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Chemical Structure| 25372-09-2 Chemical Structure| 25372-09-2

Structure of 25372-09-2

Chemical Structure| 25372-09-2

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Product Details of [ 25372-09-2 ]

CAS No. :25372-09-2
Formula : C11H12N2
M.W : 172.23
SMILES Code : CC1=C(N2C=CN=C2)C(C)=CC=C1
MDL No. :MFCD15209755

Safety of [ 25372-09-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501

Application In Synthesis of [ 25372-09-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 25372-09-2 ]

[ 25372-09-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 4761-00-6 ]
  • [ 25372-09-2 ]
  • C22H27N2(1+)*Br(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
90% In acetone; at 20 - 60℃; for 4h;Inert atmosphere; To a stirred solution of 1-(2,6-Me2C6H3)imidazole (0.2 g, 1.16 mmol) in acetone (8 mL), mesitylene methyl bromide (0.29 g, 1.39 mmol) was added at room temperature, then temperature was slowly raised to 60 C stirred for 4 h then white precipitate was formed, which was filtered, washed with acetone (2 × 5 mL) to result 7 as a white solid. Yield 90% (Based on 1-(2,6-Me2C6H3)imidazole). M.p., >250 C. 1H NMR (CDCl3, 400 MHz): delta 10.49 (s, 1H, Im NCHN), 7.28-7.32 (t, 1H, Ar-H), 7.23-7.24 (d, 1H, Im-H), 7.17 (s, 1H, ImH), 7.14-7.16 (d, 2H, ArH), 6.90 (s, 2H, Mes ArH), 5.95 (s, 2H, Mes CH2-Im), 2.31 (s, 6H, Mes CH3), 2.26 (s, 3H, Mes CH3), 2.09 (s, 3H, Ar-CH3) ppm. 13C NMR (CDCl3, 100 MHz): delta 139.7, 137.9, 137.5, 134.4, 132.9, 130.9, 129.8, 129.1, 125.5, 123.1, 123, 121.5, 48.5, 20.8, 19.7, 17.5 ppm. FT-IR (neat, ?): 2967(s), 2922(s), 2859(m), 1612(m), 1547(s), 1475(s), 1449(m), 1182(s) cm-1.
 

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