Name: 1357634-60-6|9-(2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole|95%
Brand: Ambeed
SKU: A633993
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1
[ 902518-11-0 ]
[ 1357634-60-6 ]
9,9'-biphenyl-2,2'-diylbis-9H-carbazole [ No CAS ]

Reference： [1]Journal of Materials Chemistry,2012,vol. 22,p. 2894 - 2899

2
[ 3842-55-5 ]
[ 1357634-60-6 ]
9-(2-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-carbazole [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
86%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water at 80℃; for 24h;	Preparation of 9-(2-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-carbazole (CzTrz) 9-(2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9Hcarbazole(3 g, 8.12 mmol), 2-chloro-4,6-diphenyl-1,3,5-triazine(2.61 g, 9.75 mmol), and tetrakis(triphenylphosphine)palladium(0) (0.28 g, 0.24 mmol) were dissolved in 2 M potassiumcarbonate solution (40 mL) and tetrahydrofuran (100 mL). The reactionmixture was stirred for 24 h at 80 C. The mixture wasdiluted with dichloromethane and washed thrice with distilledwater (100 mL). The organic layer was dried over anhydrous MgSO4and evaporated in vacuo to yield the crude product, which waspurified through column chromatography using dichloromethane/n-hexane to yield a pale yellow powder. The other dopants, mCzTrzand tCzTrz, were prepared through procedures similar to thosedescribed above.CzTrz Yield 86%. Tg: 124.6 C, Tm: 211.9 C, Td: 365.9 C (5%weight loss). 1H NMR (500 MHz, CDCl3): d 7.02e7.24 (m, 4H), 7.33 (t,6H, J 16 Hz), 7.48 (t, 2H, J 14.4 Hz), 7.73 (d, 1H, J 8.8 Hz), 7.78 (t,1H, J 15.2 Hz), 7.84 (t, 1H, J 15.2 Hz), 8.03 (t, 6H, J 17.6 Hz), 8.57(d, 1H, J 7.6 Hz). 13C NMR (CDCl3): d 109.5, 119.5, 120.2, 123.4,125.9, 128.3, 128.7, 128.8, 130.6, 132.3, 132.5, 132.7, 135.4, 136.1,141.7, 171.2, 172.1. MS (EI) m/z 474 [(MH)]. Anal Calcd forC33H22N4: C, 83.52%; H, 4.67%; N,11.81%. Found: C, 83.52%; H, 4.74%;N, 11.69%.

Reference： [1]Cha, Jae-Ryung; Lee, Chil Won; Lee, Jun Yeob; Gong, Myoung-Seon [Dyes and Pigments, 2016, vol. 134, p. 562 - 568]

3
[ 86-74-8 ]
[ 1357634-60-6 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: copper (I) iodide; potassium carbonate / N,N-dimethyl acetamide / 24 h / Inert atmosphere; Reflux 2: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; anhydrous potassium acetate / 1,4-dioxane / 24 h / 80 °C / Inert atmosphere
	Multi-step reaction with 2 steps 1: copper (I) iodide; potassium carbonate / N,N-dimethyl acetamide / 24 h / Inert atmosphere; Reflux 2: palladium (II) [1,1'-bis(diphenylphosphanyl)ferrocene] dichloride; anhydrous potassium acetate / 1,4-dioxane / 24 h / 80 °C / Inert atmosphere
	Multi-step reaction with 2 steps 1: copper (I) iodide; tripotassium phosphate tribasic; (±)-trans-1,2-diaminocyclohexane / toluene / 4 h 2: palladium (II) [1,1'-bis(diphenylphosphanyl)ferrocene] dichloride; anhydrous potassium acetate / 1,4-dioxane / 6 h

Reference： [1]Cha, Jae-Ryung; Lee, Chil Won; Lee, Jun Yeob; Gong, Myoung-Seon [Dyes and Pigments, 2016, vol. 134, p. 562 - 568]
[2]Cha, Jae-Ryung; Lee, Chil Won; Gong, Myoung-Seon [Dyes and Pigments, 2017, vol. 140, p. 399 - 406]
[3]Current Patent Assignee: LT SAMBO CO LTD - US2022/106332, 2022, A1

4
[ 583-53-9 ]
[ 1357634-60-6 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: copper(l) iodide; potassium carbonate / N,N-dimethyl acetamide / 24 h / Inert atmosphere; Reflux 2: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate / 1,4-dioxane / 24 h / 80 °C / Inert atmosphere
	Multi-step reaction with 2 steps 1: copper(l) iodide; potassium carbonate / N,N-dimethyl acetamide / 24 h / Inert atmosphere; Reflux 2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 24 h / 80 °C / Inert atmosphere

Reference： [1]Cha, Jae-Ryung; Lee, Chil Won; Lee, Jun Yeob; Gong, Myoung-Seon [Dyes and Pigments, 2016, vol. 134, p. 562 - 568]
[2]Cha, Jae-Ryung; Lee, Chil Won; Gong, Myoung-Seon [Dyes and Pigments, 2017, vol. 140, p. 399 - 406]

5
[ 902518-11-0 ]
[ 73183-34-3 ]
[ 1357634-60-6 ]

Yield	Reaction Conditions	Operation in experiment
80%		Under the protection of nitrogen atmosphere,2-bromobenzoxazole10mmol and bis(pinacol) diboron 10mmol were added to the three-necked bottle.Add 50 mL of dioxane to stir to dissolve, and pass nitrogen for 30 min. Add potassium acetate 10mmol,The temperature was raised to 100 ° C and the reaction was stirred for 12 h.The crude product was purified by silica gel column chromatography.The eluent is a 2:1 dichloromethane-n-hexane mixed solvent. A white crystalline product was obtained in a yield of 80percent.
	With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate; In 1,4-dioxane; at 80℃; for 24h;Inert atmosphere;	A mixture of <strong>[902518-11-0]9-(2-bromophenyl)-9H-carbazole</strong> (10 g,31.04 mmol), 4,4,40,40,5,5,50,50-octamethyl-2,20-bi(1,3,2-dioxaborolane) (10.25 g, 40.35 mmol), 1,10-bis(diphenylphosphino)ferrocene-palladium(II) dichloride dichloromethanecomplex (0.76 g, 0.93 mmol), potassium acetate (9.14 g,93.11 mmol), and anhydrous 1,4-dioxane (180 mL) was degassedwith nitrogen for 1 h while stirring. The reaction mixture was thenmaintained under a nitrogen atmosphere at 80 C for 24 h. Themixture was diluted with dichloromethane and washed thrice withdistilled water (100 mL). The organic layer was dried over anhydrousMgSO4 and evaporated in vacuo to yield the crude product,which was purified through column chromatography usingdichloromethane/n-hexane to obtain a white powder. Other intermediatecompounds, 3,6-dimethyl-9-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole and 3,6-di-tert-butyl-9-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9Hcarbazolewere prepared by similar procedures described above.1H NMR (500 MHz, CDCl3): d 0.79 (s, 12H), 7.18 (d, 2H, J 12 Hz),7.25 (t, 2H, J 18 Hz), 7.37 (t, 2H, J 18 Hz), 7.53 (t, 2H, J 18 Hz),7.69 (t, 1H, J 16 Hz), 7.96 (d, 1H, J 12 Hz), 8.14 (d, 2H, J 12 Hz).
	With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; at 80℃; for 24h;Inert atmosphere;	A mixture of <strong>[902518-11-0]9-(2-bromophenyl)-9H-carbazole</strong> (10 g,31.04 mmol), 4,4,4',4',5,5,5',5'-octamethyl-2,2'-bi(1,3,2-dioxaborolane) (10.25 g, 40.35 mmol), 1,1'-bis(diphenylphosphino)ferrocene-palladium(II) dichloride dichloromethane complex(0.76 g, 0.93 mmol), potassium acetate (9.14 g, 93.11 mmol),and anhydrous 1,4-dioxane (180 ml) was degassed with nitrogenfor 1 h while stirring. The reaction mixture was then maintained innitrogen at 80 °C for 24 h. The mixture was diluted withdichloromethane and washed with distilled water (100 mL) threetimes. The organic layer was dried over anhydrous MgSO4 andevaporated in vacuo to give the crude product, which was purifiedby column chromatography using dichloromethane/n-hexane andgave a white powder.1H NMR (500 MHz, CDCl3): delta 0.79 (s, 12H), 7.18 (d, 2H, J = 12 Hz),7.25 (t, 2H, J = 18 Hz), 7.37 (t, 2H, J = 18 Hz), 7.53 (t, 2H, J = 18 Hz),7.69 (t, 1H, J = 16 Hz), 7.96 (d, 1H, J = 12 Hz), 8.14 (d, 2H, J = 12 Hz).13C NMR (CDCl3): delta 24.4, 83.4, 109.7, 119.1, 119.9, 123.1, 125.5, 127.6,128.6, 132.1, 136.3, 142.1, 142.4.

Reference： [1]Patent: CN108484592,2018,A .Location in patent: Paragraph 0061; 0062; 0064
[2]Dyes and Pigments,2016,vol. 134,p. 562 - 568
[3]Dyes and Pigments,2017,vol. 140,p. 399 - 406

6
[ 1700-02-3 ]
[ 1357634-60-6 ]
9,9'-((6-phenyl-1,3,5-triazine-2,4-diyl)bis(2,1-phenylene))bis(9H-carbazole) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
71%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran at 80℃; for 24h;	2.4. Preparation of 9,9'-((6-phenyl-1,3,5-triazine-2,4-diyl)bis(2,1-phenylene))bis(9H-carbazole) (BisCz-Trz) 9-(2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9Hcarbazole(11.04 g, 27.87 mmol), 2,4-dichloro-6-phenyl-1,3,5-triazine (3 g, 13.27 mmol), and tetrakis(triphenylphosphine)palladium(0) (1.53 g, 1.33 mmol) were dissolved in a 2 M potassiumcarbonate solution (40 mL) and tetrahydrofuran (100 mL). The reactionmixture was stirred for 24 h at 80 °C. The mixture wasdiluted with dichloromethane and washed with distilled water(100 mL) three times. The organic layer was dried over anhydrousMgSO4 and evaporated in vacuo to give the crude product, whichwas purified by column chromatography using dichloromethane/nhexaneand gave a pale yellow powder.BisCz-Trz: Yield 71%. Tg: 100 °C, Tm: 263 °C, Td: 374 °C (5%weight loss). 1H NMR (500 MHz, CDCl3): δ 6.79 (d, 2H, J = 8 Hz),6.895 (t, 2H, J = 15 Hz), 6.965 (d, 4H, J = 8 Hz), 7.163-7.217 (m, 5H),7.263 (t, 4H, J = 15 Hz), 7.478 (t, 2H, J = 15 Hz), 7.563 (d, 2H,J = 8 Hz), 7.659-7.708 (m, 4H), 7.986 (d, 4H, J = 8 Hz). 13C NMR(CDCl3): δ 109.4, 119.4, 120.1, 123.3, 125.9, 127.8, 128.4, 128.6, 130.4,131.9, 132.4, 132.6, 135.3, 136.4, 141.5. Mass (EI) m/z 639 [(M+H)+].Anal Calcd for C45H29N5: C, 84.48%; H, 4.57%; N, 10.95%. Found: C,84.48%; H, 4.57%; N, 10.86%. UV-vis: λmax 339 (THF) nm. Fluorescence: λmax (emission) 457 (solid state) nm. Φfl 0.756.

Reference： [1]Cha, Jae-Ryung; Lee, Chil Won; Gong, Myoung-Seon [Dyes and Pigments, 2017, vol. 140, p. 399 - 406]

7
[ 108-77-0 ]
[ 1357634-60-6 ]
2,4,6-tris(2-(9H-carbazol-9-yl)phenyl)-1,3,5-triazine [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
37%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran at 80℃; for 24h;	2.5. Preparation of 2,4,6-tris(2-(9H-carbazol-9-yl)phenyl)-1,3,5-triazine (TrisCz-Trz) 9-(2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9Hcarbazole(15.36 g, 53.68 mmol), 2,4,6-trichloro-6-1,3,5-triazine(3 g, 16.27 mmol), and tetrakis(triphenylphosphine)palladium(0)(2.82 g, 2.44 mmol) were dissolved in a 2 M potassium carbonatesolution (40 mL) and tetrahydrofuran (100 mL). The reactionmixture was stirred for 24 h at 80 °C. The mixture was diluted withdichloromethane and washed with distilled water (100 mL) three times. The organic layer was dried over anhydrous MgSO4 andevaporated in vacuo to give the crude product, which was purifiedby column chromatography using dichloromethane/n-hexane andgave a pale yellow powder.TrisCz-Trz: Yield 37%. Tg: 126 °C, Tm: 323 °C, Td: 395 °C (5%weight loss). 1H NMR (500 MHz, CDCl3): δ 6.238 (d, 3H, J = 8 Hz),6.558 (d, 6H, J = 8 Hz), 6.968 (t, 3H, J = 15 Hz), 7.216-7.261 (m,12H),7.341 (d, 3H, J = 8 Hz), 7.485 (t, 3H, J = 15 Hz), 8.100 (d, 6H, J = 7 Hz).13C NMR (CDCl3): δ 109.4, 119.2, 123.2, 125.9, 128.2, 130.0, 132.2,133.6, 136.0, 141.3, 170.2. Mass (EI) m/z 803 [(M+H)+]. Anal Calcdfor C57H36N6 C, 85.05%; H, 4.51%; N, 10.44%. Found: C, 85.07%; H,4.49%; N, 10.45%. UV-vis: λmax 339 (THF) nm. Fluorescence: λmax(emission) 457 (solid state) nm. Φfl 0.708.

Reference： [1]Cha, Jae-Ryung; Lee, Chil Won; Gong, Myoung-Seon [Dyes and Pigments, 2017, vol. 140, p. 399 - 406]

8
[ 566939-58-0 ]
[ 1357634-60-6 ]
1,3-bis[2-(9H-carbazol-9-yl)phenyl]-5-octyl-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione [ No CAS ]

Reference： [1]Journal of Materials Chemistry C,2017,vol. 5,p. 1997 - 2004

9
[ 1357634-60-6 ]
4'-(5-bromo-3-ethyl-2-(pyridin-4-yl)-3H-benzo[e]indol-1-yl)-4-(9H-carbazol-9-yl)-[1,1'-biphenyl]-3-carbonitrile [ No CAS ]
4'-(5-(2-(9H-carbazol-9-yl)phenyl)-3-ethyl-2-(pyridin-4-yl)-2,3-dihydro-1H-benzo[e]indol-1-yl)-4-(9H-carbazol-9-yl)-[1,1'-biphenyl]-3-carbonitrile [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
24.1%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾ In N,N-dimethyl-formamide at 95℃; for 12h; Inert atmosphere;	1.6 Step 6 Add compound e to the reaction flask4'-(5-bromo-2-(pyridin-4-yl)-3H-benzo[e]indol-1-yl)-4-(9H-carbazol-9-yl)-[1,1 '-biphenyl]-3-carbonitrile (0.08069 g, 0.1163 mmol), 9-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane- 2-yl)phenyl)-9H-carbazole (0.04296 g, 0.1170 mmol) and tetrachlorotriphenylphosphine palladium (0) (0.0010 g, 0.007 mmol) was added under nitrogen atmosphere to remove nitrogen three times. A 3:1 volume ratio of DMF and (2M) K2CO3 solution was added to the reaction flask for reaction.The reaction temperature is 95° C., and the reaction is stopped after 12 h, and extracted with ethyl acetate and deionized water for 2-3 times.The upper organic phase was dried over anhydrous magnesium sulfate and evaporated to dryness. Column chromatography (eluent is ethyl acetate:Petroleum ether = 1:2) gave 0.024 g (yield 24.1%) of a yellow powder of CzCNPyCa-1.

Reference： [1]Current Patent Assignee: NANJING UNIVERSITY OF POSTS AND TELECOMMUNICATIONS - CN107827874, 2018, A Location in patent: Paragraph 0042; 0053; 0054

10
[ 90-90-4 ]
[ 1357634-60-6 ]
C₃₁H₂₁NO [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
66%	Stage #1: (4-bromophenyl)(phenyl)methanone; 9-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane- 2-yl)phenyl)-9H-carbazole With potassium carbonate In water; toluene for 0.0833333h; Inert atmosphere; Stage #2: With tetrakis(triphenylphosphine) palladium⁽⁰⁾ In water; toluene for 36h; Reflux;	3.2 (2) Synthesis of the final product [4-(2-benzoxazole) benzophenone] 4-bromobenzophenone 10mmol under nitrogen atmosphere protectionAnd 12mmol of 2-carbazole phenylborate was added to the three-necked bottle.Add 50 mL of toluene and stir to dissolve.Adding potassium carbonate aqueous solution 14mmol / 2ml H2O and 0.5ml phase transfer agent,After stirring for 5 minutes,0.05 g of tetrakistriphenylphosphine palladium was added as a catalyst.After stirring at reflux for 36 h, the reaction solution was cooled and suction filtered.The filtrate was evaporated to dryness using a rotary evaporator.Purification by silica gel column chromatography,The eluent was a mixed solution of dichloromethane and n-hexane in a volume ratio of 2:1.The white crystalline product was obtained in a yield of 66%.

Reference： [1]Current Patent Assignee: SUN YAT-SEN UNIVERSITY (CHINA) - CN108484592, 2018, A Location in patent: Paragraph 0061; 0065; 0066; 0067

11
[ 1357634-60-6 ]
C₃₇H₄₅ClFN₃ [ No CAS ]
C₅₅H₅₇FN₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium acetate; XPhos In 1,4-dioxane; water; toluene at 100℃;

Reference： [1]Current Patent Assignee: Samsung Display (in: Samsung); SAMSUNG ELECTRONICS CO.,LTD. - WO2019/101594, 2019, A1 Location in patent: Page/Page column 68

12
[ 1353056-40-2 ]
[ 1357634-60-6 ]
C₄₁H₂₅Br₂N₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
76%	With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; potassium carbonate; tri tert-butylphosphoniumtetrafluoroborate In water; toluene at 20℃; Inert atmosphere;	Under nitrogen protection, weigh compounds S22 (2.5 mmol), S23 (5.5 mmol),[Pd2 (dba) 3] · CHCl3 (0.12mmol) and HP (tBu) 3 · BF4 (0.24mmol),Add to a 250 mL two-necked flask. Inject 80mL of toluene into the two-necked flask (pass N2 for 15min to remove oxygen in advance),Then, 5.8 mL of a 1M K2CO3 aqueous solution (N2 was removed in advance for 15 minutes to remove oxygen) was added dropwise, and the mixture was stirred at room temperature overnight.After the reaction was completed, 25 mL of deionized water was added, and a few drops of 2M HCl were added dropwise.Extract with dichloromethane, collect the organic phase, and dry over anhydrous Na2SO4.The dried solution was filtered, and the solvent was removed on a rotary evaporator to obtain a crude product.The crude product was purified by a silica gel column, and finally purified to obtain solid S24 (1.9 mmol, 76%).

Reference： [1]Current Patent Assignee: TIANMA MICROELECTRONICS CO., LTD. - CN110642842, 2020, A Location in patent: Paragraph 0125-0127

13
[ 1357634-60-6 ]
C₄Br₂I₂S [ No CAS ]
C₄₀H₂₄Br₂N₂S [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
68%	With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; potassium carbonate; tri tert-butylphosphoniumtetrafluoroborate In water; toluene at 20℃; Inert atmosphere;	1 Example 1; Synthesis of compound P1 Under nitrogen protection, weigh compounds S1 (2.2 mmol), S2 (4.8 mmol),[Pd2 (dba) 3] · CHCl3 (0.10 mmol) and HP (t-Bu) 3 · BF4 (0.20 mmol),Add to a 250 mL two-necked flask.Inject 70mL of toluene into the two-necked flask (pass N2 in advance for 15min to remove oxygen),Then, 5 mL of a 1M K2CO3 aqueous solution was added dropwise (except for N215min in advance to remove oxygen), and stirred at room temperature overnight.After the reaction, 20 mL of deionized water was added, and a few drops of 2M HCl were added dropwise.Extract with dichloromethane, collect the organic phase, and dry over anhydrous Na2SO4.The dried solution was filtered, and the solvent was removed on a rotary evaporator to obtain a crude product.The crude product was purified by a silica gel column, and finally purified to obtain solid S20 (1.5 mmol, 68%).

Reference： [1]Current Patent Assignee: TIANMA MICROELECTRONICS CO., LTD. - CN110746413, 2020, A Location in patent: Paragraph 0111-0115

14
[ 1357634-60-6 ]
C₂₀H₁₀BrN₃ [ No CAS ]
C₃₈H₂₂N₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
13 g	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water	1 Synthesis of Compound EH1 16 g (43 mmol, 1 eq) of Intermediate EH1(1), 31.7 g (86 mmol, 2 eq) of Compound I-3, 23.8 g (172 mmol, 4 eq) of potassium carbonate (K2CO3), and 2.3 g (2 mmol, 0.05 eq) of Pd(PPh3)4 were added to a mixed solution of 110 ml of tetrahydrofuran (THF) and 85 ml of water, and the resulting mixed solution was stirred at a temperature of 85° C. overnight (by using a pressure reactor). The mixed solution thus obtained was cooled to room temperature, and the reaction mixture was extracted with ethyl acetate. The resulting organic layer was dried by using MgSO4, filtered, and concentrated in vacuo to remove the solvent. A resulting product obtained therefrom was separated and purified by silica gel column chromatography, thereby obtaining 13 g of Compound EH1 (purity of 99.95% by LC-MS). LC-Mass Cal.: 534.18 g/mol, Measured.: M+1=535.18 g/mol

Reference： [1]Current Patent Assignee: SAMSUNG ELECTRONICS CO.,LTD. - US2020/91439, 2020, A1 Location in patent: Paragraph 0268; 0271-0273

15
[ 1357634-60-6 ]
C₂₁H₉BrN₄ [ No CAS ]
C₃₉H₂₁N₅ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
13 g	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water	2 Synthesis of Compound EH2 16 g (40 mmol, 1 eq) of Intermediate EH2(1), 22.2 g (60 mmol, 1.5 eq) of Compound I-3, 16.8 g (120 mmol, 3 eq) of potassium carbonate (K2CO3), and 2.2 g (2 mmol, 0.05 eq) of Pd(PPh3)4 were added to a mixed solution of 300 ml of tetrahydrofuran (THF) and 75 ml of water, and the resulting mixed solution was stirred at a temperature of 85° C. overnight (by using a pressure reactor). The mixed solution thus obtained was cooled to room temperature, and the reaction mixture was extracted with ethyl acetate. The resulting organic layer was dried by using MgSO4, filtered, and concentrated in vacuo to remove the solvent. A resulting product obtained therefrom was separated and purified by silica gel column chromatography, thereby obtaining 13 g (purity of 99.90% by LC-MS) of Compound EH2.LC-Mass Cal.: 559.18 g/mol, Measured.: M+1=560.18 g/mol

Reference： [1]Current Patent Assignee: SAMSUNG ELECTRONICS CO.,LTD. - US2020/91439, 2020, A1 Location in patent: Paragraph 0274; 0277-0279

16
[ 1357634-60-6 ]
[ 55758-02-6 ]
C₂₄H₁₅N₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
32%	With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In tetrahydrofuran; water; for 18h;Reflux;	General procedure: 5.00 grams (g) (13.5 millimoles, mmol) of 9-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole, 2.73 g (14.9 mmol) of 6-bromopicolinonitrile, 0.782 g (0.680 mmol) of tetrakistriphenylphosphine palladium (0) (Pd(PPh3)4, and 4.68 g (33.9 mmol) of potassium carbonate were added to a mixture including 30 mL of THF and 15 mL of water, and the resulting mixture was stirred under reflux for 18 hours. After completion of the reaction, the reaction mixture was cooled to room temperature and the aqueous layer was removed therefrom through extraction. The organic layer was filtered under reduced pressure through a silica gel, and the filtrate was concentrated under reduced pressure. The product was filtered to obtain Compound 1 (3.37 g, the yield of 72%) by silica gel column chromatography. LC-Mass (calculated: 345.13 g/mol, found: M+1=346 g/mol)

Reference： [1]Patent: US2020/131150,2020,A1 .Location in patent: Paragraph 0378-0380; 0403-0408

17
[ 1357634-60-6 ]
C₂₄H₁₂Br₃N₉ [ No CAS ]
C₇₈H₄₈N₁₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
45%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In ethanol; toluene at 80℃; for 24h; Inert atmosphere;	1 Synthesis of compound 1-1: Compound TTT-Br (200mg, 0.3mmol),2-(9-carbazolyl) phenylboronic acid pinacol ester (665 mg, 1.8 mmol),Tetrakis(triphenyl)palladium (51 mg, 0.045 mmol),potassium carbonate (2mol/L, 5mL) and10mL: 30mL mixed solution of ethanol and toluene was added to a 100mL single-neck bottle,The mixture was heated to reflux at 80°C for 24h under nitrogen protection.After the reaction was completed, it was cooled to room temperature, the toluene was removed by rotary evaporation under reduced pressure, and the reaction solution was extracted with dichloromethane (4×30 mL).The collected organic layers were washed with water (50 mL),Drying and distillation under reduced pressure to remove the solvent,The residue was separated by column chromatography with dichloromethane as the eluent to obtain 155 mg of white solid with a yield of 45%.

Reference： [1]Current Patent Assignee: XIANGTAN UNIVERSITY - CN113861206, 2021, A Location in patent: Paragraph 0055-0059

18
[ 583-55-1 ]
[ 1357634-60-6 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: copper (I) iodide; tripotassium phosphate tribasic; (±)-trans-1,2-diaminocyclohexane / toluene / 4 h 2: palladium (II) [1,1'-bis(diphenylphosphanyl)ferrocene] dichloride; anhydrous potassium acetate / 1,4-dioxane / 6 h

Reference： [1]Current Patent Assignee: LT SAMBO CO LTD - US2022/106332, 2022, A1

19
[ 1357634-60-6 ]
C₅₄H₃₈N₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: tetrakis-(triphenylphosphine)-palladium; potassium carbonate / toluene; ethanol; lithium hydroxide monohydrate / 4 h 2: palladium diacetate; sodium tertiary butoxide; tri-tert-butyl phosphine / toluene / 1.5 h

Reference： [1]Current Patent Assignee: LT SAMBO CO LTD - US2022/106332, 2022, A1

20
[ 1357634-60-6 ]
[ 105946-82-5 ]
C₃₀H₂₀BrN [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
54%	With tetrakis-(triphenylphosphine)-palladium; potassium carbonate In ethanol; lithium hydroxide monohydrate; toluene for 4h;	A1-1 Synthesis of Intermediate A(1)-P1 P2 (60 g, 1 eq.), 4-bromo-4′-iodo-1,1′-biphenyl (63 g, 1.3 eq.), Pd(PPh3)4 (7.8 g, 0.05 eq.), K2CO3 (28 g, 1.5 eq.), toluene (600 ml), ethanol (100 ml) and H2O (100 ml) were introduced to a 1-neck-round bottom flask (1-neck-r.b.f), and stirred for 4 hours. (0143) The reaction solution completed with the stirring was hot filtered twice only with methylene chloride (MC) to obtain P1 (33 g). (0144) Step yield=54%

Reference： [1]Current Patent Assignee: LT SAMBO CO LTD - US2022/106332, 2022, A1 Location in patent: Paragraph 0135; 0142-0144

21
[ 591-18-4 ]
[ 1357634-60-6 ]
[ 2417210-67-2 ]

Yield	Reaction Conditions	Operation in experiment
66%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In ethanol; water; toluene at 80℃; Inert atmosphere;	8 Synthesis of Intermediate IM-15 In an Ar atmosphere, in a 1000 mL three-neck flask, 9-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-9H-carbazole (25.00 g, 67.7 mmol), 1-bromo-3-iodobenzene (19.15 g, 1.1 equiv, 67.7 mmol), K2CO3(28.07 g, 3.0 equiv, 203.1 mmol), Pd(PPh3)4(3.91 g, 0.05 equiv, 3.4 mmol), and a mixed solution of toluene/EtOH/H2O (4/2/1) (473 mL) were sequentially added and heated and stirred at about 80° C. After air-cooled to room temperature, the reaction solution was extracted with toluene. A water layer was removed, and the organic layers were washed with saturated saline and then dried over MgSO4. The compound MgSO4was filtered off and the organic layers were concentrated, and then the resulting crude product was purified by silica gel column chromatography (using a mixed solvent of hexane and toluene as an eluent) to obtain Intermediate IM-15 (17.80 g, yield 66%).By measuring FAB-MS, a mass number of m/z=398 was observed by molecular ion peak, thereby identifying Intermediate IM-15.
66 %	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In ethanol; water; toluene at 80℃; Inert atmosphere;	8 Synthesis of Intermediate IM-15 In an Ar atmosphere, in a 1000 mL three-neck flask, 9-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-9H-carbazole (25.00 g, 67.7 mmol), 1-bromo-3-iodobenzene (19.15 g, 1.1 equiv, 67.7 mmol), K2CO3(28.07 g, 3.0 equiv, 203.1 mmol), Pd(PPh3)4(3.91 g, 0.05 equiv, 3.4 mmol), and a mixed solution of toluene/EtOH/H2O (4/2/1) (473 mL) were sequentially added and heated and stirred at about 80° C. After air-cooled to room temperature, the reaction solution was extracted with toluene. A water layer was removed, and the organic layers were washed with saturated saline and then dried over MgSO4. The compound MgSO4was filtered off and the organic layers were concentrated, and then the resulting crude product was purified by silica gel column chromatography (using a mixed solvent of hexane and toluene as an eluent) to obtain Intermediate IM-15 (17.80 g, yield 66%).By measuring FAB-MS, a mass number of m/z=398 was observed by molecular ion peak, thereby identifying Intermediate IM-15.
66 %	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In ethanol; water; toluene at 80℃; Inert atmosphere;	8 Synthesis of Intermediate IM-15 In an Ar atmosphere, in a 1000 mL three-neck flask, 9-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-9H-carbazole (25.00 g, 67.7 mmol), 1-bromo-3-iodobenzene (19.15 g, 1.1 equiv, 67.7 mmol), K2CO3(28.07 g, 3.0 equiv, 203.1 mmol), Pd(PPh3)4(3.91 g, 0.05 equiv, 3.4 mmol), and a mixed solution of toluene/EtOH/H2O (4/2/1) (473 mL) were sequentially added and heated and stirred at about 80° C. After air-cooled to room temperature, the reaction solution was extracted with toluene. A water layer was removed, and the organic layers were washed with saturated saline and then dried over MgSO4. The compound MgSO4was filtered off and the organic layers were concentrated, and then the resulting crude product was purified by silica gel column chromatography (using a mixed solvent of hexane and toluene as an eluent) to obtain Intermediate IM-15 (17.80 g, yield 66%).By measuring FAB-MS, a mass number of m/z=398 was observed by molecular ion peak, thereby identifying Intermediate IM-15.

Reference： [1]Current Patent Assignee: SAMSUNG ELECTRONICS CO.,LTD.; Samsung Display (in: Samsung) - US2022/310934, 2022, A1 Location in patent: Paragraph 0313-0315
[2]Current Patent Assignee: SAMSUNG ELECTRONICS CO.,LTD.; Samsung Display (in: Samsung) - US2022/310934, 2022, A1 Location in patent: Paragraph 0313-0315
[3]Current Patent Assignee: SAMSUNG ELECTRONICS CO.,LTD.; Samsung Display (in: Samsung) - US2022/310934, 2022, A1 Location in patent: Paragraph 0313-0315

22
[ 1357634-60-6 ]
[ 2417210-68-3 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; ethanol; water / 80 °C / Inert atmosphere 2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / Inert atmosphere; Reflux

Reference： [1]Current Patent Assignee: SAMSUNG ELECTRONICS CO.,LTD.; Samsung Display (in: Samsung) - US2022/310934, 2022, A1

23
[ 1357634-60-6 ]
[ 2839715-21-6 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; ethanol; water / 80 °C / Inert atmosphere 2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / Inert atmosphere; Reflux 3: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; ethanol; water / 80 °C / Inert atmosphere

Reference： [1]Current Patent Assignee: SAMSUNG ELECTRONICS CO.,LTD.; Samsung Display (in: Samsung) - US2022/310934, 2022, A1

24
[ 1357634-60-6 ]
[ 2248674-24-8 ]
[ 2641838-84-6 ]

Yield	Reaction Conditions	Operation in experiment
	With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate Inert atmosphere; Heating;

Reference： [1]Lin, Yu Hsuan; Lin, Wei-Han; Huang, Yi-Sheng; Wu, Chen-Hsun; Gnanasekaran, Premkumar; Chang, Yi-Min; Teng, Sheng-Wei; Lu, Chin-Wei; Chang, Chih-Hao; Chang, Yuan Jay [Journal of Materials Chemistry C, 2023, vol. 11, # 8, p. 3101 - 3111]

25
[ 1357634-60-6 ]
[ 2922950-90-9 ]
[ 2922947-10-0 ]

Yield	Reaction Conditions	Operation in experiment
68 %	With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water Reflux;	45 Synthesis Example 45 im-3-13 (15 g, 24.3 mmol) and im-a-5 (9.4 g, 25.5 mmol) were added to 300 ml of THF and stirred and refluxed. Thereafter, potassium carbonate (10.1g, 72.9mmol) was dissolved in 100 ml of water, and after stirring sufficiently, bis(tri-tert-butylphosphine)palladium(0) (0.1g, 0.2mmol) was added. After reacting for 5 hours, the mixture was cooled to room temperature, and the organic layer was distilled after separating the organic layer and the water layer. This was dissolved in chloroform again, and after washing twice with water, the organic layer was separated, stirred with anhydrous magnesium sulfate, filtered, and the filtrate was distilled under reduced pressure. The concentrated compound was purified by silica gel column chromatography to prepare 13.6 g of Compound 45. (yield 68%)

Reference： [1]Current Patent Assignee: LG CHEM CO.,LTD. - KR2023/53530, 2023, A Location in patent: Paragraph 0425-0427

26
[ 1357634-60-6 ]
[ 2922950-49-8 ]
[ 2922950-43-2 ]

Yield	Reaction Conditions	Operation in experiment
64 %	With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water Reflux;	5 Synthesis Example 5 Im-1-3 (15 g, 30.9 mmol) and im-a-5 (12 g, 32.5 mmol) were added to 300 ml of THF and stirred and refluxed. Thereafter, potassium carbonate (12.8g, 92.8mmol) was dissolved in 100 ml of water, and after stirring sufficiently, bis(tri-tert-butylphosphine)palladium(0) (0.2g, 0.3mmol) was added. After reacting for 5 hours, the mixture was cooled to room temperature, and the organic layer was distilled after separating the organic layer and the water layer. This was dissolved in chloroform again, and after washing twice with water, the organic layer was separated, stirred with anhydrous magnesium sulfate, filtered, and the filtrate was distilled under reduced pressure. The concentrated compound was purified by silica gel column chromatography to prepare 13.7 g of Compound 5. (Yield 64%)

Reference： [1]Current Patent Assignee: LG CHEM CO.,LTD. - KR2023/53530, 2023, A Location in patent: Paragraph 0265-0267

27
[ 1357634-60-6 ]
[ 2922951-02-6 ]
[ 2922946-98-1 ]

Yield	Reaction Conditions	Operation in experiment
65 %	With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water Reflux;	57 Synthesis Example 57 im-4-7 (15 g, 24.3 mmol) and im-a-5 (9.4 g, 25.5 mmol) were added to 300 ml of THF and stirred and refluxed. Thereafter, potassium carbonate (10.1g, 72.9mmol) was dissolved in 100 ml of water, and after stirring sufficiently, bis(tri-tert-butylphosphine)palladium(0) (0.1g, 0.2mmol) was added. After reacting for 4 hours, the mixture was cooled to room temperature, and the organic layer and the water layer were separated and the organic layer was distilled. This was dissolved in chloroform again, and after washing twice with water, the organic layer was separated, stirred with anhydrous magnesium sulfate, filtered, and the filtrate was distilled under reduced pressure. The concentrated compound was purified by silica gel column chromatography to prepare 13 g of compound 57. (yield 65%)

Reference： [1]Current Patent Assignee: LG CHEM CO.,LTD. - KR2023/53530, 2023, A Location in patent: Paragraph 0473-0475

28
[ 1357634-60-6 ]
[ 2922951-13-9 ]
[ 2922949-66-2 ]

Yield	Reaction Conditions	Operation in experiment
66 %	With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water Reflux;	72 Synthesis Example 72 Im-5-8 (15 g, 28.6 mmol) and im-a-5 (11.1 g, 30 mmol) were added to 300 ml of THF and stirred and refluxed. Thereafter, potassium carbonate (11.8g, 85.7mmol) was dissolved in 100 ml of water, and after stirring sufficiently, bis(tri-tert-butylphosphine)palladium(0) (0.1g, 0.3mmol) was added. After reacting for 2 hours, it was cooled to room temperature, and the organic layer and the water layer were separated, and the organic layer was distilled. This was dissolved in chloroform again, and after washing twice with water, the organic layer was separated, stirred with anhydrous magnesium sulfate, filtered, and the filtrate was distilled under reduced pressure. The concentrated compound was purified by silica gel column chromatography to prepare 13.8 g of Compound 72. (yield 66%)

Reference： [1]Current Patent Assignee: LG CHEM CO.,LTD. - KR2023/53530, 2023, A Location in patent: Paragraph 0533-0535

29
[ 1357634-60-6 ]
[ 2922951-14-0 ]
[ 2922947-14-4 ]

Yield	Reaction Conditions	Operation in experiment
64 %	With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water Reflux;	73 Synthesis Example 73 Im-5-9 (15 g, 24.3 mmol) and im-a-5 (9.4 g, 25.5 mmol) were added to 300 ml of THF and stirred and refluxed. Thereafter, potassium carbonate (10.1g, 72.9mmol) was dissolved in 100 ml of water, and after stirring sufficiently, bis(tri-tert-butylphosphine)palladium(0) (0.1g, 0.2mmol) was added. After reacting for 4 hours, the mixture was cooled to room temperature, and the organic layer and the water layer were separated and the organic layer was distilled. This was dissolved in chloroform again, and after washing twice with water, the organic layer was separated, stirred with anhydrous magnesium sulfate, filtered, and the filtrate was distilled under reduced pressure. The concentrated compound was purified by silica gel column chromatography to prepare 12.8 g of Compound 73. (yield 64%)

Reference： [1]Current Patent Assignee: LG CHEM CO.,LTD. - KR2023/53530, 2023, A Location in patent: Paragraph 0537-0539

30
[ 1357634-60-6 ]
[ 2922951-25-3 ]
[ 2922950-11-4 ]

Yield	Reaction Conditions	Operation in experiment
61 %	With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water Reflux;	84 Synthesis Example 84 Im-6-6 (15 g, 28.6 mmol) and im-a-5 (11.1 g, 30 mmol) were added to 300 ml of THF and stirred and refluxed. Thereafter, potassium carbonate (11.8g, 85.7mmol) was dissolved in 100 ml of water, and after stirring sufficiently, bis(tri-tert-butylphosphine)palladium(0) (0.1g, 0.3mmol) was added. After reacting for 2 hours, it was cooled to room temperature, and the organic layer and the water layer were separated, and the organic layer was distilled. This was dissolved in chloroform again, and after washing twice with water, the organic layer was separated, stirred with anhydrous magnesium sulfate, filtered, and the filtrate was distilled under reduced pressure. The concentrated compound was purified by silica gel column chromatography to prepare 12.7 g of compound 84. (yield 61%)

Reference： [1]Current Patent Assignee: LG CHEM CO.,LTD. - KR2023/53530, 2023, A Location in patent: Paragraph 0581-0583

31
[ 1357634-60-6 ]
[ 2922951-27-5 ]
[ 2922947-03-1 ]

Yield	Reaction Conditions	Operation in experiment
69 %	With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water Reflux;	86 Synthesis Example 86 Im-6-8 (15 g, 30.9 mmol) and im-a-5 (12 g, 32.5 mmol) were added to 300 ml of THF and stirred and refluxed. Thereafter, potassium carbonate (12.8g, 92.8mmol) was dissolved in 100 ml of water, and after stirring sufficiently, bis(tri-tert-butylphosphine)palladium(0) (0.2g, 0.3mmol) was added. After reacting for 5 hours, the mixture was cooled to room temperature, and the organic layer was distilled after separating the organic layer and the water layer. This was dissolved in chloroform again, and after washing twice with water, the organic layer was separated, stirred with anhydrous magnesium sulfate, filtered, and the filtrate was distilled under reduced pressure. The concentrated compound was purified by silica gel column chromatography to prepare 14.8 g of compound 86. (yield 69%)

Reference： [1]Current Patent Assignee: LG CHEM CO.,LTD. - KR2023/53530, 2023, A Location in patent: Paragraph 0589-0591

32
[ 1357634-60-6 ]
[ 2922950-64-7 ]
[ 2922946-97-0 ]

Yield	Reaction Conditions	Operation in experiment
67 %	With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water Reflux;	20 Synthesis Example 20 Im-2-8 (15 g, 33.4 mmol) and im-a-5 (13 g, 35.1 mmol) were added to 300 ml of THF and stirred and refluxed. Thereafter, potassium carbonate (13.9g, 100.3mmol) was dissolved in 100 ml of water, and after stirring sufficiently, bis(tri-tert-butylphosphine)palladium(0) (0.2g, 0.3mmol) was added. After reacting for 3 hours, the mixture was cooled to room temperature, and the organic layer was distilled after separating the organic layer and the water layer. This was dissolved in chloroform again, and after washing twice with water, the organic layer was separated, stirred with anhydrous magnesium sulfate, filtered, and the filtrate was distilled under reduced pressure. The concentrated compound was purified by silica gel column chromatography to prepare 14.7 g of Compound 20. (Yield 67%)

Reference： [1]Current Patent Assignee: LG CHEM CO.,LTD. - KR2023/53530, 2023, A Location in patent: Paragraph 0325-0327

33
[ 1357634-60-6 ]
[ 2922950-65-8 ]
[ 2922948-92-1 ]

Yield	Reaction Conditions	Operation in experiment
72 %	With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium carbonate In tetrahydrofuran; water Reflux;	21 Synthesis Example 21 Im-2-9 (15 g, 28.6 mmol) and im-a-5 (11.1 g, 30 mmol) were added to 300 ml of THF and stirred and refluxed. Thereafter, potassium carbonate (11.8g, 85.7mmol) was dissolved in 100 ml of water, and after stirring sufficiently, bis(tri-tert-butylphosphine)palladium(0) (0.1g, 0.3mmol) was added. After reacting for 3 hours, the mixture was cooled to room temperature, and the organic layer was distilled after separating the organic layer and the water layer. This was dissolved in chloroform again, and after washing twice with water, the organic layer was separated, stirred with anhydrous magnesium sulfate, filtered, and the filtrate was distilled under reduced pressure. The concentrated compound was purified by silica gel column chromatography to prepare 15 g of Compound 21. (Yield 72%)

Reference： [1]Current Patent Assignee: LG CHEM CO.,LTD. - KR2023/53530, 2023, A Location in patent: Paragraph 0329-0331

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CAS No. :	1357634-60-6	MDL No. :	MFCD30737495
Formula :	C₂₄H₂₄BNO₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	KQQUPCGBWUTWMK-UHFFFAOYSA-N
M.W :	369.26	Pubchem ID :	129319311
Synonyms :

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H302-H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
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P103	Read label before use
Prevention
Code	Phrase
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P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
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P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
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P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
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P231 + P232	Handle under inert gas. Protect from moisture.
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Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
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P320
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P321
P322
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P331	Do NOT induce vomiting.
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P342	If experiencing respiratory symptoms:
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P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
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P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
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P411
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P413
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P422
P402 + P404	Store in a dry place. Store in a closed container.
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P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 1357634-60-6 ] {[proInfo.proName]}

Quality Control of [ 1357634-60-6 ]

Related Doc. of [ 1357634-60-6 ]

Product Details of [ 1357634-60-6 ]

Safety of [ 1357634-60-6 ]

Application In Synthesis of [ 1357634-60-6 ]

[ 1357634-60-6 ] Synthesis Path-Downstream 1~33

Related Functional Groups of
[ 1357634-60-6 ]

Organoboron

Esters

Precautionary Statements-General

Prevention

Response

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Physical hazards

Health hazards

Environmental hazards

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