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Chemical Structure| 1385826-95-8 Chemical Structure| 1385826-95-8

Structure of 1385826-95-8

Chemical Structure| 1385826-95-8

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Product Details of [ 1385826-95-8 ]

CAS No. :1385826-95-8
Formula : C39H25ClN4
M.W : 585.10
SMILES Code : ClC1=NC(C2=CC(N3C4=C(C5=C3C=CC=C5)C=CC=C4)=CC=C2)=NC(C6=CC=C(C7=CC(C8=CC=CC=C8)=CC=C7)C=C6)=N1
MDL No. :N/A
InChI Key :LNPNTLQWZHXPTQ-UHFFFAOYSA-N
Pubchem ID :89592433

Safety of [ 1385826-95-8 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 1385826-95-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1385826-95-8 ]

[ 1385826-95-8 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1133796-50-5 ]
  • [ 1385826-95-8 ]
  • [ 1402225-88-0 ]
YieldReaction ConditionsOperation in experiment
53% With potassium phosphate; tetrakis(triphenylphosphine) palladium(0); In methanol; water; toluene; for 4.0h;Inert atmosphere; Reflux; A toluene/ethanol mixture solution (2:1, 30 mL) which had undergone nitrogen bubbling was added to intermediate 4 (2.00 g, 3.41 mmol) and intermediate 7 (1.22 g, 4.44 mmol). Thereto were further added Pd(PPh3)4 (198 mg, 0.171 mmol) and an aqueous tripotassium phosphate solution (2.0 M, 5 mL) which had undergone nitrogen bubbling, in this order. Thereafter, the resultant mixture was stirred for 4 hours while heating the mixture with refluxing. After the mixture was returned to room temperature, distilled water was added thereto and the resultant mixture was extracted with toluene. The organic layer was washed with saturated aqueous sodium chloride solution and dried with magnesium sulfate. Thereafter, the solvent was distilled off under reduced pressure. The residue was purified by silica gel column chromatography using an eluent composed of hexane/methylene chloride = 2/1. Thus, compound (C-3) (1.41 g, 53%) was obtained. The results of analysis by 1H NMR spectroscopy are shown below. Analysis by differential scanning calorimetry (DSC analysis) revealed that compound (C-3) had a glass transition temperature of 103C. 1H NMR: delta [ppm] 8.49-8.44 (m, 4H), 8.34 (t, 1H), 8.19 (d, 2H), 7.84 (t, 1H), 7.71-7.19 (m, 28H), 7.08-7.05 (m, 1H), 6.99 (t, 1H).
 

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