[ CAS No. 915088-14-1 ] {[proInfo.proName]}

Name: 915088-14-1|N,N-Diphenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline|98%
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SKU: A1004779
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Quality Control of [ 915088-14-1 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 915088-14-1 ]

Product Details of [ 915088-14-1 ]

CAS No. :	915088-14-1	MDL No. :
Formula :	C₂₄H₂₆BNO₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	QCXZGMTXGKIZBZ-UHFFFAOYSA-N
M.W :	371.28	Pubchem ID :	59207617
Synonyms :

Safety of [ 915088-14-1 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 915088-14-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 915088-14-1 ]

[ 915088-14-1 ] Synthesis Path-Downstream 1~27

1
[ 58530-53-3 ]
[ 915088-14-1 ]
[ 1361051-58-2 ]

Reference： [1]Chemical Communications,2012,vol. 48,p. 2695 - 2697

2
[ 915088-14-1 ]
[ 1361051-56-0 ]

Reference： [1]Chemical Communications,2012,vol. 48,p. 2695 - 2697

3
[ 915088-14-1 ]
[ 1361051-57-1 ]

Reference： [1]Chemical Communications,2012,vol. 48,p. 2695 - 2697

4
[ 16292-17-4 ]
[ 915088-14-1 ]
[ 1361051-55-9 ]

Reference： [1]Chemical Communications,2012,vol. 48,p. 2695 - 2697

5
[ 61676-62-8 ]
[ 78600-33-6 ]
[ 915088-14-1 ]

Yield	Reaction Conditions	Operation in experiment
58%		issolve <strong>[78600-33-6]3-bromo-N,N-diphenylaniline</strong> (1.62g, 5mmol)40 mL of freshly steamed tetrahydrofuran was placed in a low temperature reactor at -78 C for 10 min.After degassing three times with freezing, 3 mL of n-butyllithium (2.40 M, 7 mmol) was slowly added dropwise.After activation for 4 h, slowly add about 2 mL of isopropanol pinacol borate (7 mmol).Stir at room temperature for 48 h.The mixture was extracted with dichloromethane and concentrated to give a crude product.Purification by column chromatography (petroleum ether: methylene chloride = 1: 2) gave white solid (0.84 g,yield: 58%).

Reference： [1]Chemical Communications,2012,vol. 48,p. 2695 - 2697
[2]Patent: CN109608403,2019,A .Location in patent: Paragraph 0052-0054
[3]Journal of Materials Chemistry C,2019,vol. 7,p. 14709 - 14716

6
[ 915088-14-1 ]
[ 1443793-90-5 ]
[ 1542164-20-4 ]

Reference： [1]Chemistry of Materials,2014,vol. 26,p. 1413 - 1419

7
[ 78600-33-6 ]
[ 73183-34-3 ]
[ 915088-14-1 ]

Yield	Reaction Conditions	Operation in experiment
38%	With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In dimethyl sulfoxide; at 80℃; for 10h;Inert atmosphere;	A mixture of 10 g of 3-bromo-N, N-diphenylaniline,11.7 g of bispinacolato diboron,9.1 g of KOAc and 0.76 g of [1,1'-bis (biphenylphosphino) ferrocene] dichloropalladium (II) [Pd (dppf) Cl2]And 100 ml (ml) of DMSO were placed in a round bottom three-necked flask under a nitrogen atmosphere,And stirred at 80 C for 10 hours.The reaction solution was cooled and extracted with dichloromethane and water,And concentrating the extracted solution. The concentrated solution was subjected to column chromatography using a mixed solvent of dichloromethane and n-hexane and concentrated to give 3.9 g of N, N-diphenyl-3- (4,4,5,5-tetramethyl- 1,3,2-dioxaborane-2-yl) aniline (yield 38%).
38%	With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate; In dimethyl sulfoxide; at 80℃; for 10h;Inert atmosphere;	10 g of <strong>[78600-33-6]3-bromo-N,N-diphenylaniline</strong>, 11.7 g of bis(pinacolato)diboron, 9.1 g of potassium acetate,0.76 g of [1,1-bis(biphenylphosphino)ferrocene]dichloromethane (II),100 ml of DMSO was placed in a round bottom three-necked flask under a nitrogen atmosphere and stirred at 80C for 10 hours.The reaction solution was cooled and extracted with dichloromethane and water.The extracted solution was concentrated, and then the concentrated solution was subjected to column chromatography using a mixed solvent of dichloromethane and n-hexane and concentrated to thereby obtain 3.9 g of N,N-diphenyl-3-(4,4,5). , 5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline (yield: 38%).

Reference： [1]Chemistry of Materials,2014,vol. 26,p. 1413 - 1419
[2]Patent: TWI579270,2017,B .Location in patent: Paragraph 0088; 0089; 0090
[3]Patent: TWI602799,2017,B .Location in patent: Paragraph 0122-0123

Yield	Reaction Conditions	Operation in experiment
87%	With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In N,N-dimethyl-formamide; at 90℃;	General procedure: Said M 1-I-1 obtained in the synthesis (112.78g, 347.9mmol) senses a rotation velocity of the disk to a DMF to in round bottom flask , Bis (pinacolato) diboron (97.17g, 382.6mmol), Pd (dppf) Cl 2 (8.52g, 10.4mmol), KOAc (102.42g, 1043.6mmol) added 90 C stirring section. When reaction is completed by etching are removed and then the DMF via fractional distillation CH 2 Cl 2 extracted and water. Organic layer MgSO 4 to dry a silicagel column with a compound formed after the products and recrystallization 114.95g (yield: 89%)is obtained.
86%	With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In N,N-dimethyl-formamide; at 90℃;	General procedure: Wherein M 2-I-1 (63.01 g, 194.3 mmol) to a round bottom flask was charged with DMF (970 ml) to dissolve later, Bis (pinacolato) diboron (54.29 g, 213.8 mmol), PdCl2 (dppf) (4.76 g, 5.8 mmol), was added KOAc (57.22 g, 583 mmol) and the resulting mixture was stirred at 90 C. After completion of reaction by distillation to remove DMF and CH2Cl2. And extracted with water. The organic layer was dried over MgSO4 and concentrated and the resulting product was compound silicagel column and recrystallization 62.78 g (yield:87% was obtained).

9
[ 915088-14-1 ]
C₂₄H₁₅BrClN [ No CAS ]
C₄₂H₂₉BrN₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
74%	With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide; In tetrahydrofuran; water; at 80℃;	General procedure: Said Sub 1-V-1 obtained in the synthesis (46.13g, 106.6mmol) senses a rotation velocity of the disk to a in round bottom flask THF to, M 1-1 (47.49g, 127.9mmol), Pd (PPh 3) 4 (3.7g, 3.2mmol), NaOH (12.79g, 319.8mmol), water are added 80 C stirring section. When reaction is completed CH 2 Cl 2 and a water extraction of organic layer after MgSO 4 to dry a silicagel column with a compound formed after the products and recrystallization 50.92g (yield: 80%)is obtained.Said Sub 1-V-1 obtained in the synthesis (27.86g, 64.4mmol) to M 1-12 (28.68g, 77.3mmol), Pd (PPh 3) 4 (2.23g, 1.9mmol), NaOH (7.73g, 193.1mmol), THF, 30.57g the products reusing synthetic said Sub 1-VI-1 water (yield: 74%)is obtained.

Reference： [1]Patent: KR2015/98062,2015,A .Location in patent: Paragraph 0135-0139; 0155; 0156; 0161-0164; 0169; 0170

10
[ 915088-14-1 ]
[ 57103-20-5 ]
C₃₆H₂₅BrN₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
58%	With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In water; toluene;Inert atmosphere; Reflux;	A mixture of 10 g of <strong>[57103-20-5]3,6-dibromo-9-phenyl-9H-carbazole</strong>,4.6 g of the intermediate 1 obtained in Preparation Example 1,0.3 g of Pd (PPh3) 4 and5.1 g of K2CO3 was placed in a round bottom three-necked flask under a nitrogen atmosphere,And 100 ml of toluene was added.The mixture was stirred and refluxed.After completion of the reaction, the resulting solution was washed with dichloromethane and water. Collecting organic layer,Dried over MgSO4 and separated by column,Thus, 4.1 g of intermediate 13 was obtained (yield 58percent).

Reference： [1]Patent: TWI579270,2017,B .Location in patent: Paragraph 0135; 0136; 0137

11
[ 915088-14-1 ]
[ 57103-20-5 ]
C₅₄H₃₉N₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
49%	With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In water; toluene;Inert atmosphere; Reflux;	2 g of <strong>[57103-20-5]3,6-dibromo-9-phenyl-9H-carbazole</strong>,3.9 g of the intermediate 1 synthesized in Preparation Example 1,0.3 g of Pd (PPh3) 4 and 4.1 g of K2CO3 were placed in a round bottom three-necked flask under a nitrogen atmosphere,And 50 ml of toluene was added.The mixture was stirred and refluxed.After completion of the reaction,The reaction solution was washed with dichloromethane and water.The moisture of the collected organic layer was then removed using MgSO4.The reaction mixture was separated by column and recrystallized,Thus, 1.8 g of compound 1 (yield 49percent) was obtained.

Reference： [1]Patent: TWI579270,2017,B .Location in patent: Paragraph 0147; 0148; 0149; 0150

12
[ 915088-14-1 ]
C₆₆H₄₈N₄ [ No CAS ]

Reference： [1]Patent: TWI579270,2017,B

13
[ 915088-14-1 ]
[ 16372-96-6 ]
C₄₈H₃₆N₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
90%	With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In methanol; toluene; at 65℃; for 4h;Inert atmosphere;	1.5 g Intermediate 1 prepared in Preparation Example 13.6 g Intermediate 5 prepared in Preparation Example 50.7 g of tetrakis(triphenylphosphine)palladium(0), 2.5 g of potassium carbonate, 50 ml of toluene, and 20 ml of methanol were placed in a 250 ml round bottom three-necked flask under a nitrogen atmosphere.And stirred at 65 C for 4 hours.The reaction solution was cooled, extracted with dichloromethane and water, then column chromatography using a mixed solvent of dichloromethane and n-hexane, and concentration and recrystallization were performed, thus obtaining 2.7 g of Compound 1 (yield 90%).

Reference： [1]Patent: TWI602799,2017,B .Location in patent: Paragraph 0162-0163

14
[ 915088-14-1 ]
C₄₀H₂₇Br [ No CAS ]
C₅₈H₄₁N [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
69%	With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In water; toluene; at 90℃; for 24h;Inert atmosphere;	n a 100 mL round bottom flask, M6 (0.8 g, 5 mmol), M3 (2.93 g, 5 mmol), tetrakis(triphenylphosphine)palladium (120 mg, 0.105 mmol), potassium carbonate (5.52 g, 40 mmol) dissolved in 40 mL of toluene and A 20 mL aqueous solution was refluxed at 90 C for 24 hours under a nitrogen atmosphere. The mixture was extracted with dichloromethane, concentrated to give a crude product, which was purified by column chromatography ( petroleum ether: dichloromethane= 2: 1) gave a yellow solid (2.59 g, yield: 69%).

Reference： [1]Patent: CN109608403,2019,A .Location in patent: Paragraph 0052; 0055; 0056

15
[ 915088-14-1 ]
6-bromo-2-iodothiophene[2,3-b]pyrazine [ No CAS ]
3-(6-bromothiophen[2,3-b]pyrazin-2-yl)-N,N-diphenylaniline [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In ethanol; water; toluene; at 85℃; for 12h;Inert atmosphere;	2) In a 500ml three-neck bottle,Add 6-bromo-2-iodothiophene [2,3-b]pyrazine (34.10 g, 100 mmol),3-diphenylaminophenyl boronate (37.13 g, 100 mmol),Potassium carbonate (27.64 g, 200 mmol), 150 g of toluene, 75 g of ethanol,75g water, tetrakis(triphenylphosphine)palladium was added under the protection of N2, and reacted at 85 C for 12 h.The TLC monitoring reaction was completed. After cooling to room temperature, the reaction solution was washed twice with water (200 ml).The organic phase is obtained by liquid separation, decolorized by adding activated carbon, filtered, and the solvent is distilled off under reduced pressure.Recrystallized twice with ethyl acetate,Drying under vacuum gave the intermediate 3-(6-bromothiophen[2,3-b]pyrazin-2-yl)-N,N-diphenylaniline.

Reference： [1]Patent: CN109810120,2019,A .Location in patent: Paragraph 0188; 0191

16
[ 915088-14-1 ]
6-bromo-2-iodothiophene[2,3-b]pyrazine [ No CAS ]
C₆₆H₄₁N₅OS [ No CAS ]

Reference： [1]Patent: CN109810120,2019,A

17
[ 915088-14-1 ]
9-phenyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole [ No CAS ]
4,5-dibromo-9H-carbazole [ No CAS ]
N,N-diphenyl-3-(9'-phenyl-9H,9'H-[4,4'-biscarbazole]-5-yl)aniline [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		1) In a 500ml three-neck bottle,Add 4,5-dibromo-9H-carbazole (32.50 g, 100 mmol),3-diphenylaminobenzene borate (37.13 g, 100 mmol),Potassium carbonate (27.64 g, 200 mmol), 150 g of toluene, 75 g of ethanol, 75 g of water, tetrakis(triphenylphosphine)palladium was added under N2 protection, and reacted at 85 C for 12 h.The TLC monitors the completion of the reaction and begins to cool down. After falling to room temperature,9-Phenyl-9H-carbazole-4-borate (36.93 g, 100 mmol) was added to a three-necked flask and reacted at 85 C for 12 h.The reaction was completed by TLC. After cooling to room temperature,The reaction solution was washed twice with water (200 ml), and the mixture was separated to give an organic phase.Recrystallized twice with ethyl acetate,Drying under vacuum gave the intermediate N,N-diphenyl-3-(9'-phenyl-9H,9'H-[4,4'-biscarbazole]-5-yl)aniline.

Reference： [1]Patent: CN109810120,2019,A .Location in patent: Paragraph 0168-0170

18
[ 915088-14-1 ]
[ 1416893-93-0 ]
3-(6-(10-(3-(diphenylamino)phenyl)anthracen-9-yl)pyren-1-yl)-N,N-diphenylaniline [ No CAS ]

Reference： [1]Journal of Materials Chemistry C,2019,vol. 7,p. 14709 - 14716

19
[ 591-18-4 ]
[ 915088-14-1 ]

Reference： [1]Patent: JP2021/95342,2021,A

20
[ 122-39-4 ]
[ 915088-14-1 ]

Reference： [1]Patent: JP2021/95342,2021,A

21
[ 608-30-0 ]
[ 915088-14-1 ]
N3,N3,N3'',N3"-tetraphenyl-[1,1': 3',1"-terphenyl]-2,3,3''-triamine [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
17.5 g	With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tetrabutylammomium bromide; palladium diacetate; potassium carbonate; In water; toluene; for 2h;Inert atmosphere; Reflux;	2,6-Dibromoaniline (8.5 g), N, N-diphenyl-3- (4,4,5,5) -Tetramethyl-1,3,2-dioxaborolan-2-yl) aniline (27.7 g), Potassium carbonate (18.7 g), Tetrabutylammonium bromide (3.3 g), Palladium acetate (II) (0.15 g), Dicyclohexyl (2', 6'-dimethoxy- [1, 1'-biphenyl] -2-yl) phosphine (0.56 g), toluene (85 ml), A flask containing Solmix A-11 (manufactured by Japan Alcohol Trading Co., Ltd., solmix, 40 ml) and water (20 ml) was placed in a nitrogen atmosphere. The mixture was heated under reflux for 2 hours. After the reaction is complete The mixture was cooled to room temperature, the solvent of the organic layer was distilled off under reduced pressure, and the obtained solid was dissolved in toluene. It was passed through a Kagelpas column (eluent: toluene, heptane). Fraction containing the object After distilling off the solvent under reduced pressure, it was recrystallized from toluene and heptane to form a white solid. do it N3, N3, N3 ", N3" -tetraphenyl- [1,1': 3', 1 "-terphenyl] -2'3,3" -triamine (17.5 g) was obtained.

Reference： [1]Patent: JP2021/95342,2021,A .Location in patent: Paragraph 0480; 0483

22
[ 1722-12-9 ]
[ 915088-14-1 ]
[ 2640665-53-6 ]

Yield	Reaction Conditions	Operation in experiment
65 %	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In water; toluene at 100℃; Inert atmosphere; Schlenk technique;

Reference： [1]Hruzd, Mariia; Kahlal, Samia; le Poul, Nicolas; Wojcik, Laurianne; Cordier, Marie; Saillard, Jean-Yves; Rodríguez-López, Julián; Robin-Le Guen, Françoise; Gauthier, Sébastien; Achelle, Sylvain [Dalton Transactions, 2023, vol. 52, # 7, p. 1927 - 1938]

23
[ 22536-63-6 ]
[ 915088-14-1 ]
[ 2945121-95-7 ]

Yield	Reaction Conditions	Operation in experiment
76 %	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In water; toluene at 100℃; Inert atmosphere; Schlenk technique;

24
[ 915088-14-1 ]
[ 33034-67-2 ]
[ 2945121-96-8 ]

Yield	Reaction Conditions	Operation in experiment
80 %	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In water; toluene at 100℃; Inert atmosphere; Schlenk technique;

25
[ 14508-49-7 ]
[ 915088-14-1 ]
[ 2945121-98-0 ]

Yield	Reaction Conditions	Operation in experiment
88 %	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In water; toluene at 100℃; Inert atmosphere; Schlenk technique;

26
[ 5190-68-1 ]
[ 915088-14-1 ]
[ 2945122-00-7 ]

Yield	Reaction Conditions	Operation in experiment
55 %	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In water; toluene at 100℃; Inert atmosphere; Schlenk technique;

27
[ 915088-14-1 ]
[ 259092-66-5 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
25.3 %	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate In ethanol; water; toluene Inert atmosphere; Reflux;	3 Under an argon atmosphere, intermediates 8 (9.8 g, 1.0 equivalents, 26.30 mmol), intermediate 9 (6.73 g, 1.0 equivalents, 26.30 mmol), tetrakis (triphenylphosphine) palladium (0) (1.5 g, 0.05 equivalents, 1.31 mmol), Na 2 CO3(6. 9 g, 2.0 equivalents, 65.74 mmol), toluene (98 ml), ethanol (24 ml) and H2O (78 ml) were added to thethree-prong flask and stirred under heat and stirring under reflux for 12 hours. After cooling to room temperature, the reaction solution was filtered to obtain crystals. THF was added to dissolve the crystals, then passed through a silica gel pad, and the solvent was removed by reduced pressure distillation to obtain intermediate 10 (2.8 g, yield: 25.3%).
25.3 %	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate In ethanol; water; toluene Inert atmosphere; Reflux;	3 Synthesis of Intermediate 10 In an argon atmosphere, Intermediate 8 (9.8 g, 1.0 eq, 26.30 mmol), Intermediate 9 (6.73 g, 1.0 eq, 26.30 mmol), tetrakis(triphenylphosphine)palladium(0) (1.5 g, 0.05 eq, 1.31 mmol), Na2CO3 (6.9 g, 2.0 eq, 65.74 mmol), toluene (98 ml), ethanol (24 m1), and H2O (78 ml) were added to a three-neck flask, and heated while stirring under reflux for 12 hours. After cooling to room temperature, the reaction solution was filtered to obtain crystals. After dissolving the crystals by adding THF thereto, the reaction solution was passed through a pad of silica gel, and the solvent was removed therefrom by distillation under reduced pressure to obtain Intermediate 10 (2.8 g, yield: 25.3%).

Reference： [1]Current Patent Assignee: SAMSUNG ELECTRONICS CO.,LTD. - KR2023/41574, 2023, A Location in patent: Paragraph 0276-0278; 0288-0290
[2]Current Patent Assignee: SAMSUNG ELECTRONICS CO.,LTD. - US2023/126543, 2023, A1 Location in patent: Paragraph 0219; 0226-0227

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P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 915088-14-1 ] {[proInfo.proName]}

Quality Control of [ 915088-14-1 ]

Related Doc. of [ 915088-14-1 ]

Product Details of [ 915088-14-1 ]

Safety of [ 915088-14-1 ]

Application In Synthesis of [ 915088-14-1 ]

[ 915088-14-1 ] Synthesis Path-Downstream 1~27

Related Functional Groups of [ 915088-14-1 ]

Organoboron

Esters

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 915088-14-1 ]