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[ CAS No. 281-23-2 ]

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2D
Chemical Structure| 281-23-2
Chemical Structure| 281-23-2
Structure of 281-23-2 *Storage: {[proInfo.prStorage]}

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Product Details of [ 281-23-2 ]

CAS No. :281-23-2MDL No. :MFCD00074719
Formula : C10H16 Boiling Point : 187.1°C at 760 mmHg
Linear Structure Formula :-InChI Key :-
M.W :136.23Pubchem ID :9238
Synonyms :

Computed Properties of [ 281-23-2 ]

TPSA : 0 H-Bond Acceptor Count : 0
XLogP3 : 3.8 H-Bond Donor Count : 0
SP3 : 1.00 Rotatable Bond Count : 0

Safety of [ 281-23-2 ]

Signal Word:WarningClass:N/A
Precautionary Statements:P261-P305+P351+P338UN#:N/A
Hazard Statements:H302-H315-H319-H335Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 281-23-2 ]

  • Upstream synthesis route of [ 281-23-2 ]
  • Downstream synthetic route of [ 281-23-2 ]

[ 281-23-2 ] Synthesis Path-Upstream   1~11

  • 1
  • [ 281-23-2 ]
  • [ 39751-07-0 ]
Reference: [1] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986, p. 947 - 956
  • 2
  • [ 281-23-2 ]
  • [ 935-56-8 ]
  • [ 7346-41-0 ]
  • [ 1128-76-3 ]
  • [ 121-44-8 ]
Reference: [1] Chemistry Letters, 1998, # 11, p. 1085 - 1086
  • 3
  • [ 201230-82-2 ]
  • [ 281-23-2 ]
  • [ 39269-10-8 ]
YieldReaction ConditionsOperation in experiment
80%
Stage #1: With Al2Br7(1-)*CBr3(1+) In 1,2-dibromomethane at 0℃; for 3 h;
Stage #2: With water In 1,2-dibromomethaneCooling
At room temperature, CBr4*2AlBr3 was prepared by stirring CBr4 with AlBr3 in a molar ratio of 1-2 in anhydrous CH2Br2. Next, at 0 °C under atmospheric CO pressure, AdH (1) (1.43 mmol) was added to the freshly prepared CBr4*2AlBr3 (2.87 mmol) in CH2Br2 (3 mL). The mixture was stirred for 3 h. Then at atmospheric CO pressure, H2O (15 mL) was added carefully with cooling. The reaction mixture was kept for 1-2 d until the precipitation of 1,3-Ad(COOH)2 was complete. The Ad(COOH)2 was filtered, washed with H2O, dried, and crystallized from AcOH. The yield of analytically pure compound was 80percent with respect to 1. Mp 285-286 °C. Calcd. for C12H16O4, (percent): C, 64.27; H, 7.19. Found (percent): C, 64.21; H, 7.24.
Reference: [1] Tetrahedron Letters, 2012, vol. 53, # 27, p. 3493 - 3496
[2] Journal of Organic Chemistry, 1998, vol. 63, # 2, p. 222 - 223
[3] Journal of Organic Chemistry, 1978, vol. 43, p. 4978 - 4980
  • 4
  • [ 64-18-6 ]
  • [ 281-23-2 ]
  • [ 39269-10-8 ]
Reference: [1] Chemische Berichte, 1994, vol. 127, # 10, p. 2081 - 2088
[2] Synthetic Communications, 1984, vol. 14, # 2, p. 113 - 120
[3] Chemische Berichte, 1991, vol. 124, # 4, p. 915 - 922
  • 5
  • [ 201230-82-2 ]
  • [ 281-23-2 ]
  • [ 768-95-6 ]
  • [ 828-51-3 ]
  • [ 15897-81-1 ]
  • [ 39269-10-8 ]
Reference: [1] Journal of Organic Chemistry, 1998, vol. 63, # 2, p. 222 - 223
  • 6
  • [ 281-23-2 ]
  • [ 39269-10-8 ]
Reference: [1] Chemische Berichte, 1960, vol. 93, p. 1366 - 1371
[2] MedChemComm, 2017, vol. 8, # 1, p. 135 - 147
  • 7
  • [ 281-23-2 ]
  • [ 103-84-4 ]
  • [ 700-57-2 ]
  • [ 1459-50-3 ]
Reference: [1] Journal of Organic Chemistry USSR (English Translation), 1987, vol. 23, # 9, p. 1672 - 1675[2] Zhurnal Organicheskoi Khimii, 1987, vol. 23, # 9, p. 1882 - 1886
  • 8
  • [ 75-35-4 ]
  • [ 281-23-2 ]
  • [ 17768-28-4 ]
  • [ 17768-36-4 ]
  • [ 4942-47-6 ]
Reference: [1] Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.), 1992, vol. 41, # 7.2, p. 1244 - 1246[2] Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992, # 7, p. 1612 - 1615
[3] Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.), 1992, vol. 41, # 7.2, p. 1244 - 1246[4] Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992, # 7, p. 1612 - 1615
[5] Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.), 1992, vol. 41, # 7.2, p. 1244 - 1246[6] Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992, # 7, p. 1612 - 1615
  • 9
  • [ 281-23-2 ]
  • [ 26562-81-2 ]
Reference: [1] Russian Journal of Organic Chemistry, 2017, vol. 53, # 8, p. 1170 - 1175[2] Zh. Org. Khim., 2017, vol. 53, # 8, p. 1156 - 1161,6
  • 10
  • [ 281-23-2 ]
  • [ 131211-27-3 ]
Reference: [1] J. Gen. Chem. USSR (Engl. Transl.), 1990, vol. 60, # 8.1, p. 1603 - 1606[2] Zhurnal Obshchei Khimii, 1990, vol. 60, # 8, p. 1795 - 1799
[3] Patent: US9802185, 2017, B2,
  • 11
  • [ 281-23-2 ]
  • [ 157282-19-4 ]
Reference: [1] Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1994, vol. 49, # 6, p. 801 - 811
[2] Patent: US9802185, 2017, B2,
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