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Chemical Structure| 27914-73-4 Chemical Structure| 27914-73-4

Structure of 27914-73-4

Chemical Structure| 27914-73-4

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Product Details of [ 27914-73-4 ]

CAS No. :27914-73-4
Formula : C9H7ClO3
M.W : 198.60
SMILES Code : CC(OC1=CC=C(C(Cl)=O)C=C1)=O
MDL No. :MFCD03424709
InChI Key :CGEOYYBCLBIBLG-UHFFFAOYSA-N
Pubchem ID :2756254

Safety of [ 27914-73-4 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314
Precautionary Statements:P280-P305+P351+P338-P310
Class:8
UN#:3261
Packing Group:

Application In Synthesis of [ 27914-73-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 27914-73-4 ]

[ 27914-73-4 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 27914-73-4 ]
  • [ 615-67-8 ]
  • C24H17ClO8 [ No CAS ]
YieldReaction ConditionsOperation in experiment
90% With pyridine; In 1,2-dichloro-ethane; at 20℃; for 48h;Inert atmosphere; Three-necked 500 mL round bottom flask wasequipped with magnetic stirrer, nitrogen inlet and calciumchloride guard tube. To the reaction flask, 2-chloro hydroquinone(5.78 g, 0.04 mole) and pyridine (25 mL, 0.3 mole)were added and stirred till dissolution. In another flask, 4-acetoxy benzoyl chloride (23.82 g, 0.12 mole) and 300 mLdry 1,2-dichloroethane were placed and the acid chloridesolution was added to the reaction mixture of 2-<strong>[615-67-8]chlorohydroquinone</strong>solution. This reaction mixture was stirredunder nitrogen blanket for 48 h at room temperature. Thereaction mixture was then washed sequentially with 5%sodium carbonate solution,5%hydrochloric acid and distilledwater. 1,2-Dichloroethane layer was evaporated to dryness onrotavapor. The crude product obtainedwas recrystallised fromchloroform/petroleum ether [60:80] solvent mixture and driedin vacuum oven at 80C for 4 h. Yield 90%.M. p.: 181C, IR(Nujol, cm-1): 1740 (C=O stretching), 760 (C-H bending).1HNMR(CDCl3,delta): 2.3 (s, 6H); 7.1 (m, 6H); 7.3 (d, 1H); 8.2(dd, 4H).
  • 2
  • [ 27914-73-4 ]
  • [ 2026-70-2 ]
  • C17H14F3NO3 [ No CAS ]
 

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