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Chemical Structure| 2223-95-2 Chemical Structure| 2223-95-2

Structure of 2223-95-2

Chemical Structure| 2223-95-2

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Product Citations

Product Citations

Shults, Andrey A. ; Lu, Guanyu ; Caldwell, Joshua D. ; Macdonald, Janet E. ;

Abstract: Techniques are well established for the control of nanoparticle shape and size in colloidal synthesis, but very little is understood about precursor interactions and their effects on the resultant crystalline phase. Here we show that oleate, a surface stabilizing ligand that is ubiquitous in nanocrystal synthesis, plays a large role in the mechanism of phase selection of various metal sulfide nanoparticles when thiourea is used as the sulfur source. Gas and solid-phase FTIR, 13C, and 1H NMR studies revealed that oleate and thiourea interact to produce oleamide which promotes the isomeric shift of thiourea into ammonium thiocyanate, a less reactive sulfur reagent. Because of these sulfur sequestering reactions, sulfur deficient and metastable nanoparticles are produced, a trend seen across four different metals: copper, iron, nickel, and cobalt. At low carboxylate concentrations, powder XRD indicated that the following phases formed: covellite (CuS); vaesite (NiS2); smythite (FeS1.3), greigite (FeS1.3), marcasite (FeS2) and pyrite (FeS2); and cattierite (CoS2). At high sodium oleate concentration, these phases formed: digenite (CuS0.55), nickel sulfide (NiS), pyrrhotite (FeS1.1), and jaipurite (CoS).

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Product Details of [ 2223-95-2 ]

CAS No. :2223-95-2
Formula : C36H70NiO4
M.W : 625.63
SMILES Code : CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.[Ni+2]
MDL No. :MFCD00054344
InChI Key :JMWUYEFBFUCSAK-UHFFFAOYSA-L
Pubchem ID :160624

Safety of [ 2223-95-2 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302-H319-H372-H410
Precautionary Statements:P501-P273-P260-P270-P264-P280-P391-P314-P337+P313-P305+P351+P338-P301+P312+P330
Class:9
UN#:3077
Packing Group:

Application In Synthesis of [ 2223-95-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2223-95-2 ]

[ 2223-95-2 ] Synthesis Path-Downstream   1~21

YieldReaction ConditionsOperation in experiment
...iazole; 2,2'-methylene-bis[4-(1,1,3,3-tetramethylbutyl)-6-(2N-benzotriazol-2-yl)phenol]; a condensation product of methyl-3-[3-t-butyl-5-(2H-benzotriazol-2-yl)-4-hydroxyphenyl] propionate and polyethylene glycol; and 2-(2-hydroxyphenyl)benzotriazole copolymer. Hydroxybenzoate photostabilizers ... Calcium, barium, cadmium, lead or nickel stearate, and calcium, cadmium, barium or ...
  • 2
  • [ 6018-89-9 ]
  • [ 57-11-4 ]
  • [ 2223-95-2 ]
  • 3
  • nickel(II) isopropoxide [ No CAS ]
  • [ 57-11-4 ]
  • [ 2223-95-2 ]
  • 4
  • nickel diacetate [ No CAS ]
  • [ 57-11-4 ]
  • [ 2223-95-2 ]
  • 5
  • nickel methanolate [ No CAS ]
  • [ 57-11-4 ]
  • [ 2223-95-2 ]
  • 6
  • [ 57-11-4 ]
  • nickel dichloride [ No CAS ]
  • [ 2223-95-2 ]
  • 8
  • [ 2223-95-2 ]
  • [ 107-15-3 ]
  • Ni(2+)*2C17H35CO2(1-)*4NH2C2H4NH2=Ni(C17H35CO2)2*4NH2C2H4NH2 [ No CAS ]
  • 10
  • [ 107-10-8 ]
  • [ 2223-95-2 ]
  • Ni(2+)*2C17H35CO2(1-)*2C3H7NH2=Ni(C17H35CO2)2*2C3H7NH2 [ No CAS ]
  • 11
  • [ 111-68-2 ]
  • [ 2223-95-2 ]
  • Ni(2+)*2C17H35CO2(1-)*2C7H15NH2=Ni(C17H35CO2)2*2C7H15NH2 [ No CAS ]
  • 12
  • [ 110-86-1 ]
  • [ 2223-95-2 ]
  • Ni(C17H35CO2)2 * 2 pyridine [ No CAS ]
  • 14
  • [ 119-65-3 ]
  • [ 2223-95-2 ]
  • {Ni(C18H35O2)2*(C9H7N)2} [ No CAS ]
  • 15
  • [ 2223-95-2 ]
  • [ 100-46-9 ]
  • Ni(2+)*2C17H35CO2(1-)*2C6H5CH2NH2=Ni(C17H35CO2)2*2C6H5CH2NH2 [ No CAS ]
  • 16
  • [ 7664-41-7 ]
  • [ 2223-95-2 ]
  • Ni(2+)*2C17H35CO2(1-)*4NH3=Ni(C17H35CO2)2*4NH3 [ No CAS ]
  • 17
  • [ 2223-95-2 ]
  • [ 75-04-7 ]
  • Ni(2+)*2C17H35CO2(1-)*3C2H5NH2=Ni(C17H35CO2)2*3C2H5NH2 [ No CAS ]
  • 18
  • [ 2223-95-2 ]
  • Ni(2+)*2C17H35COO(1-)*CH3OH=Ni(OOCC17H35)2*CH3OH [ No CAS ]
  • 19
  • [ 2223-95-2 ]
  • [ 557-05-1 ]
  • ZnO#dotNi [ No CAS ]
  • 20
  • nickel(II) nitrate hexahydrate [ No CAS ]
  • [ 822-16-2 ]
  • [ 2223-95-2 ]
  • 21
  • [ 2223-95-2 ]
  • [ 112-55-0 ]
  • polydymite [ No CAS ]
 

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