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Chemical Structure| 695-99-8 Chemical Structure| 695-99-8

Structure of 695-99-8

Chemical Structure| 695-99-8

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Product Citations

Emily Penn ; Antonio Baclig ; Devi Ganapathi ; William C. Chueh ;

Abstract: Eutectic electrolytes can attain high concentrations of redox-active species, offering a path toward high energy density redox flow batteries. Here we introduce a new entropically-driven eutectic mixing approach using organic small molecules. By mixing chemically similar redox-active species, we engineer highly concentrated, low viscosity liquids composed almost entirely of redox-active molecules. Using quinones as a model system, we discover a ternary benzoquinone eutectic mixture and a binary naphthoquinone eutectic mixture which have theoretical redox-active electron concentrations of 16.8 and 8.8 M e–, respectively. We investigate compatibility with protic supporting electrolytes and quantify ionic conductivity and viscosity of quinone eutectic electrolytes across multiple states of charge. A binary naphthoquinone eutectic electrolyte with a protic ionic liquid supporting electrolyte (7.1 M e–, theoretical volumetric capacity 188 Ah L–1) achieves a volumetric capacity of 49 Ah L–1 in symmetric static cell cycling. These preliminary results suggest that entropy-driven eutectic mixing is a promising strategy for developing high-energy density flow battery electrolytes.

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Product Details of [ 695-99-8 ]

CAS No. :695-99-8
Formula : C6H3ClO2
M.W : 142.54
SMILES Code : O=C(C=C1)C=C(Cl)C1=O
MDL No. :MFCD00075260
InChI Key :WOGWYSWDBYCVDY-UHFFFAOYSA-N
Pubchem ID :69671

Safety of [ 695-99-8 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 695-99-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 695-99-8 ]
  • Downstream synthetic route of [ 695-99-8 ]

[ 695-99-8 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 695-99-8 ]
  • [ 3786-46-7 ]
References: [1] Justus Liebigs Annalen der Chemie, 1906, vol. 349, p. 64.
[2] Justus Liebigs Annalen der Chemie, 1906, vol. 349, p. 64.
 

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