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Type HazMat fee for 500 gram (Estimated)
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Chemical Structure| 1121-37-5 Chemical Structure| 1121-37-5

Structure of 1121-37-5

Chemical Structure| 1121-37-5

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Product Details of [ 1121-37-5 ]

CAS No. :1121-37-5
Formula : C7H10O
M.W : 110.15
SMILES Code : O=C(C1CC1)C2CC2
MDL No. :MFCD00001276
InChI Key :BIPUHAHGLJKIPK-UHFFFAOYSA-N
Pubchem ID :70721

Safety of [ 1121-37-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225-H302-H315-H318
Precautionary Statements:P210-P233-P240-P241+P242+P243-P264-P270-P280-P301+P312+P330-P302+P352+P332+P313+P362+P364-P305+P351+P338+P310-P370+P378-P403+P235-P501
Class:3(8)
UN#:2924
Packing Group:

Application In Synthesis of [ 1121-37-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1121-37-5 ]

[ 1121-37-5 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 1121-37-5 ]
  • [ 131818-17-2 ]
  • tert-butyl N-[4-[dicyclopropyl(hydroxy)methyl]phenyl]carbamate [ No CAS ]
YieldReaction ConditionsOperation in experiment
16.5 g i) To a solution of tert-butyl N-(4-bromophenyl)carbamate (20.1 g) in dry THF (400 mL) at -78C under nitrogenatmosphere was added dropwise n-BuLi (59.1 mL, 2.5 M in hexanes). After stirring at -78C for 2 hours, dicyclopropylmethanone(9.28 mL) was added dropwise and the reaction mixture was allowed to slowly warm up to RTovernight. The reaction mixture was quenched by addition of a saturated aqueous NH4Cl solution (200 mL). Thelayers were separated and the aqueous layer was extracted with EtOAc (2x200 mL). The combined organic extractswere washed with brine, dried over Na2SO4 and concentrated under reduced pressure. The residue was purifiedby column chromatography on silica gel, using DCM as the eluent to obtain 16.5 g of tert-butyl N-[4-[dicyclopropyl(hydroxy)methyl]phenyl]carbamate.
  • 2
  • [ 1121-37-5 ]
  • [ 131818-17-2 ]
  • (4-aminophenyl)-dicyclopropyl-methanol [ No CAS ]
 

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