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Chemical Structure| 23202-47-3 Chemical Structure| 23202-47-3

Structure of 23202-47-3

Chemical Structure| 23202-47-3

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Product Details of [ 23202-47-3 ]

CAS No. :23202-47-3
Formula : C23H25NO2
M.W : 347.45
SMILES Code : OCCN(CCO)C(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
MDL No. :MFCD00156570

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Application In Synthesis of [ 23202-47-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 23202-47-3 ]

[ 23202-47-3 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 23202-47-3 ]
  • [ 3386-35-4 ]
  • [ 881742-74-1 ]
YieldReaction ConditionsOperation in experiment
83% With potassium hydroxide; In tetrahydrofuran; for 20h;Heating / reflux; N,N-Di (2-octyloxyβthyl) -N-trityl amine:To a solution of N-trityl-diethanolamine (3.0 g, 8.6 mmole) in dry THF (40 mL) under an atmosphere of nitrogen was added tosyl-n-octanol (9.8 g, 34.4 mmol) and finely ground potassium hydroxide (5.8 g, 103 mmole) . The solution was refluxed for 20 h then cooled to room temperature. The reaction mixture was diluted with EtOAc, washed twice with saturated NaCl, water and the organic EPO <DP n="39"/>phase dried and concentrated. The residue was purified by column chromatography on silica (10% EtOAc/hexanes) to give iMV-V-di (2-octyloxyethyl) -iV-trityl amine (4.92 g, 83%) . Rf 0.65 (10% EtOAc/hexanes) . 1H NMR (300 MHz, CDCl3) : δ 0.87 (6H, t, J 6.0 Hz, CH3) , 1.28 (20H, m, CH2), 1.55 (4H, m, CH2), 2.54 (4H, t, J 6.0 Hz, EtO) , 3.38 (4H, t, J 6.0 Hz, O-octyl) , 3.57 (4H, t, J 6.0 Hz, EtO), 7.10-7.60 (15H, m, trityl ArH) .
 

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