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Chemical Structure| 171611-11-3 Chemical Structure| 171611-11-3

Structure of 171611-11-3

Chemical Structure| 171611-11-3

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Product Citations

Product Citations

Shahali, H ; Rahman, M Akif ; Suarez, Caleb ; Luttenberg, Summer ; Weston, Javen S ; Amiri, Ahmad

Abstract: Methyl acetate (MA) is a promising solvent due to its strong oxidative stability, low viscosity, and extremely low freezing point; however, its application is limited by poor compatibility with graphite. This study introduces a novel MA-based electrolyte with enhanced performance across a wide temperature range by modulating Li+–MA interactions through non-solvating mechanisms, thereby tailoring the solvation structure to enable low-temperature operation. The engineered electrolyte exhibits excellent compatibility with both graphite and Li-rich Nickel Manganese Cobalt (LiNMC) cathodes and remains in a stable liquid state down to −80 °C. A non-solvating fluoroether co-solvent is incorporated to compete with Li+ and partially disrupt MA solvation during graphite lithiation, enhancing desolvation efficiency and lowering desolvation energy. At optimized concentrations, this co-solvent promotes anion integration into the Li+ solvation shell, increasing the presence of free solvent molecules, contact-ion pairs (CIPs), aggregates (AGGs), and nanometric aggregates (n-AGGs). These changes reduce the band gap between LUMO and HOMO in the solvation shell, facilitating its reduction and promoting SEI formation via FSI decomposition. Consequently, LiNMC/graphite cells retain over 90 % of their initial capacity after 150 cycles at −60 °C, while LiNMC811/graphite cells deliver a record-high capacity of 149.3 mAh/g.

Keywords: Low Temperature Batteries ; Methyl Acetate ; Non-solvating interactions ; Desolvation energy ; Fluoroether co-solvent

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Product Details of [ 171611-11-3 ]

CAS No. :171611-11-3
Formula : F2LiNO4S2
M.W : 187.07
SMILES Code : O=S([N-]S(=O)(F)=O)(F)=O.[Li+]
MDL No. :MFCD28126786
InChI Key :VDVLPSWVDYJFRW-UHFFFAOYSA-N
Pubchem ID :86277430

Safety of [ 171611-11-3 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314
Precautionary Statements:P280-P305+P351+P338-P310
Class:8
UN#:1759
Packing Group:
 

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