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Chemical Structure| 175694-99-2 Chemical Structure| 175694-99-2

Structure of 175694-99-2

Chemical Structure| 175694-99-2

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Product Details of [ 175694-99-2 ]

CAS No. :175694-99-2
Formula : C8H7NS
M.W : 149.21
SMILES Code : CSC1=CC=CC=C1[N+]#[C-]

Safety of [ 175694-99-2 ]

Application In Synthesis of [ 175694-99-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 175694-99-2 ]

[ 175694-99-2 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 15754-51-5 ]
  • [ 175694-99-2 ]
  • benzo[d]thiazol-2-ylbis(4-methoxyphenyl)phosphine oxide [ No CAS ]
YieldReaction ConditionsOperation in experiment
83% With oxygen; Rose Bengal lactone; In dimethyl sulfoxide; at 20℃; for 13h;Inert atmosphere; Irradiation; Green chemistry; General procedure: To a reaction tube equipped with a magnetic stir bar was charged with 1a (0.15 mmol), 2a (0.30 mmol), Rose Bengal (1 mol%) and DMSO (1.5 mL). The solution was stirred at room temperature with the irradiation of a 23 W white LED for 13 h. After the reaction was completed, the resulting mixture was extracted with ethyl acetate (20 mL×3). The combined organic extracts were dried over MgSO4 and concentrated under reduced pressure. The residue was puri-fied by flash chromatography on silica gel (eluant: petrole-um ether/ethyl acetate = 4:1 to 2:1, V/V) to obtain the desired pure product.
  • 2
  • [ 30309-80-9 ]
  • [ 175694-99-2 ]
  • benzo[d]thiazol-2-yldi-o-tolylphosphine oxide [ No CAS ]
YieldReaction ConditionsOperation in experiment
71% With oxygen; Rose Bengal lactone; In dimethyl sulfoxide; at 20℃; for 13h;Inert atmosphere; Irradiation; Green chemistry; General procedure: To a reaction tube equipped with a magnetic stir bar was charged with 1a (0.15 mmol), 2a (0.30 mmol), Rose Bengal (1 mol%) and DMSO (1.5 mL). The solution was stirred at room temperature with the irradiation of a 23 W white LED for 13 h. After the reaction was completed, the resulting mixture was extracted with ethyl acetate (20 mL×3). The combined organic extracts were dried over MgSO4 and concentrated under reduced pressure. The residue was puri-fied by flash chromatography on silica gel (eluant: petrole-um ether/ethyl acetate = 4:1 to 2:1, V/V) to obtain the desired pure product.
  • 3
  • [ 5720-05-8 ]
  • [ 175694-99-2 ]
  • [ 16112-21-3 ]
  • 4
  • [ 80041-89-0 ]
  • [ 175694-99-2 ]
  • [ 17626-86-7 ]
 

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