Structure of 139102-37-7
*Storage: {[sel_prStorage]}
*Shipping: {[sel_prShipping]}
The BI-3802 was designed by Boehringer Ingelheim and could be obtained free of charge through the Boehringer Ingelheim open innovation portal opnMe.com, associated with its negative control.
4.5
*For Research Use Only !
Change View
Size | Price | VIP Price | US Stock |
Global Stock |
In Stock | ||
{[ item.pr_size ]} |
Inquiry
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price, item.pr_usd) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,1,item.pr_is_large_size_no_price, item.discount_usd) ]} {[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price, item.pr_usd) ]} |
Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]} | Inquiry {[ item.pr_usastock ]} In Stock Inquiry - | {[ item.pr_chinastock ]} {[ item.pr_remark ]} In Stock 1-2 weeks - Inquiry - | Login | - + | Inquiry |
Please Login or Create an Account to: See VIP prices and availability
US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days
1-2weeks
Inquiry
{[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price, item.pr_usd) ]}
{[ getRatePrice(item.pr_usd,1,item.mem_rate,item.pr_is_large_size_no_price, item.pr_usd) ]}
Inquiry
{[ getRatePrice(item.pr_usd,item.pr_rate,1,item.pr_is_large_size_no_price, item.vip_usd) ]}
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price, item.pr_usd) ]}
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price, item.pr_usd) ]}
In Stock
- +
Please Login or Create an Account to: See VIP prices and availability
US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
CAS No. : | 139102-37-7 |
Formula : | C8H7IO2 |
M.W : | 262.04 |
SMILES Code : | O=CC1=CC=C(I)C=C1OC |
MDL No. : | MFCD20924440 |
InChI Key : | ZDNOHFJWXJKIJF-UHFFFAOYSA-N |
Pubchem ID : | 15128239 |
GHS Pictogram: |
![]() |
Signal Word: | Warning |
Hazard Statements: | H302 |
Precautionary Statements: | P261-P280-P305+P351+P338-P304+P340 |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
46% | With 18-crown-6 ether; copper; potassium carbonate; In 1,2-dichloro-benzene; at 200℃; for 0.333333h;Microwave irradiation; | To a magnetically stirred solution of carbazole (0.89 mmol)i n 1 , 2 - d i c h l o r o be n z ene ( 0 . 2 ml ) 4 - i o do- 2 -methoxybenzaldehyde 3 (0.89 mmol), K2CO3 (2.67 mmol),Cu (0.44 mmol) and 18-crown-6 (1.78 mmol) were added in10 ml microwave tube. The mixture was degassed with nitrogenfor about 30 min and then heated at 200 C for 20 min inthe microwave. The temperature of the reaction mixture wasbrought down, filtered and evaporated giving a brown oil which was treated with hexane and left overnight with constant magneticstirring to elute impurities. The hexane layer wasdiscarded and the residue was purified by column using hexane:ethyl acetate (10:1) as an eluent. Yield 46%. Mp. 138-140 C.1H NMR (500 MHz, CdCl3) δ 10.51 (s, 1H), 8.14 (d, J =7.7 Hz, 2H), 8.07 (d, J = 8.2Hz, 1H), 7.52 (d, J = 8.2 Hz, 2H),7.45-7.42 (m, 2H), 7.34-7.30 (m, 2H), 7.29 (dd, J = 8.2,1.2 Hz, 1H), 7.23 (d, J = 1.7 Hz, 1H), 3.96 (s, 3H).13C NMR (126 MHz, CdCl3) δ 188.66, 162.90, 144.68,140.02, 130.21, 126.27, 123.90, 123.39, 120.72, 120.49,118.73, 109.89, 109.67, 56.02. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
40% | With sodium carbonate; In acetone; for 12h;Inert atmosphere; Reflux; | Under nitrogen, <strong>[38170-02-4]2-hydroxy-4-iodobenzaldehyde</strong>(0.093 mmol) and sodium carbonate (2.8 mmol) were takenin RB flask with acetone to it DMS (1.8 mmol) was added.The reaction mixture was refluxed for 12 h. After completionof reaction, sodium carbonate was filtered out. The remainingsolution was concentrated on rota evaporator. Yield: 40%.Mp. 84-86 C. 1H NMR (500 MHz, CdCl3) delta 10.41 (s, 1H), 7.51 (d, J =8.1 Hz, 1H), 7.42 (ddd, J = 8.2, 1.3, 0.7 Hz, 1H), 7.37 (d, J =1.3 Hz, 1H), 3.93 (s, 3H). |