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[ CAS No. 27982-06-5 ] {[proInfo.proName]}

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Chemical Structure| 27982-06-5
Chemical Structure| 27982-06-5
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Product Details of [ 27982-06-5 ]

CAS No. :27982-06-5 MDL No. :MFCD00568422
Formula : C15H14O2 Boiling Point : -
Linear Structure Formula :- InChI Key :IBRIFDGHXDFGBY-UHFFFAOYSA-N
M.W : 226.27 Pubchem ID :248129
Synonyms :

Safety of [ 27982-06-5 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 27982-06-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 27982-06-5 ]

[ 27982-06-5 ] Synthesis Path-Downstream   1~51

  • 1
  • [ 109-06-8 ]
  • [ 27982-06-5 ]
  • 1-(4-ethoxy-phenyl)-1-phenyl-2-[2]pyridyl-ethanol [ No CAS ]
  • 2
  • [ 10467-10-4 ]
  • [ 27982-06-5 ]
  • 4-(1-phenyl-propenyl)-phenetole [ No CAS ]
  • 4
  • [ 27982-06-5 ]
  • [ 151-50-8 ]
  • [ 1066-33-7 ]
  • [ 86029-57-4 ]
  • 5
  • [ 27982-06-5 ]
  • phenylmagnesium bromide [ No CAS ]
  • [ 62345-22-6 ]
  • 7
  • [ 27982-06-5 ]
  • [ 35672-52-7 ]
  • 10
  • [ 27982-06-5 ]
  • [ 860564-39-2 ]
  • 11
  • [ 27982-06-5 ]
  • 4'-ethoxy-2,3',5'-trinitro-benzophenone [ No CAS ]
  • 14
  • [ 98-88-4 ]
  • [ 103-73-1 ]
  • [ 27982-06-5 ]
YieldReaction ConditionsOperation in experiment
92% With bismuth(lll) trifluoromethanesulfonate; In neat (no solvent); at 100℃; for 0.166667h;Sealed tube; Microwave irradiation; General procedure: A 10-mL pressurized glass tube with Teflon-coated septum equipped with amagnetic stirrer was charged with substrate (1 mmol), benzoyl chloride (1 mmol),and metal triflate (0.1 equiv). The tube was sealed and placed into a CEM microwaveat the temperature for the appropriate time. The reaction mixture was allowed tocool to the room temperature in the MW oven. After cooling, water (15 mL) wasadded to the mixture and the product was extracted by ethyl acetate or dichloromethane,which gave similar results (315mL). The organic layer was decanted;washed with water, aqueous NaHCO3, and brine; and dried with MgSO4. Thesolvent was then removed on a rotary evaporator and subjected to flash chromatographyon silica gel (mixture of hexane and ethyl acetate solvent to elute theproduct). The fractions containing product were concentrated and dried undervacuum to yield pure product. All products are known compounds; the purity and identityof all products were confirmed by GC-MS and 1H and 13C NMR spectroscopy.
  • 15
  • [ 98-88-4 ]
  • [ 103-73-1 ]
  • [ 27982-06-5 ]
  • [ 127154-52-3 ]
  • 16
  • [ 27982-06-5 ]
  • [ 6921-34-2 ]
  • [ 856066-40-5 ]
  • 18
  • [ 1144-74-7 ]
  • [ 141-52-6 ]
  • [ 27982-06-5 ]
  • 19
  • [ 27982-06-5 ]
  • [ 1576-35-8 ]
  • [ 100556-03-4 ]
  • 20
  • [ 611-94-9 ]
  • [ 64-17-5 ]
  • [ 27982-06-5 ]
YieldReaction ConditionsOperation in experiment
The following benzophenones and benzhydrols are representative of compounds which are useful in the practice of the present invention: ... 3-bromo-4'-chlorobenzophenone 2-n-propyl-3'-chlorobenzophenone 3,3'-dichloro-2-nitrobenzophenone 3-chloro-3'-methylbenzophenone 4-ethoxybenzophenone 3-diethylcarbamoylbenzophenone 2-hydroxy-3',5'-dichlorobenzophenone 3-trifluoromethylbenzophenone ...
  • 23
  • [ 27982-06-5 ]
  • alcoholic KOH-solution [ No CAS ]
  • [ 34979-36-7 ]
  • 24
  • [ 64-17-5 ]
  • [ 27982-06-5 ]
  • sodium [ No CAS ]
  • [ 35672-52-7 ]
  • 25
  • [ 951884-62-1 ]
  • alcoholic KOH-solution [ No CAS ]
  • [ 27982-06-5 ]
  • 26
  • 4-(1,2-dimethyl-1-phenyl-allyl)-phenetole [ No CAS ]
  • [ 64-19-7 ]
  • CrO3 [ No CAS ]
  • [ 27982-06-5 ]
  • [ 619-86-3 ]
  • 28
  • [ 27982-06-5 ]
  • 4'-methylamino-2,3',5'-trinitro-benzophenone [ No CAS ]
  • 29
  • [ 27982-06-5 ]
  • 4-methylamino-3,5,3'-trinitro-benzophenone [ No CAS ]
  • 30
  • [ 27982-06-5 ]
  • 4-(2-bromo-1-phenyl-propenyl)-phenetole [ No CAS ]
  • 35
  • [ 591-50-4 ]
  • [ 201230-82-2 ]
  • [ 22237-13-4 ]
  • [ 27982-06-5 ]
YieldReaction ConditionsOperation in experiment
With potassium carbonate; at 100℃; under 7500.75 Torr; for 8h;Autoclave; Carbonylative Suzuki coupling reactions All of the carbonylative Suzuki coupling reactions were conducted in a sealed stainless steel reaction kettle. Arylboronic acid (1.5 mmol), aryl iodide (1.0 mmol), base (3.0 mmol), 3 wt% Pd/SiC and anisole (10 mL) were added to the reaction kettle, and the resulting mixture was placed under a certain pressure of CO. All of the reactions were conducted over several hours at certain temperatures. The products of the reactions were analyzed by GC-MS on a Bruker SCION SQ 456 GC-MS system (Karlsruhe, Germany).
  • 36
  • [ 74-96-4 ]
  • [ 1137-42-4 ]
  • [ 27982-06-5 ]
YieldReaction ConditionsOperation in experiment
86% With potassium carbonate; In acetone; at 55℃; for 20h; Bromoethane (3.2 g, 30 mmol) and 4-hydroxybenzophenone (4.95 g, 25 mmol) were added to a three-necked flask,After adding 300mL of acetone,Additional potassium carbonate (4.1 g, 30 mmol)Then the temperature was raised to 55 C and stirring was continued for 20h.After the reaction was stopped cooling to room temperature,filter,The filtrate was collected,Rotary evaporation of the solvent gave the crude product,A volume ratio of 50: 1 petroleum ether and ethyl acetate mixture as eluent,SiO2 as the stationary phase,Purification by column chromatography to give 4-n-hexyloxybenzophenone 4.9g,Yield 86%.
70% With potassium carbonate; In acetone; for 12h;Reflux; Inert atmosphere; 4-Hydroxybenzophenone (4.9 g, 25 mmol), anhydrous potassium carbonate (6.9 g, 50 mmol), bromoethane (2.23 mL, 30 mmol) was added to a 250 mL two-necked flask.An appropriate amount of acetone solvent was added and refluxed for 12 hours under a nitrogen atmosphere.The reaction was completely cooled to room temperature, and an appropriate amount of dilute hydrochloric acid solution (2 mol/L) was added until no bubbles were formed.The organic phase is extracted with chloroform and combined to obtain a crude product which is purified by chromatography to obtain a pure product.The yield was 70%, and the structure was characterized by 1H-NMR and 13C-NMR to confirm that the product was a compound of Comparative Example I.
  • 37
  • [ 27982-06-5 ]
  • [ 1137-42-4 ]
  • 4-(2-(4-ethoxyphenyl)-1,2-diphenylvinyl)phenol [ No CAS ]
YieldReaction ConditionsOperation in experiment
41% With titanium tetrachloride; zinc; In tetrahydrofuran; at 0 - 70℃; for 36.5h;Inert atmosphere; A 250 mL round bottom flask was charged with 4-hydroxybenzophenone (1.9 g, 10 mmol)<strong>[27982-06-5]4-ethoxybenzophenone</strong> (2.7 g, 12 mmol),Zn powder (3.9 g, 50 mmol).After evacuating nitrogen for three times,Add 80 mL of tetrahydrofuran.After cooling to 0 C,TiCl4 (5.7 g, 25 mmol) was slowly added,Then stirred for 0.5 h.Then stirred at 70 C for 36 h,After cooling to room temperature,Add 80mL dilute hydrochloric acid (1mol / L),Adjusted to neutral,DCM extraction three times,The organic layer was collected,Dried over anhydrous magnesium sulfate,The solvent is dried to give the crude product,A volume ratio of 50: 1 petroleum ether and ethyl acetate mixture as eluent,SiO2 as the stationary phase,Column chromatography isolated white solid 0.8g,Yield 41%.
  • 38
  • [ 34979-36-7 ]
  • [ 27982-06-5 ]
YieldReaction ConditionsOperation in experiment
With perchloric acid; tetrabutylammonium bromochromate; In water; acetic acid; at 29.84℃;Kinetics; Thermodynamic data; General procedure: A thermostatic water bath was used to maintain the desired temperature within ± 0.1 C. The calculated amount of the reactants, i.e., benzhydrol (BH), TBABC, perchloric acid, acetic acid and water taken in a reaction vessel which was kept in a thermostatic water bath. After allowing sufficient time to attain the temperature of the experiment, arequisite amount of solutions were rapidly pipetted out into the spectrophotometric cell. The total volume of the reaction mixture was 5 mL in each case. Progress of the reaction was followed by measuring the decrease in [TBABC] by spectrophotometrically at 362 nm using UV-visible spectrophotometer, Shimadzu UV-1800 model. The reaction was carried under pseudo first-order conditions, i.e., [BH] >> [TBABC] in the presence of perchloric acid in 50 % acetic acid - 50 % water medium.
  • 39
  • C23H23NO3S [ No CAS ]
  • [ 27982-06-5 ]
  • 40
  • N-(p-ethoxybenzoyl)succinimide [ No CAS ]
  • [ 98-80-6 ]
  • [ 27982-06-5 ]
  • 41
  • [ 55836-71-0 ]
  • [ 27982-06-5 ]
  • 43
  • C19H27NO6 [ No CAS ]
  • [ 100-58-3 ]
  • [ 27982-06-5 ]
  • 44
  • tert-butyl (4-ethoxybenzoyl)(methyl)carbamate [ No CAS ]
  • [ 100-58-3 ]
  • [ 27982-06-5 ]
  • 45
  • [ 103095-30-3 ]
  • [ 27982-06-5 ]
  • 46
  • [ 64-17-5 ]
  • [ 134-85-0 ]
  • [ 27982-06-5 ]
  • 47
  • [ 27982-06-5 ]
  • (2,2-di-p-tolylvinyl)(4-methoxyphenyl)sulfane [ No CAS ]
  • (2,2-di-p-tolylvinyl)(4-methoxyphenyl)sulfane [ No CAS ]
  • 49
  • [ 27982-06-5 ]
  • C18H18N2O [ No CAS ]
  • 50
  • [ 27982-06-5 ]
  • 1-((4-ethoxyphenyl)(phenyl)methyl)-1H-1,2,4-triazole [ No CAS ]
  • 51
  • [ 108-01-0 ]
  • [ 1137-42-4 ]
  • [ 105-58-8 ]
  • [ 27982-06-5 ]
  • [ 51777-15-2 ]
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