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Chemical Structure| 103-01-5 Chemical Structure| 103-01-5

Structure of N-Phenylglycine
CAS No.: 103-01-5

Chemical Structure| 103-01-5

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Product Citations

Product Citations

Wang, Huaming ; Shen, Xianyan ; Du, Changling ; Liu, Xian‐You ; Yang, Anyu ; Cao, Yanni , et al.

Abstract: Removable adhesives with controllable bonding and debonding capabilities are essential for biomedical devices, temporary fixation, and recyclable materials. Here, a dual-wavelength hydrogel glue is presented that integrates visible-light polymerization (470 nm) for strong adhesion and UV-induced degradation (365 nm) for rapid debonding. The system leverages camphorquinone as a visible-light photoinitiator and ortho-nitrobenzyl poly(ethylene glycol) dimethacrylate (ONB-PEGDMA) as a UV-cleavable crosslinker, ensuring independent control over adhesion and detachment with orthogonal polymerization and degradation. The degradation rate of ONB-PEGDMA increases proportionally with light intensity, providing precise control over cleavage kinetics, with first-order rate constants of 0.155, 0.278, and 0.669 min−1 for 20, 50, and 100 mW cm−2, respectively. The hydrogel exhibits strong adhesion (≈200 kPa) and undergoes a fourfold reduction in adhesion strength within 90 s of 365 nm irradiation at 100 mW cm−2 under a constant tensile load of 10 N, enabling efficient removal. Rheological analysis confirms a significant decrease in storage modulus and crosslinking density after UV exposure, leading to network softening and structural failure. This work pioneers a phototunable hydrogel glue that bridges photopolymerization and photodegradation, offering a promising platform for next-generation adhesives with precise spatiotemporal control and with easy application, good bonding, and rapid UV-triggered debonding.

Keywords: decrosslinking ; hydrogel ; ortho-nitrobenzyl ; photo-responsive ; removable glue

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Product Details of [ 103-01-5 ]

CAS No. :103-01-5
Formula : C8H9NO2
M.W : 151.16
SMILES Code : O=C(O)CNC1=CC=CC=C1
MDL No. :MFCD00014009

Safety of [ 103-01-5 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 103-01-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 103-01-5 ]

[ 103-01-5 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 71176-54-0 ]
  • [ 103-01-5 ]
  • [(4-{(E)-[3,5-bis(hydroxymethyl)phenyl]diazenyl}phenyl)amino]acetic acid [ No CAS ]
 

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