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Chemical Structure| 15537-87-8 Chemical Structure| 15537-87-8

Structure of 15537-87-8

Chemical Structure| 15537-87-8

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Product Details of [ 15537-87-8 ]

CAS No. :15537-87-8
Formula : C14H28BrNO
M.W : 306.28
SMILES Code : O=C(NCCCCCCCCCCCC)CBr

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Application In Synthesis of [ 15537-87-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 15537-87-8 ]

[ 15537-87-8 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 4877-80-9 ]
  • [ 15537-87-8 ]
  • <i>N</i>-dodecyl-2-(3,6,7,10,11-pentakis-dodecylcarbamoylmethoxy-triphenylen-2-yloxy)-acetamide [ No CAS ]
YieldReaction ConditionsOperation in experiment
52% With potassium carbonate; In N,N-dimethyl-formamide; at 60℃; In a 100 ml double-necked flask, <strong>[4877-80-9]2,3,6,7,10,11-hexahydroxytriphenylene</strong> (300 mg, 0.92 mmol) was dissolved in dry DMF (25 ml) in a nitrogen stream. To the solution were added finely ground potassium carbonate (1.28 g, 6.0 eq.) and 1-bromoacetyldodecyl amide (1.86 g, 6.6 eq.) and the resultant mixture was stirred overnight at 60° C. There was added 200 ml of distilled water and the precipitate was collected by filtration and washed with methanol. The crude product was dissolved in chloroform and purified by column chromatography (silica gel; chloroform:methanol=10:1) to give compound 1 as white solid (800 mg/52percent). The product was identified by MALDI-TOF-MS, elemental analysis and 1H-NMR (see Table 1). MALDI-TOF-MS (CHCA): m/z 1700.05 (Calcd for [M+Na]+11715.605); Anal. Calcd for C102H174N6O12: C, 73.07; H, 10.46; N, 5.01percent. Found: C, 72.17; H, 10.21: N, 4.80percent. TABLE 1 1H-NMR(RT, CDCl3, 600MHz, TMS standard) split integral theoretical delta (J/Hz) ratio ratio assignment 0.87 t 17.8 18Ha(CH3) 1.11-1.29 m 120.5 108H b(CH3CH2) 1.54-1.58 m - 12Hc(NHCH2CH2) 3.38 q 18.0 12Hd(NHCH2) 4.75 s 14.8 12H e 6.84 s 5.4 6H f 7.79 s 6.0 6H g
 

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