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Chemical Structure| 117923-32-7 Chemical Structure| 117923-32-7

Structure of 117923-32-7

Chemical Structure| 117923-32-7

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Product Details of [ 117923-32-7 ]

CAS No. :117923-32-7
Formula : C17H30O
M.W : 250.42
SMILES Code : CCC[C@@H]1CC[C@H](CC1)CCC2CCC(=O)CC2
MDL No. :MFCD12911604
InChI Key :OLRRTAGESHHXPY-UHFFFAOYSA-N
Pubchem ID :14495772

Safety of [ 117923-32-7 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P261-P302+P352-P305+P351+P338

Application In Synthesis of [ 117923-32-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 117923-32-7 ]

[ 117923-32-7 ] Synthesis Path-Downstream   1~7

  • 1
  • [ 117923-32-7 ]
  • [ 909122-17-4 ]
  • [ 1011301-09-9 ]
YieldReaction ConditionsOperation in experiment
With hydrogenchloride; magnesium; In tetrahydrofuran; water; toluene; First Step 1.0 g of well dried magnesium and 30 mL of THF were placed in a reactor under nitrogen atmosphere, and heated to 43 C. 10.0 g of 1-bromo-2-chloro-4-ethoxy-3-fluorobenzene (6) dissolved in 20 mL of THF was slowly added dropwise thereto at a temperature range of from 43 to 51 C., followed by stirring for 30 minutes. Thereafter, 21.2 g of <strong>[117923-32-7]4-(2-(trans-4-propylcyclohexyl)ethyl)cyclohexanone</strong> (7) dissolved in 20 mL of THF was slowly added dropwise thereto at a temperature range of from 50 to 55 C., followed by stirring for 30 minutes. After cooling the resulting reaction mixture to 25 C., the reaction mixture was mixed with 100 mL of 3N hydrochloric acid and 100 mL of toluene in a vessel and separated into an organic layer and an aqueous layer by standing still, so as to attain extraction to the organic layer. The resulting organic layer was fractionated and washed with water, a 2N sodium hydroxide aqueous solution, a saturated sodium bicarbonate aqueous solution and water, followed by drying over anhydrous magnesium sulfate. Thereafter, the solvent was removed by distillation under reduced pressure to obtain 16.4 g of 1-(2-chloro-4-ethoxy-3-fluorophenyl)-4-(2-(trans-4-propylcyclohexyl)ethyl)cyclohexanol (8). The resulting compound (8) was a yellow solid matter.
YieldReaction ConditionsOperation in experiment
Example 9 Properties of Liquid Crystal Compound (No. 18) A liquid crystal composition (x) containing 85% by weight of the base mixtures (i-i) and 15% by weight of 2-chloro-1-ethoxy-3-fluoro-4-(4-propylcyclohexa-1-enyl)benzene (No. 18) obtained in Example 7 was prepared.
  • 3
  • [ 108-86-1 ]
  • [ 117923-32-7 ]
  • (1-hydroxy-4-(2-(trans-4-n-propylcyclohexyl)ethyl)cyclohexyl)benzene [ No CAS ]
YieldReaction ConditionsOperation in experiment
With hydrogenchloride; In tetrahydrofuran; (1) Metal magnesium in an amount of 11.6 g was suspended in 100 ml of tetrahydrofuran (hereinafter referred to as THF) under nitrogen gas stream, and a solution prepared by dissolving 69 g of bromobenzene in 200 ml of THF was added dropwise in the suspension and then stirred at room temperature for 1 hour. A solution prepared by dissolving 100 g of 4-(2-(trans-4-n-propylcyclohexyl)ethyl)cyclohexanone in 300 ml of THF was added dropwise thereto and stirred at room temperature for 1 hour. After finishing of the reaction, 500 ml of dilute hydrochloric acid was added thereto and extracted with 1 l of ethyl acetate. Organic layer was washed with water and dried over anhydrous magnesium sulfate, and the solvent was distilled off under a reduced pressure to obtain 119 g of (1-hydroxy-4-(2-(trans-4-n-propylcyclohexyl)ethyl)cyclohexyl)benzene.
  • 4
  • [ 117923-32-7 ]
  • [ 138526-69-9 ]
  • 1-(trans-4-propylcyclohexyl)-2-[trans-4-(3,4,5-trifluorophenyl)cyclohexyl]ethane [ No CAS ]
YieldReaction ConditionsOperation in experiment
Using 4-[2-(trans-4-propylcyclohexyl)ethyl]cyclohexanone and 1-bromo-3,4,5-trifluorobenzene as starting raw materials, 1-(trans-4-propylcyclohexyl)-2-[trans-4-(3,4,5-trifluorophenyl)cyclohexyl]ethane was obtained in the same manner as in Example 1.
  • 5
  • [ 117923-32-7 ]
  • (1-methyl-4-(2-((1r,4s)-4-propylcyclohexyl)ethyl)cyclohexyl)(trifluoromethyl)sulfane [ No CAS ]
 

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