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Chemical Structure| 120239-63-6 Chemical Structure| 120239-63-6

Structure of 120239-63-6

Chemical Structure| 120239-63-6

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Product Details of [ 120239-63-6 ]

CAS No. :120239-63-6
Formula : C16H40N6
M.W : 316.53
SMILES Code : NCCCN(CCCN)CCCCN(CCCN)CCCN
MDL No. :MFCD00676811

Safety of [ 120239-63-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314
Precautionary Statements:P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P321-P363-P405-P501
Class:8
UN#:2735
Packing Group:

Application In Synthesis of [ 120239-63-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 120239-63-6 ]

[ 120239-63-6 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 6492-86-0 ]
  • [ 120239-63-6 ]
  • C64H60N10O8 [ No CAS ]
YieldReaction ConditionsOperation in experiment
74% In ethanol; at 70℃; for 2h; Poly(propylenamine) (0.316 g, 1 mmol) from first generation and <strong>[6492-86-0]4-amino-1,8-naphthalic anhydride</strong> (0.85 g, 4 mmol) were dissolved in ethanol (30 ml). The solution was refluxed 2 h at 70 C and the reaction was monitored using thin layer chromatography (TLC). After 2 h the resulting precipitate was filtered and dried in vacuum. Yield: 0.81 g (74%). FTIR (cm-1): 3346, 3226, 3082, 2943, 2825, 1676, 1629, 1610, 1570, 1358, 1238, 1167, 772,756. 1H NMR (CDCl3, 600 MHz ppm): 8.58 (d, J = 8.3 Hz, 4H, Ar-H), 8.28 (d, J = 8.0 Hz, 4H, Ar-H), 8.06 (d, J = 8.6 Hz, 4H, Ar-H), 7.52 (dd, J = 7.9 Hz, J = 6.0 Hz, 4H, Ar-H), 6.62 (d, J = 8.4 Hz, 4H, Ar-H), 6.47 (br.s, 8H, NH2), 4.04-4.12 (m, 8H, (OC)2NCH2), 2.84-2.96 (m, 12H, CH2N<), 2.00-2.14 (m, 8H, (OC)2NCH2CH2CH2N), 1.84-1.91 (m, 4H, -NCH2CH2CH2CH2N-). 13C NMR (CDCl3) delta (ppm): 164.4, 163.9, 152.3, 136.4, 132.0, 129.6, 125.7, 124.1, 123.2, 121.0, 114.3, 105.3, 56.9, 45.5, 42.7, 24.4.(MALDI TOF) Calc. for C64H60N10O8 (1096.1) found 1097.3 (M+H)+.Anal. Calc. C, 70.06; H, 5.51; N, 12.77. Found: C, 70.29; H, 5.68;N, 12.56.
 

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