Home Cart Sign in  
Chemical Structure| 106006-85-3 Chemical Structure| 106006-85-3

Structure of 106006-85-3

Chemical Structure| 106006-85-3

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 106006-85-3 ]

CAS No. :106006-85-3
Formula : C10H15N3OS
M.W : 225.31
SMILES Code : CCC(N[C@H](CC1)CC2=C1N=C(N)S2)=O
MDL No. :MFCD07369802

Safety of [ 106006-85-3 ]

Application In Synthesis of [ 106006-85-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 106006-85-3 ]

[ 106006-85-3 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 123-62-6 ]
  • [ 106092-11-9 ]
  • [ 106006-85-3 ]
  • 2
  • [ 106006-85-3 ]
  • [ 104632-27-1 ]
YieldReaction ConditionsOperation in experiment
77% General procedure: In typical experimental procedure for the Synthesis of (3aS,12bS)-5-chloro-2-methyl-2,3,3a,12b-tetrahydro-1H-dibenzo[2,3:6,7]oxepino[4,5-c]pyrrolemaleate(1b?): Amide (1a) (10 g, 33.43 mmol) and DCM (100 mL) were charged into a round bottomed flask and stirred under nitrogen atmosphere for 10-15 minutes and cooled to 0-5C. Trimethylsilyl chloride (5.1 mL, 40.12 mmol) was then added to the mixture over 10-15 minutes and stirred for 10-15 minutes at same temperature.Lithium aluminum hydride (19.5 mL, 46.81 mmol) in THF solution is added dropwise at -10-0C. After complete addition, the solution is allowed to 0-10C and stirring is continued for 1-2 hours. After completion of reaction (TLC), thereaction was quenched by slow dropwise addition of 2M sodium hydroxide (30 mL)and stirred for 10-15 minutes. Separate aqueous and organic layer. Extract the compound from aqueous layer with DCM (50.0 mL). Combine both the organic layerand wash with 20% sodium chloride solution. Concentrate the DCM to get the crude which was dissolved in isopropyl alcohol (50.0 mL).
 

Historical Records

Technical Information

Categories