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[ CAS No. 116529-62-5 ] {[proInfo.proName]}

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Chemical Structure| 116529-62-5
Chemical Structure| 116529-62-5
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Product Details of [ 116529-62-5 ]

CAS No. :116529-62-5 MDL No. :MFCD09909618
Formula : C7H4INO4 Boiling Point : -
Linear Structure Formula :- InChI Key :IZBFYNYRKIUGSG-UHFFFAOYSA-N
M.W : 293.02 Pubchem ID :18919883
Synonyms :

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Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 116529-62-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 116529-62-5 ]

[ 116529-62-5 ] Synthesis Path-Upstream   1~2

  • 1
  • [ 116529-62-5 ]
  • [ 20776-54-9 ]
YieldReaction ConditionsOperation in experiment
100% With tin(ll) chloride In ethyl acetate at 20℃; for 16 h; B. 2-Amino-4-iodo-benzoic acid. ; 4-lodo-2-nitro-benzoic acid (20 g, 68 mmol, 1.0 equiv.) was dissolved in 200 mL of EtOAc and then SnCl2.2H2O (46 g, 204 mmol, 3.0 equiv.) was added in three portions. The reaction mixture was stirred at rt for 16 h. Satd. aq. NaHCO3 was carefully added to adjust the mixture to pH=9. The precipitated solid was removed by filtration through diatomaceous earth, washing with water. The aqueous layer in the filtrate was separated and acidified with conc. HCl to pH=2. The precipitated solid was collected by filtration and dried to afford the title compound as white solid (19 g, 68 mmol, 100percent). 1H NMR (400 MHz, CD3OD): 1H NMR (500 MHz, CDCl3): 7.56 (d, J=8.5, 1H), 7.08 (s, 1H), 6.99 (d, J=8.5, 1H), 5.71 (br s, 2H).
Reference: [1] Patent: US2006/69286, 2006, A1, . Location in patent: Page/Page column 26
[2] American Chemical Journal, 1910, vol. 44, p. 448
  • 2
  • [ 116529-62-5 ]
  • [ 7664-41-7 ]
  • [ 20776-54-9 ]
Reference: [1] American Chemical Journal, 1910, vol. 44, p. 448
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