14172-91-9|5,10,15,20-Tetraphenyl-21H,23H-porphine copper(II)| Ambeed

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Quality Control of [ 14172-91-9 ] Purity: 98% SDS Specification

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Product Details of [ 14172-91-9 ]

CAS No. :	14172-91-9
Formula :	C₄₄H₂₈CuN₄
M.W :	676.27
SMILES Code :	C1(C(C(C=C2)=[N]3C2=C(C4=CC=C5C(C6=CC=CC=C6)=C7C=C8)C9=CC=CC=C9)=C%10C=CC%11=C(C%12=CC=CC=C%12)C8=[N]7[Cu+2]3([N-]45)[N-]%10%11)=CC=CC=C1
MDL No. :	MFCD00148862

Safety of [ 14172-91-9 ]

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H302-H315-H319-H335
Precautionary Statements:	P261-P305+P351+P338

Application In Synthesis of [ 14172-91-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 14172-91-9 ]

[ 14172-91-9 ] Synthesis Path-Downstream 1~35

1
[ 917-23-7 ]
copper(II) perchlorate hexahydrate [ No CAS ]
[ 14172-91-9 ]

References: [1]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[2]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[3]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[4]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[5]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[6]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[7]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[8]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[9]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[10]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[11]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[12]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327.
[13]Journal of Physical Chemistry,1992,vol. 96,p. 1204 - 1215.

2
[ 917-23-7 ]
copper(II) choride dihydrate [ No CAS ]
[ 14172-91-9 ]

References: [1]Russian Journal of Inorganic Chemistry,2005,vol. 50,p. 1561 - 1565.

3
[ 917-23-7 ]
copper dichloride [ No CAS ]
[ 14172-91-9 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium carbonate; In water; at 350.0℃; for 0.0666667h;Inert atmosphere; Sealed tube;	Using a 50 mL volumetric flask, 1.208 g of copper sulfate as a metal salt was dissolved in 50 mL of distilled water to prepare a 0.1 mol / L CuSO 4 aqueous solution. Next, 0.02 g (3.3 × 10 -5 mol) of tetraphenylporphyrin (TPP) as a compound having a porphyrin-type skeleton, 0.02 g (3.3 × 10 -5 mol) of copper sulfate Aqueous solution of sodium carbonate and 0.032 g of sodium carbonate equivalent to copper sulfate to prevent corrosion of the reaction vessel, and the interior of the reaction vessel was purged with argon and sealed. Next, the reaction vessel was charged into the sand bath set at 350 C. The reaction temperature in the reaction vessel reached the reaction temperature in about 4 minutes.

References: [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512.
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652.
[2]Russian Journal of Coordination Chemistry,2006,vol. 32,p. 276 - 281.
[3]Kinetics and Catalysis,1989,vol. 29,p. 674 - 680.
[4]Kinetics and Catalysis,1989,vol. 29,p. 674 - 680.
[5]Kinetics and Catalysis,1989,vol. 29,p. 674 - 680.
[6]Kinetics and Catalysis,1989,vol. 29,p. 674 - 680.
[7]Patent: JP5823988,2015,B2 .Location in patent: Paragraph 0068.

4
[ 917-23-7 ]
[ 142-71-2 ]
[ 14172-91-9 ]

Yield	Reaction Conditions	Operation in experiment
400 mg	With acetic acid; In chloroform; for 2h;Reflux;	Copper tetraphenyl porphyrin was synthesised by taking tetra phenyl porphyrin[H2(TPP)]16(500mg) in chloroform(100ml).Copper(II) acetate(200mg) in glacial aceticacid(50ml) was added to the above solution andthe mixture was refluxed for 2hrs. The contents wereconcentrated to a volume of about 50-60ml andcooled to room temperature which resulted in crudecopper-tetraphenyl porphyrin Cu(TPP) (about450mg). The crude product was purified by columnchromatography using neutral alumina andchloroform as eluent. On elution the unreactedtetraphenyl porphyrin was eluted out first, followedby pure Cu(TPP). The chloroform fraction containingCu(TPP) was concentrated to obtain pure crystalsof Cu(TPP)[2]. The formation of Cu(TPP) wasmonitored by UV-visible spectroscopy which givepeaks-around 580, 541 and 417nm respectivelyconfirming the formation of Cu(TPP) (yield=400mg).

References: [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512.
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652.
[2]Thesis Clark Univ., Worcester, Mass., 1957, S. 34,.
[3]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760.
[4]Journal of the American Chemical Society,1948,vol. 70,p. 1808 - 1812.
[5]Journal of Thermal Analysis and Calorimetry,1998,vol. 54,p. 243 - 248.
[6]Russian Journal of Inorganic Chemistry,2003,vol. 48,p. 439 - 442.
[7]Journal of the American Chemical Society,1948,vol. 70,p. 1808 - 1812.
[8]Journal of Thermal Analysis and Calorimetry,1998,vol. 54,p. 243 - 248.
[9]Journal of Physics and Chemistry of Solids,1988,vol. 49,p. 315 - 322.
[10]Journal of the American Chemical Society,1951,vol. 73,p. 4315 - 4320.
[11]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760.
[12]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760.
[13]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760.
[14]Oriental Journal of Chemistry,2015,vol. 31,p. 1195 - 1200.

5
7,8-dihydro-5,10,15,20-tetraphenylporphyrin [ No CAS ]
[ 142-71-2 ]
[ 14172-91-9 ]

References: [1]Journal of Chemical Physics,1988,vol. 89,p. 6567 - 6576.

6
[ 10170-99-7 ]
[ 917-23-7 ]
[ 14172-91-9 ]

References: [1]Russian Journal of Inorganic Chemistry,2003,vol. 48,p. 439 - 442.
[2]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.

7
[ 917-23-7 ]
[ 13014-03-4 ]
[ 14172-91-9 ]

References: [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.

8
[ 917-23-7 ]
[ 45227-32-5 ]
[ 14172-91-9 ]

References: [1]Inorganic Chemistry,2001,vol. 40,p. 5636 - 5644.

9
[ 917-23-7 ]
[ 7787-70-4 ]
[ 14172-91-9 ]

References: [1]Canadian Journal of Chemistry,1990,vol. 68,p. 2234 - 2238.

10
[ 917-23-7 ]
copper(II) oxide [ No CAS ]
[ 14172-91-9 ]

References: [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512.
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652.

11
[ 917-23-7 ]
[ 12775-96-1 ]
[ 14172-91-9 ]

References: [1]Journal of Chemical Research - Part S,.
Journal of Chemical Research, Synopses,1981,p. 14 - 14.
[2]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512.
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652.

12
[ 917-23-7 ]
[ 377741-30-5 ]
[ 14172-91-9 ]

References: [1]Inorganic Chemistry,2001,vol. 40,p. 5636 - 5644.

13
[ 917-23-7 ]
[ 503276-25-3 ]
[ 14172-91-9 ]

References: [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.

14
[ 917-23-7 ]
copper(II) nitrate [ No CAS ]
[ 14172-91-9 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium carbonate; In water; at 350.0℃; for 0.0666667h;Inert atmosphere; Sealed tube;	Using a 50 mL volumetric flask, 1.208 g of copper sulfate as a metal salt was dissolved in 50 mL of distilled water to prepare a 0.1 mol / L CuSO 4 aqueous solution. Next, 0.02 g (3.3 × 10 -5 mol) of tetraphenylporphyrin (TPP) as a compound having a porphyrin-type skeleton, 0.02 g (3.3 × 10 -5 mol) of copper sulfate Aqueous solution of sodium carbonate and 0.032 g of sodium carbonate equivalent to copper sulfate to prevent corrosion of the reaction vessel, and the interior of the reaction vessel was purged with argon and sealed. Next, the reaction vessel was charged into the sand bath set at 350 C. The reaction temperature in the reaction vessel reached the reaction temperature in about 4 minutes.

References: [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512.
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652.
[2]Patent: JP5823988,2015,B2 .Location in patent: Paragraph 0068.

15
[ 917-23-7 ]
[ 6046-93-1 ]
[ 14172-91-9 ]

References: [1]Russian Chemical Bulletin,2007,vol. 56,p. 748 - 753.

16
[ 917-23-7 ]
copper(II) perchlorate [ No CAS ]
[ 14172-91-9 ]

References: [1]Helvetica Chimica Acta,1956,vol. 39,p. 2130 - 2132.
[2]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760.

17
[ 917-23-7 ]
copper(II) ethylenediaminetetraacetate [ No CAS ]
[ 14172-91-9 ]

References: [1]Russian Journal of Coordination Chemistry,2006,vol. 32,p. 529 - 533.

18
[ 917-23-7 ]
[ 15416-63-4 ]
[ 14172-91-9 ]

References: [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.
[2]Russian Journal of Inorganic Chemistry,2003,vol. 48,p. 439 - 442.

19
[ 917-23-7 ]
[ 16561-86-7 ]
[ 14172-91-9 ]

References: [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.
[2]Russian Journal of Inorganic Chemistry,2003,vol. 48,p. 439 - 442.

20
[ 917-23-7 ]
[ 31106-16-8 ]
[ 14172-91-9 ]

References: [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.

21
[ 917-23-7 ]
[ 12320-32-0 ]
[ 14172-91-9 ]

References: [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.

22
[ 917-23-7 ]
copper(II) α-nitroso-β-naphtholate [ No CAS ]
[ 14172-91-9 ]

References: [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.

23
[ 917-23-7 ]
[ 34946-82-2 ]
[ 14172-91-9 ]
Cu((C₆H₅)4C₂₀H₁₀N₄)⁽²⁺⁾ [ No CAS ]

References: [1]Polyhedron,2000,vol. 19,p. 633 - 639.

24
[ 917-23-7 ]
[ 13395-16-9 ]
[ 14172-91-9 ]

References: [1]Inorganic Chemistry,1992,vol. 31,p. 2877 - 2880.
[2]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.

25
copper(ll) sulfate pentahydrate [ No CAS ]
[ 917-23-7 ]
[ 14172-91-9 ]

References: [1]Inorganic Chemistry,1985,vol. 24,p. 3538 - 3541.

26
[ 917-23-7 ]
[ 7758-99-8 ]
[ 14172-91-9 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium carbonate; In water; at 350.0℃; for 0.0666667h;Inert atmosphere; Sealed tube;	Using a 50 mL volumetric flask, 1.208 g of copper sulfate as a metal salt was dissolved in 50 mL of distilled water to prepare a 0.1 mol / L CuSO 4 aqueous solution. Next, 0.02 g (3.3 × 10 -5 mol) of tetraphenylporphyrin (TPP) as a compound having a porphyrin-type skeleton, 0.02 g (3.3 × 10 -5 mol) of copper sulfate Aqueous solution of sodium carbonate and 0.032 g of sodium carbonate equivalent to copper sulfate to prevent corrosion of the reaction vessel, and the interior of the reaction vessel was purged with argon and sealed. Next, the reaction vessel was charged into the sand bath set at 350 C. The reaction temperature in the reaction vessel reached the reaction temperature in about 4 minutes.

27
copper(I) oxide [ No CAS ]
[ 917-23-7 ]
[ 14172-91-9 ]

References: [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512.
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652.

28
[ 917-23-7 ]
[ 91199-75-6 ]
[ 14172-91-9 ]

References: [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775.

29
[ 14172-91-9 ]
[ 68-12-2 ]
[ 71763-49-0 ]

Yield	Reaction Conditions	Operation in experiment
87%		General procedure: Under the protection of nitrogen, 0.14 mmol of the corresponding 5,10,15,20-tetrakis(4-R-phenyl)porphyrin copper(II)complex was dissolved in 16 ml of CHCl3, to which 0.75 ml of DMFwas added with magnetic stirring. The solution was cooled to 0 Cin an ice bath, and then 0.56 ml of phosphoryl chloride (POCl3) wasslowly added within 20 min. The ice bath was removed and stirringwas continued at room temperature for 1 h, and the solution wascontinuously stirred and heated at 70 C for 24 h. Then 3.606 g ofNaAc and 14.4 ml of distilled water were added in an ice bath andstirring for another 1 h. After separation of the aqueous layer, theorganic layer was washed with 10 ml of distilled water for 3 times,then dried over anhydrous magnesium sulfate and filtered. Thesolvent was removed by rotary evaporation at low temperature toafford a crude product. The crude product was dissolved indichloromethane and subjected to column chromatography overneutral alumina with dichloromethane/petroleum ether (v/v 3:1)as the eluent. The third coloured bandwas collected and the solventwas removed by rotary evaporation to afford a purple powder.

References: [1]Inorganica Chimica Acta,1980,vol. 45,p. L161 - L164.
[2]Journal of the American Chemical Society,2002,vol. 124,p. 6168 - 6179.
[3]Journal of Molecular Structure,2019,vol. 1188,p. 244 - 254.
[4]Russian Chemical Bulletin,2007,vol. 56,p. 160 - 167.

30
[ 14172-91-9 ]
[ 10544-72-6 ]
C₄₄H₂₈CuN₆O₄ [ No CAS ]

References: [1]Journal of Physics and Chemistry of Solids,1988,vol. 49,p. 315 - 322.

31
[ 71147-55-2 ]
[ 124-41-4 ]
[ 14172-91-9 ]
[ 95386-81-5 ]
[ 95386-84-8 ]

References: [1]Journal of the Chemical Society. Perkin Transactions 2 (2001),1996,vol. 1996,p. 1251 - 1260.

32
[ 71147-55-2 ]
[ 124-41-4 ]
[ 14172-91-9 ]

References: [1]Journal of the Chemical Society. Perkin Transactions 2 (2001),1996,vol. 1996,p. 1251 - 1260.

33
[ 52064-15-0 ]
[ 14172-91-9 ]

References: [1]Journal of the American Chemical Society,1946,vol. 68,p. 2278.
[2]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760.

34
[ 10380-28-6 ]
N-methyl-5,10,15,20-tetraphenylporphyrin [ No CAS ]
[ 14172-91-9 ]
C₄₅H₃₁N₄CuC₉H₆NO [ No CAS ]

References: [1]Russian Journal of General Chemistry,2000,vol. 70,p. 1299 - 1303.

35
[ 14172-91-9 ]
(5,10,15,20-tetraphenylporphyrinato)copper(II) cation radical [ No CAS ]

References: [1]Dalton Transactions,2004,p. 1703 - 1707.

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H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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CAS No.: 14172-91-9

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CAS No.: 14172-91-9

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[ 14172-91-9 ] Synthesis Path-Downstream 1~35

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