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Chemical Structure| 183619-13-8 Chemical Structure| 183619-13-8

Structure of 183619-13-8

Chemical Structure| 183619-13-8

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Product Details of [ 183619-13-8 ]

CAS No. :183619-13-8
Formula : C11H7Br2N
M.W : 312.99
SMILES Code : BrC1=CC=C(C2=NC=C(Br)C=C2)C=C1
MDL No. :MFCD18909520
InChI Key :YDCKPVSNPLMYRB-UHFFFAOYSA-N
Pubchem ID :20870828

Safety of [ 183619-13-8 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 183619-13-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 183619-13-8 ]

[ 183619-13-8 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 183619-13-8 ]
  • [ 121554-09-4 ]
  • C39H49NO2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate; In 1,2-dimethoxyethane; water;Reflux; Suzuki coupling reaction of 5-bromo-2-iodopyridine (11) with (4-bromophenyl)boronic acid, using Pd(PPh3)4 as the catalyst, afforded compound (12) in moderate yield. 5-Bromo-2-(4- bromophenyl)pyridine (12) was then converted to compound (13) by Suzuki coupling with (4- (octyloxy)phenyl)boronic acid, which was followed by octyloxy deprotection using BBr3 to afford the corresponding bis-phenol (14). The cross-linking group was attached to compound(14) via Wlliamson-ether reaction in refluxing butanone using potassium carbonate as the base with 8-bromo-1-vinyloxy octane to yield compound (15). Subsequent cyclometalation of 15 using K2PtCI4 in 2-ethoxyethanol at 80 C afforded DIMER-3 that was converted to the cross-linkable acac phosphor Pt(3-ph-4-ph)-(2-ppy)(acac) using acetylacetone and sodium carbonate in 2-ethoxyethanol at 100 00.
 

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