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Chemical Structure| 19792-91-7 Chemical Structure| 19792-91-7
Chemical Structure| 19792-91-7

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Synonyms: Phenyl sulfamate

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Product Details of Phenyl sulfamate

CAS No. :19792-91-7
Formula : C6H7NO3S
M.W : 173.19
SMILES Code : O=S(OC1=CC=CC=C1)(N)=O
Synonyms :
Phenyl sulfamate
MDL No. :MFCD00901858

Safety of Phenyl sulfamate

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis of Phenyl sulfamate

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 19792-91-7 ]

[ 19792-91-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 702-79-4 ]
  • [ 19792-91-7 ]
  • C18H25NO3S [ No CAS ]
YieldReaction ConditionsOperation in experiment
80% With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate; for 2.5h; In a 100 ml stainless steel mortar, <strong>[702-79-4]1,3-dimethyladamantane</strong> (2.464 g, 15.0 mmol), Rh2 (esp) 2 (0.05 mmol, 37.9 mg), phenylsulfamate (10.0 mmol, 1.73 g), iodobenzene diacetate (20 mmol, 6.4 g), NaHCO3 (10 g). Then put the stainless steel mortar on the ball mill. After it is safely placed, adjust the rotation speed to 350r / min for 150min and start the machine. After the reaction was completed, it was cooled to room temperature to obtain a crude product. The solid in the mortar was transferred out and separated using a silica gel column of 100-200 mesh, and eluted with a mixed solvent of petroleum ether / ethyl acetate. The target product was collected, and the organic phase was concentrated under reduced pressure to remove the solvent, and dried under vacuum to give a white color. Solid, isolated yield was 80%
 

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