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[ CAS No. 131667-57-7 ]

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Chemical Structure| 131667-57-7
Chemical Structure| 131667-57-7
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Product Details of [ 131667-57-7 ]

CAS No. :131667-57-7 MDL No. :MFCD00798175
Formula : C10H17NO2 Boiling Point : 218°C at 760 mmHg
Linear Structure Formula :- InChI Key :N/A
M.W :183.25 g/mol Pubchem ID :-
Synonyms :

Safety of [ 131667-57-7 ]

Signal Word:Danger Class:6.1
Precautionary Statements:P273-P301+P310-P305+P351+P338 UN#:2810
Hazard Statements:H301-H410 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 131667-57-7 ]

  • Upstream synthesis route of [ 131667-57-7 ]
  • Downstream synthetic route of [ 131667-57-7 ]

[ 131667-57-7 ] Synthesis Path-Upstream   1~4

  • 1
  • [ 131667-57-7 ]
  • [ 98303-20-9 ]
Reference: [1] Organic letters, 2000, vol. 2, # 2, p. 155 - 158
  • 2
  • [ 131667-57-7 ]
  • [ 161157-50-2 ]
YieldReaction ConditionsOperation in experiment
99% With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 3.25 h; [00263] Step A: A solution of m-CPBA (7.53 g, 32.7 mmol) in DCM (10 mL) was added to a solution of tert-butyl 5,6-dihydropyridine-l(2H)-carboxylate (5.00 g, 27.3 mmol) in DCM (20 mL) at 00C. The reaction was stirred at 00C for 15 minutes and then at room temperature for 3 hours. Saturated sodium sulfite solution (20 mL) and saturated sodium bicarbonate solution (30 mL) was added. The organic layer was separated, washed with brine, dried (sodium sulfate) and concentrated in vacuo to give tert-butyl 7-oxa-3-azabicyclo[4.1.0]heptane-3-carboxylate (5.36 g, 99percent) as oil.
Reference: [1] Patent: WO2009/140320, 2009, A1, . Location in patent: Page/Page column 77
  • 3
  • [ 131667-57-7 ]
  • [ 325486-45-1 ]
  • [ 128372-89-4 ]
Reference: [1] Journal of Organic Chemistry, 2017, vol. 82, # 16, p. 8506 - 8513
  • 4
  • [ 25015-63-8 ]
  • [ 171288-01-0 ]
  • [ 865245-32-5 ]
  • [ 131667-57-7 ]
Reference: [1] Journal of Organic Chemistry, 2005, vol. 70, # 18, p. 7324 - 7330
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