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Chemical Structure| 20401-88-1 Chemical Structure| 20401-88-1

Structure of 20401-88-1

Chemical Structure| 20401-88-1

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Product Details of [ 20401-88-1 ]

CAS No. :20401-88-1
Formula : C10H12O2
M.W : 164.20
SMILES Code : O=CCCC1=CC=C(OC)C=C1
MDL No. :MFCD00673205
InChI Key :ZOXCMZXXNOSBHU-UHFFFAOYSA-N
Pubchem ID :11126607

Safety of [ 20401-88-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H317
Precautionary Statements:P261-P280

Application In Synthesis of [ 20401-88-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 20401-88-1 ]

[ 20401-88-1 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 15893-42-2 ]
  • [ 20401-88-1 ]
YieldReaction ConditionsOperation in experiment
44% With iron(II) oxide; tris(2,4,6-trimethoxyphenyl)phosphine; phenylsilane; In toluene; at 60℃; for 2h;Inert atmosphere; Schlenk technique; General procedure: A typical procedure for the iron oxide catalyzed reduction of 3-phenylpropionyl chloride (1a) with H3SiPh (Table1 , entry 1): iron oxide (3.6mg, 0.050mmol) and TMPP (6.7mg, 0.013mmol) were added to a 10mL Schlenk flask with a magnetic stir bar. The flask was evacuated and backfilled with argon three times. Then, H3SiPh (34μL, 0.28mmol) was added to the flask and the reaction mixture was stirred at 60C for 20h under an argon atmosphere. Then, toluene (0.50mL) was added to the flask and the resultant solution was stirred at room temperature for 5min before 1a (37μL, 0.25mmol) was loaded. Further, the reaction mixture was stirred at 60C for 20h under an argon atmosphere. After cooling to room temperature, the reaction mixture was diluted with diethyl ether (5.0mL) and tetradecane (50μL, 0.19mmol) as an internal standard was added. The yield of 3-phenylpropanal (2a; 57%) was analyzed by gas chromatography. 2a was isolated by silica gel column chromatography (hexane: EtOAc=13: 1). Pale yellow oil (16.8mg) was obtained in 50% yield.
  • 2
  • [ 20401-88-1 ]
  • [ 2605-68-7 ]
  • (E)-methyl 5-(4-methoxyphenyl)-2-methylpent-2-enoate [ No CAS ]
  • 3
  • [ 20401-88-1 ]
  • [ 4654-08-4 ]
 

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