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Chemical Structure| 1969-73-9 Chemical Structure| 1969-73-9

Structure of 1969-73-9

Chemical Structure| 1969-73-9

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Product Details of [ 1969-73-9 ]

CAS No. :1969-73-9
Formula : C8H7NO3
M.W : 165.15
SMILES Code : O=CCC1=CC=CC=C1[N+]([O-])=O
MDL No. :MFCD08703363
InChI Key :PFURPHRKGDQJMN-UHFFFAOYSA-N
Pubchem ID :10844764

Safety of [ 1969-73-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H312-H332
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P330-P363-P501

Application In Synthesis of [ 1969-73-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1969-73-9 ]

[ 1969-73-9 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 15121-84-3 ]
  • [ 1969-73-9 ]
YieldReaction ConditionsOperation in experiment
51% With Dess-Martin periodane; In dichloromethane; at 20℃;Inert atmosphere; Into a 500-L 4-necked round-bottom flask purged and maintained with an inert atmosphere of nitrogen, was placed a solution of 2-(2-nitrophenyl)ethan-1 -ol (300 g, 1.79 mol, 1.00 equiv) in dichloromethane (3000 ml_), Dess-Martin (837.8 g, 1 .10 equiv). The resulting solution was stirred overnight at room temperature. The reaction was then quenched by the addition of 2 L of water/ice. The pH value of the solution was adjusted to 8 with sodium carbonate. The resulting solution was extracted with 3x2 L of dichloromethane and the organic layers combined. The resulting mixture was washed with 3x1 L of sodium chloride. The mixture was dried over anhydrous sodium sulfate and concentrated under vacuum. The residue was applied onto a silica gel column with ethyl acetate/petroleum ether (1 :1 ). This resulted in 150 g (51 %) of 2-(2- nitrophenyl)acetaldehyde as yellow oil.
  • 2
  • [ 1969-73-9 ]
  • [ 347174-05-4 ]
  • ethyl 4-(cyclohexylamino)-3-(2-nitrobenzylamino)benzoate [ No CAS ]
 

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