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Chemical Structure| 92345-90-9 Chemical Structure| 92345-90-9

Structure of 92345-90-9

Chemical Structure| 92345-90-9

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Product Details of [ 92345-90-9 ]

CAS No. :92345-90-9
Formula : C12H14O3
M.W : 206.24
SMILES Code : O=CC1=CC=C(OC)C(OC)=C1CC=C
MDL No. :MFCD28142850

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Application In Synthesis of [ 92345-90-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 92345-90-9 ]

[ 92345-90-9 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 784-04-3 ]
  • [ 92345-90-9 ]
  • 3-(2-allyl-3,4-dimethoxyphenyl)-1-anthracen-9-yl-propenone [ No CAS ]
  • 2
  • [ 784-04-3 ]
  • [ 92345-90-9 ]
  • [ 1391762-51-8 ]
YieldReaction ConditionsOperation in experiment
With sodium hydroxide; In methanol; at 20℃; for 6h;Inert atmosphere; Reflux; General procedure: NaOH (160 mg, 4.0 mmol) was added to a solution of substituted benzaldehydes 1 (2.0 mmol) in MeOH (20 mL) at rt. Then aryl methylketones 2a-p (2.05 mmol) or tert-butyl methyl ketones 2q-v (2.05 mmol) was added to the reaction mixture. The reaction mixture was stirred at reflux for 6 h. The reaction mixture was concentrated to yield the residue. The residue was extracted with EtOAc (330 mL). The combined organic layers were washed with brine, dried, filtered, and evaporated to afford crude skeleton 3 with quantitative yields. Without further purification, reduction of crude skeleton 3 was treated with NaBH4 in the next step. Synthesis of skeleton 3 is a known protocol and the related analytical data are consistent with those in the literature.5a,b
  • 3
  • [ 784-04-3 ]
  • [ 92345-90-9 ]
  • [ 1446353-84-9 ]
 

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