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Chemical Structure| 23277-00-1 Chemical Structure| 23277-00-1

Structure of 23277-00-1

Chemical Structure| 23277-00-1

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Product Details of [ 23277-00-1 ]

CAS No. :23277-00-1
Formula : C29H24ClP
M.W : 438.93
SMILES Code : C1([P+](C2=CC=CC=C2)(CC3=C4C=CC=CC4=CC=C3)C5=CC=CC=C5)=CC=CC=C1.[Cl-]
MDL No. :MFCD00031658
InChI Key :MOYSMPXSEXYEJV-UHFFFAOYSA-M
Pubchem ID :2734113

Safety of [ 23277-00-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313

Application In Synthesis of [ 23277-00-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 23277-00-1 ]

[ 23277-00-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 23277-00-1 ]
  • [ 54117-37-2 ]
  • (E)-9-benzyl-3-styryl-9H-carbazole [ No CAS ]
YieldReaction ConditionsOperation in experiment
88% With sodium hydride; In tetrahydrofuran;Reflux; To a suspension of <strong>[54117-37-2]9-benzyl-9H-carbazole-3-carbaldehyde</strong> (650 mg, 2.28 mmol) andbenzyltriphenylphosphonium bromide 5 (987 mg, 2.28 mmol) in 100 mL dry THF was addedsodium hydride (1 g, 41.67 mmol). The solution was refluxed overnight. During reflux, the colorchanged from white to light yellow. The residue was quenched with water. The organic phaseswere combined, dried over magnesium sulfate and the solvent removed under reduced pressure.The residue was purified by column chromatography (SiO2) using DCM:pentane 1:1 as the eluent(720 mg, 88% yield).
 

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