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Chemical Structure| 1550-27-2 Chemical Structure| 1550-27-2

Structure of 1550-27-2

Chemical Structure| 1550-27-2

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Product Details of [ 1550-27-2 ]

CAS No. :1550-27-2
Formula : C7H3ClF3NO4S
M.W : 289.62
SMILES Code : O=S(C1=CC=C(Cl)C([N+]([O-])=O)=C1)(C(F)(F)F)=O
MDL No. :MFCD00435125

Safety of [ 1550-27-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302
Precautionary Statements:P280-P305+P351+P338

Application In Synthesis of [ 1550-27-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1550-27-2 ]

[ 1550-27-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1550-27-2 ]
  • [ 6616-56-4 ]
  • [ 329317-49-9 ]
YieldReaction ConditionsOperation in experiment
In tetrahydrofuran; mineral oil; Example 23 3,6-Bis-(morpholin-4-ylmethyl)-2,5-bis-(2-nitro-4-trifluoromethanesulfonyl-phenoxy)-benzene (23). To a solution of <strong>[6616-56-4]2,5-bis-(morpholinomethyl)-hydroquinone</strong> (100 mg, 0.324 mmol) in THF was added sodium hydride (26 mg of 60% dispersion in mineral oil) followed by 2-nitro-4-(trifluoromethylsulfonyl)chlorobenzene (188 mg, 0.648 mmol). The mixture was stirred at room temperature for overnight. The reaction was extracted with ethyl acetate, the organic layer was washed with water and brine, dried, concentrated and purified to give the title compound. 1H NMR (300 MHz, DMSO-d6) delta 8.81 (d, J=2.2 Hz, 2H), 8.23 (m, 2H), 7.60 (s, 2H), 7.27 (m, 2H), 3.4 (m, 4H, 2*CH2), 3.06 (m, 8H, 4*CH2), 2.18 (m, 8H, 4*CH2). MS 815 [M++1].
 

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