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Chemical Structure| 19333-10-9 Chemical Structure| 19333-10-9

Structure of 19333-10-9

Chemical Structure| 19333-10-9

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Product Details of [ 19333-10-9 ]

CAS No. :19333-10-9
Formula : C32H16Cl2N8Si
M.W : 611.51
SMILES Code : [Cl-][Si+4]123([N-]4C5=C6C(C=CC=C6)=C4N=C7[N]1=C(C8=CC=CC=C78)N=C9[N-]2C(C%10=CC=CC=C9%10)=NC%11=[N]3C(C%12=CC=CC=C%11%12)=N5)[Cl-]
MDL No. :MFCD00010723

Safety of [ 19333-10-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501

Application In Synthesis of [ 19333-10-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 19333-10-9 ]

[ 19333-10-9 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 94-26-8 ]
  • [ 19333-10-9 ]
  • C54H42N8O6Si [ No CAS ]
YieldReaction ConditionsOperation in experiment
13.5% With pyridine; In toluene; for 48h;Reflux; General procedure: Silicon(IV) phthalocyanine dichloride (0.5 g, 0.82 mmol), ethyl-4-hydroxybenzoate (1.36 g, 8.18 mmol) and 2 mL dry pyridine in 50 mL dry toluene was refluxed for two days.After evaporation of the solvent in vacuo the residue was dissolved in CH2Cl2 and it was purified by preparative thin layer chromatography on silica gel plates using CH2Cl2/EtOH (50:1)as eluent to give desired product.
  • 2
  • [ 3386-18-3 ]
  • [ 19333-10-9 ]
  • C68H90N8O20Si [ No CAS ]
YieldReaction ConditionsOperation in experiment
14% With sodium hydride; In toluene;Inert atmosphere; Reflux; Under a nitrogen atmosphere, dichlorosilicate phthalocyanine (100 mg, 0.164 mmol),PEG400 (1.640 to 3.280 mmol, preferably 1.64 mmol)And NaH (0.01 to 0.222 mmol, preferably 0.016 mmol) were added to toluene 7 to 15 ml (preferably 10 ml)Reflux for 12 to 24 hours (preferably 18 hours).The solvent was removed by vacuum rotary evaporation, washed with water to give the crude blue product. The crude product was purified by silica gel column using a trichloromethane: ethanol (10: 1) as eluent to collect the second fractions and concentrated to dryness to give the blue product in 14.00% yield. The maximum absorption peak of the product in DMF was located at 672 nm and the maximum absorption wavelength in the 1% castor oil derivative (Cremophor EL, wt%) was 677 nm
  • 3
  • [ 4224-62-8 ]
  • [ 19333-10-9 ]
  • bis(6-chlorohexanoate)silicon phthalocyanine [ No CAS ]
  • 4
  • [ 4497-04-5 ]
  • [ 19333-10-9 ]
  • bis[3-(Ν-morpholine)propylester]silicon phthalocyanine [ No CAS ]
YieldReaction ConditionsOperation in experiment
43% Reflux; Inert atmosphere; Under nitrogen, silicon phthalocyanine dichloride (244.7mg, 0.4mmol), 3-(N-morpholino)propanoic acid 1.2 - 2.4mmol (preferably 2.0 mmol) were added to toluene or xylene or dioxane 20 - 50 ml (preferably toluene, 30 ml) and refluxed for 20-36 hours (preferably 24 hours). The solvent was removed by vacuum rotary evaporation, dissolved in 100 ml of dichloromethane and centrifuged The solution was extracted with water (3 x 100 ml). The organic layer was collected and then extracted with dilute hydrochloric acid (0.1 - 0.5 mmol) and the aqueous layer was collected. The aqueous layer was neutralized with 1 M sodium hydroxide, precipitated as a blue precipitate, centrifuged, washed with water and dried in vacuo to give a blue product in 43percent yield. The maximum absorption peak of the product in DMF is at 681 nm and the maximum absorption wavelength in the aqueous solution is at 691-700 nm.
 

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