Alternatived Products of [ 1153-45-3 ]
Product Details of [ 1153-45-3 ]
CAS No. : | 1153-45-3 |
MDL No. : | MFCD00092127 |
Formula : |
C13H11NO5S
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
293.30
|
Pubchem ID : | - |
Synonyms : |
|
Safety of [ 1153-45-3 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 1153-45-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 1153-45-3 ]
- Downstream synthetic route of [ 1153-45-3 ]
- 1
-
[ 110-89-4 ]
-
[ 1153-45-3 ]
-
[ 100-02-7 ]
-
[ 4703-22-4 ]
-
[ 6574-15-8 ]
- 2
-
[ 288-32-4 ]
-
[ 1153-45-3 ]
-
[ 2232-08-8 ]
- 3
-
[ 1153-45-3 ]
-
tetraethylammonium imidazolate
[ No CAS ]
-
[ 2232-08-8 ]
- 4
-
[ 288-13-1 ]
-
[ 1153-45-3 ]
-
[ 6126-10-9 ]
Yield | Reaction Conditions | Operation in experiment |
12% |
With potassium chloride In ethanol; water at 25℃; |
|
- 5
-
[ 2075-45-8 ]
-
[ 1153-45-3 ]
-
[ 116228-41-2 ]
Yield | Reaction Conditions | Operation in experiment |
|
With potassium chloride In ethanol; water at 25℃; |
|
- 6
-
[ 7569-26-8 ]
-
[ 1153-45-3 ]
-
4-nitro-3-(toluene-4-sulfonylmethyl)phenyl toluene-4-sulfonate
[ No CAS ]
- 7
-
[ 1153-45-3 ]
-
[ 3598-13-8 ]
-
3-cyanomethyl-4-nitrophenyl toluene-4-sulfonate
[ No CAS ]
-
3-amino-2,4-bis(4-chlorophenoxy)crotononitrile
[ No CAS ]
-
3-[(4-chlorophenoxy)cyanomethyl]-4-nitrophenyl toluene-4-sulfonate
[ No CAS ]
- 8
-
[ 1153-45-3 ]
-
4-bromoimidazolate ion
[ No CAS ]
-
[ 116228-41-2 ]
Yield | Reaction Conditions | Operation in experiment |
|
With potassium chloride In ethanol; water at 25℃; |
|
- 9
-
[ 1153-45-3 ]
-
[ 1576-35-8 ]
-
[ 14062-05-6 ]
- 10
-
[ 1153-45-3 ]
-
[ 100-46-9 ]
-
[ 100-02-7 ]
-
[ 14309-92-3 ]
-
[ 1576-37-0 ]
-
[ 104-15-4 ]
Yield | Reaction Conditions | Operation in experiment |
|
In acetonitrile at 65℃; |
|
- 11
-
[ 76-37-9 ]
-
[ 1153-45-3 ]
-
[ 786-31-2 ]
-
[ 14609-74-6 ]
- 12
-
[ 1153-45-3 ]
-
[ 1528-74-1 ]
Yield | Reaction Conditions | Operation in experiment |
83% |
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(acetylacetonato)palladium(II); zinc In tetrahydrofuran at 25℃; for 6h; |
|
- 13
-
[ 1153-45-3 ]
-
[ 98-80-6 ]
-
[ 952-97-6 ]
Yield | Reaction Conditions | Operation in experiment |
84% |
With copper(l) iodide; sulfur; sodium t-butanolate at 60 - 80℃; for 4h; |
Unsymmetrical Diaryl Sulfides from Arylboronic Acid and Phenolic Esters; General Procedure
General procedure: A one-necked flask was charged with CuI (30 mg, 0.15 mmol), NaOt-Bu (376 mg, 4.0 mmol), S8 (47 mg, 1.5 mmol), phenolic ester (1 mmol), arylboronic acid (1.1 mmol), and PEG200 (2 mL). The mixture was magnetically stirred and heated at 60-80 °C for the appropriate reaction time (Table 2). After completion of the reaction, the reaction mixture was cooled to r.t. H2O (4 mL) was added and the product was extracted with EtOAc (3 × 4 mL) and dried (anhyd Na2SO4). Evaporation of the solvent and purification by column chromatography on silicagel (n-hexane/EtOAc) gave the desired unsymmetrical diaryl sulfides in 74-95% yields. |
80 %Chromat. |
With sulfur; nickel(II) ferrite; sodium t-butanolate at 90℃; for 7h; Green chemistry; |
|
Reference:
[1]Rostami, Abed; Rostami, Amin; Ghaderi, Arash; Gholinejad, Mohammad; Gheisarzadeh, Sajedeh
[Synthesis, 2017, vol. 49, # 22, p. 5025 - 5038]
[2]Atashkar, Bahareh; Rostami, Amin; Rostami, Abed; Zolfigol, Mohammad Ali
[Applied Organometallic Chemistry, 2019, vol. 33, # 3]
- 14
-
[ 1153-45-3 ]
-
[ 639-58-7 ]
-
[ 952-97-6 ]
Yield | Reaction Conditions | Operation in experiment |
88% |
With potassium fluoride; copper diacetate; potassium carbonate; sulfur at 80℃; for 0.5h; |
C-S Bond Formation by the Reaction of Triphenyltin Chloride with Phenolic Esters; General Procedure
General procedure: A one-necked flask was charged with Cu(OAc)2 (30 mg, 0.15 mmol), K2CO3 (414 mg, 3.0 mmol), S8 (48 mg, 1.5 mmol), KF (180 mg, 3 mmol), phenolic ester (1 mmol), triphenyltin chloride (0.35 mmol), and PEG200 (1.5 mL). The mixture was magnetically stirred and heatedat 80 °C for the appropriate reaction time (Table 4). After completion of the reaction, the reaction mixture was cooled to r.t. H2O (4 mL) was added and the product was extracted with EtOAc (3 × 4 mL) and dried (anhyd Na2SO4). Evaporation of the solvent and purification by column chromatography on silica gel (n-hexane/EtOAc) gave the desired phenyl aryl sulfides in 79-94% yields. |
87 %Chromat. |
With sulfur; potassium fluoride; nickel(II) ferrite; potassium carbonate at 85℃; for 1h; Green chemistry; |
|
Reference:
[1]Rostami, Abed; Rostami, Amin; Ghaderi, Arash; Gholinejad, Mohammad; Gheisarzadeh, Sajedeh
[Synthesis, 2017, vol. 49, # 22, p. 5025 - 5038]
[2]Atashkar, Bahareh; Rostami, Amin; Rostami, Abed; Zolfigol, Mohammad Ali
[Applied Organometallic Chemistry, 2019, vol. 33, # 3]