h; |
|
Reference:
[1]Tolnai, Gergely L.; Nilsson, Ulf J.; Olofsson, Berit
[Angewandte Chemie - International Edition, 2016, vol. 55, # 37, p. 11226 - 11230][Angew. Chem., 2016, vol. 128, # 37, p. 11392 - 11396]
- 8
-
[ 905718-45-8 ]
-
[ 952-97-6 ]
Yield | Reaction Conditions | Operation in experiment |
41% |
With iron(III) chloride; sodiumsulfide nonahydrate In dimethyl sulfoxide at 100℃; for 12h; |
|
- 9
-
[ 905718-45-8 ]
-
[ 62-53-3 ]
-
[ 836-30-6 ]
Yield | Reaction Conditions | Operation in experiment |
91% |
Stage #1: [(4-nitrophenyl)(phenyl)iodonium trifluoromethanesulfonate] With sodium carbonate Inert atmosphere; Sealed tube;
Stage #2: aniline In toluene at 110℃; for 4h; Inert atmosphere; Sealed tube; regiospecific reaction; |
|
Reference:
[1]Purkait, Nibadita; Kervefors, Gabriella; Linde, Erika; Olofsson, Berit
[Angewandte Chemie - International Edition, 2018, vol. 57, # 35, p. 11427 - 11431][Angew. Chem., 2018, vol. 130, # 35, p. 11597 - 11601,5]
- 10
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[ 110-89-4 ]
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[ 905718-45-8 ]
-
[ 6574-15-8 ]
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