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Chemical Structure| 104863-68-5 Chemical Structure| 104863-68-5

Structure of 104863-68-5

Chemical Structure| 104863-68-5

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Product Details of [ 104863-68-5 ]

CAS No. :104863-68-5
Formula : C11H15NO3
M.W : 209.24
SMILES Code : O=C(N(OC)C)COCC1=CC=CC=C1
MDL No. :MFCD11847697

Safety of [ 104863-68-5 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 104863-68-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 104863-68-5 ]

[ 104863-68-5 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 32707-89-4 ]
  • [ 104863-68-5 ]
  • C17H12F6O2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
Ketones: alpha-Benzylated acetamides 19 (0.14-0.35 mmol) obtained above were dissolved in anhydrous THF (2 ml). 2 equivalents of aromatic Grignard reagents or aromatic lithium reagents (0.28-0.70 mmol) were added drop-wise. The reaction mixtures were stirred at room temperature for 10 minutes before CH2Cl2 (2 ml) and MeOH (1 ml) were added to quench the reaction. The mixtures were filtered through pads of silica gel in parallel and the silica pads were rinsed with ethyl acetate. The combined filtrates were concentrated and the residues were purified by flash chromatography on silica to give ketones 20.
 

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