Alternatived Products of [ 213453-08-8 ]
Product Details of [ 213453-08-8 ]
CAS No. : | 213453-08-8 |
MDL No. : | MFCD18785732 |
Formula : |
C10H15BrO4
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | QXDYJUSFCUKOQD-UHFFFAOYSA-N |
M.W : |
279.13
|
Pubchem ID : | 21216988 |
Synonyms : |
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Safety of [ 213453-08-8 ]
Application In Synthesis of [ 213453-08-8 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 213453-08-8 ]
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[ 868-77-9 ]
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[ 20769-85-1 ]
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[ 213453-08-8 ]
Yield | Reaction Conditions | Operation in experiment |
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The 2-(bromoisobutyryloxy)ethyl methacrylate (BIEM, 2b) monomer was synthesized using a modified method following a previous report.4 In a typical run, HEMA (5.0 g, 0.038 mol) and triethylamine (7.8 g, 0.077 mol) were dissolved in dichloromethane (48.9 g, 0.6 mol) in a round-bottomed Schlenk flask under nitrogen. The reaction mixture was stirred at 0 C. and degassed by N2 for 45 min. α-bromoisobutyryl bromide (10.6 g, 0.046 mol) was then added drop-wise over a period of 20 min. After the reaction mixture was stirred for another 6 h at 0 C., the insoluble solids were filtered off. The filtrate was washed three times each with de-ionized water (3×50 mL), 0.5 M NaHCO3 (3×50 mL) and saturated NaCl (3×50 mL) aqueous solutions, respectively. Subsequently, MgSO4 was added to remove trace water and filtered off. The filtrate was evaporated to dryness. The final product, BIEM (2b), was further dried in a vacuum oven and its structure was confirmed by 1H NMR (FIG. 13A). |
Reference:
[1]Macromolecules,2015,vol. 48,p. 2118 - 2126
[2]Journal of the American Chemical Society,2013,vol. 135,p. 11421 - 11424
[3]Biomacromolecules,2014,vol. 15,p. 2235 - 2245
[4]Chemical Communications,2021,vol. 57,p. 399 - 402
[5]Journal of the American Chemical Society,2003,vol. 125,p. 3831 - 3838
[6]Angewandte Chemie - International Edition,2016,vol. 55,p. 4260 - 4264
Angew. Chem.,2016,vol. 128,p. 4332 - 4336,5
[7]Macromolecules,2012,vol. 45,p. 1313 - 1320
[8]Patent: US2019/231703,2019,A1 .Location in patent: Paragraph 0104
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[ 105-16-8 ]
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[ 213453-08-8 ]
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polymer, Mn 5700 and Mw/Mn 1.88 by GPC, Mn 7900 and Mw/Mn 3.90 by GPC/viscosimetry; monomer(s): 2-(diethylamino)ethyl methacrylate; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
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[ 105-16-8 ]
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[ 213453-08-8 ]
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polymer; monomer(s): 2-(2-bromoisobutyryloxy)ethyl methacrylate; 2-(diethylamino)ethyl methacrylate
[ No CAS ]
- 4
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[ 105-16-8 ]
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[ 213453-08-8 ]
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polymer, Mn 13100 and Mw/Mn 1.36 by GPC/viscosimetry, Mn 6800 and Mw/Mn 2.00 by GPC; monomer(s): 2-(2-bromoisobutyryloxy)ethyl methacrylate; 2-(diethylamino)ethyl methacrylate
[ No CAS ]
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[ 105-16-8 ]
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[ 213453-08-8 ]
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polymer, Mn 3600 and Mw/Mn 1.76 by GPC, Mn 6300 and Mw/Mn 2.75 by GPC/viscosimetry; monomer(s): 2-(diethylamino)ethyl methacrylate; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
- 6
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[ 105-16-8 ]
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[ 213453-08-8 ]
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polymer, Mn 4500 and Mw/Mn 1.58 by GPC, Mn 6200 and Mw/Mn 2.80 by GPC/viscosimetry; monomer(s): 2-(diethylamino)ethyl methacrylate; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
- 7
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[ 105-16-8 ]
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[ 213453-08-8 ]
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polymer, Mn 30100 and Mw/Mn 1.70 by GPC, Mn 35600 and Mw/Mn 1.21 by GPC/viscosimetry; monomer(s): 2-(diethylamino)ethyl methacrylate; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
- 8
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[ 213453-08-8 ]
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poly(2-(2-bromoisobutyryloxy)ethyl methacrylate), Mn 30900 and Mw/Mn 1.66 by GPC/viscosimetry, Mn 9000 and Mw/Mn 1.32 by GPC, Mn 25000 by 1H NMR; monomer(s): 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
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[ 213453-08-8 ]
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poly(2-(2-bromoisobutyryloxy)ethyl methacrylate), Mn 14800 and Mw/Mn 5.51 by GPC; monomer(s): 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
- 10
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[ 213453-08-8 ]
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poly(2-(2-bromoisobutyryloxy)ethyl methacrylate), Mn 14800 and PDI 5.51 by GPC; monomer(s): 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
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3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
[ No CAS ]
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[ 213453-08-8 ]
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polymer, branched, Mn 9800 Da by GPC, Mn 13700 Da by GPC/viscosity, PDI 1.64 by GPC, PDI 1.50 by GPC/viscosity; monomer(s): 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
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3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
[ No CAS ]
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[ 213453-08-8 ]
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polymer, branched, Mn 6300-9300 Da by GPC, Mn 17500 Da by GPC/viscosity, PDI 1.45-1.81 by GPC, PDI 2.01 by GPC/viscosity; monomer(s): 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
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3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
[ No CAS ]
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[ 213453-08-8 ]
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polymer, branched, Mn 7900 Da by GPC, Mn 17600 Da by GPC/viscosity, PDI 1.94 by GPC, PDI 2.12 by GPC/viscosity; monomer(s): 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
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3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
[ No CAS ]
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[ 213453-08-8 ]
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polymer, branched, Mn 9500 Da by GPC, Mn 18000 Da by GPC/viscosity, PDI 1.75 by GPC, PDI 1.85 by GPC/viscosity; monomer(s): 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
- 15
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3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
[ No CAS ]
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[ 213453-08-8 ]
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polymer, branched, Mn 6700-10100 Da by GPC, Mn 21000 Da by GPC/viscosity, PDI 1.51-1.53 by GPC, PDI 1.55 by GPC/viscosity; monomer(s): 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
- 16
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3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
[ No CAS ]
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[ 213453-08-8 ]
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polymer, branched, Mn 7700-11100 Da by GPC, Mn 23300 Da by GPC/viscosity, PDI 1.43-1.53 by GPC, PDI 1.57 by GPC/viscosity; monomer(s): 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
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3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
[ No CAS ]
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[ 213453-08-8 ]
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polymer, branched, Mn 15400 Da by GPC, Mn 29800 Da by GPC/viscosity, PDI 1.44 by GPC, PDI 1.71 by GPC/viscosity; monomer(s): 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose; 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
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[ 213453-08-8 ]
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poly(2-(2-bromoisobutyryloxy)ethyl methacrylate); monomer(s): 2-(2-bromoisobutyryloxy)ethyl methacrylate
[ No CAS ]
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[ 868-77-9 ]
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[ 33693-78-6 ]
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[ 213453-08-8 ]