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Exploring Eutectic Mixing of Quinones for Engineering High Energy-Density Electrolytes
Emily Penn ; Antonio Baclig ; Devi Ganapathi , et al. Chem. Mater.,2023,35(14):5255-5266. DOI: 10.1021/acs.chemmater.3c00156
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Abstract: Eutectic electrolytes can attain high concentrations of redox-active species, offering a path toward high energy density redox flow batteries. Here we introduce a new entropically-driven eutectic mixing approach using organic small molecules. By mixing chemically similar redox-active species, we engineer highly concentrated, low viscosity liquids composed almost entirely of redox-active molecules. Using quinones as a model system, we discover a ternary benzoquinone eutectic mixture and a binary naphthoquinone eutectic mixture which have theoretical redox-active electron concentrations of 16.8 and 8.8 M e–, respectively. We investigate compatibility with protic supporting electrolytes and quantify ionic conductivity and viscosity of quinone eutectic electrolytes across multiple states of charge. A binary naphthoquinone eutectic electrolyte with a protic ionic liquid supporting electrolyte (7.1 M e–, theoretical volumetric capacity 188 Ah L–1) achieves a volumetric capacity of 49 Ah L–1 in symmetric static cell cycling. These preliminary results suggest that entropy-driven eutectic mixing is a promising strategy for developing high-energy density flow battery electrolytes.
Purchased from AmBeed: 695-99-8 ; 553-97-9 ; 3602-55-9 ; 84-65-1 ; 288-32-4 ; 130-15-4 ; 2397-59-3 ; 137395-55-2
CAS No. : | 130-15-4 | MDL No. : | MFCD00001676 |
Formula : | C10H6O2 | Boiling Point : | No data available |
Linear Structure Formula : | C6H4C(O)CHCHC(O) | InChI Key : | FRASJONUBLZVQX-UHFFFAOYSA-N |
M.W : | 158.15 | Pubchem ID : | 8530 |
Synonyms : |
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Signal Word: | Danger | Class: | 8,6.1 |
Precautionary Statements: | P272-P280-P264-P270-P271-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P403+P233-P405-P501 | UN#: | 2923 |
Hazard Statements: | H314-H317-H331-H335-H410-H301+H311 | Packing Group: | Ⅲ |
GHS Pictogram: |
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