Home Cart Sign in  
Chemical Structure| 106456-88-6 Chemical Structure| 106456-88-6

Structure of 106456-88-6

Chemical Structure| 106456-88-6

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 106456-88-6 ]

CAS No. :106456-88-6
Formula : C13H16O3
M.W : 220.26
SMILES Code : O=CC1=CC=C(C2OCC(C)(C)CO2)C=C1
MDL No. :MFCD30572359
InChI Key :MPTODIKBGJACHZ-UHFFFAOYSA-N
Pubchem ID :14827744

Safety of [ 106456-88-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 106456-88-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 106456-88-6 ]

[ 106456-88-6 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 106456-88-6 ]
  • [ 126136-05-8 ]
  • [ 128376-65-8 ]
  • (5Z,10Z,14Z,19Z)-5-[4-(5,5-Dimethyl-[1,3,2]dioxaborinan-2-yl)-phenyl]-15-[4-(5,5-dimethyl-[1,3]dioxan-2-yl)-phenyl]-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-porphyrin [ No CAS ]
  • 2
  • [ 33322-60-0 ]
  • [ 106456-88-6 ]
  • [ 1638645-86-9 ]
  • 3
  • [ 33322-60-0 ]
  • [ 106456-88-6 ]
  • [ 1638645-67-6 ]
  • 4
  • [ 106456-88-6 ]
  • [ 159152-14-4 ]
  • [ 110677-45-7 ]
  • 5-(4-(9H-carbazol-9-yl)phenyl)-15-(4-formylphenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrin [ No CAS ]
YieldReaction ConditionsOperation in experiment
8.7% 0.5 mmol aldehyde, 0.5mmol compound (2) and 1 mmol 2,2’-(2,4,6-trimethylphenylmethylene)bispyrrol (1) were added into the 100 ml dichloromethane, stirring 2 minutes under nitrogen protection, then 180 μL trifluoroacetic acid was added in a period of 30 seconds. Reaction stirred at room temperature for 1 hour, then added P-chloranil 227 mg (1 mmol) and stirred another 1 hour. After that, the mixture was neutralized by 0.337 ml triethylamine and concentrated under vacuum at 50 . The remain was purified with silica (dichloromethane/petroleum ether 7:3) to get dark purple solid. 5-(4-(9H-carbazol-9-yl)phenyl)-15-(4-formylphenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrin (3a): Yield: 8.7%, 1H NMR (400 MHz, CDCl3) δ 10.40 (s, 1H), 8.98 (d, J = 4.7 Hz, 2H), 8.80 (d, J = 4.7 Hz, 2H), 8.76 (s, 4H), 8.48 (d, J = 8.2 Hz, 2H), 8.44 (d, J = 7.9 Hz, 2H), 8.29 (t, J = 7.7 Hz, 4H), 8.00 (d, J = 8.2 Hz, 2H), 7.84 (d, J = 8.2 Hz, 2H), 7.59 (t, J = 7.6 Hz, 2H), 7.42 (t, J = 7.4 Hz, 2H), 7.32 (s, 4H), 2.66 (s, 6H), 1.88 (s, 12H), -2.56 (s, 2H).
 

Historical Records

Technical Information

Categories