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Chemical Structure| 2829-26-7 Chemical Structure| 2829-26-7

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Chemical Structure| 2829-26-7

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Product Details of [ 2829-26-7 ]

CAS No. :2829-26-7
Formula : C13H11ClN2
M.W : 230.69
SMILES Code : ClC1=CC=C(C=C1)/C=N/NC2=CC=CC=C2
MDL No. :MFCD00018758

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Application In Synthesis of [ 2829-26-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2829-26-7 ]

[ 2829-26-7 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 71-33-0 ]
  • [ 2829-26-7 ]
  • 6-(4-{N'-[1-(4-Chloro-phenyl)-meth-(E)-ylidene]-hydrazino}-phenyl)-[1,3,5]triazinane-2,4-dione [ No CAS ]
  • 2
  • [ 120-72-9 ]
  • [ 2829-26-7 ]
  • [ 178946-89-9 ]
YieldReaction ConditionsOperation in experiment
97% With Fe+3-montmorillonite K10; for 0.0055h; General procedure: Into a mortar, substituted benzaldehyde 1(1 mmol) or substituted hydrazone 4 (1 mmol), indole2 (2 mmol, 0.28 g), and Fe+3-montmorillonite K10(0.1 g) were added. The mixture was pulverized with apestle and entered a spontaneous reaction. Theprogress of a reaction was monitored by thin-layer chromatography (TLC) using EtOAc: petroleum ether(2 : 1) as eluent. The conditions of the reaction aregiven in Table 2. After the reaction was complete, theproduct was extracted with CHCl3 (3 × 10 mL) andinsoluble catalyst was removed by filtration. Theresulting crude material was purified by recrystallizationfrom EtOH to obtain pure products. Allsynthesized compounds are unknown and were characterizedby their physical constants, comparison withauthentic samples, IR, 1H NMR, and 13C NMR spectroscopies,and by elemental analysis.3,3'-[(Phenyl)methylene]bis(1H-indole) (3a). mp122-123C, IR spectrum (KBr), nu, cm-1: 3396, 3049,2867, 1602, 1537, 1450, 1338. 1H NMR spectrum(400 MHz, CDCl3), deltaH, ppm: 5.93 s (1H), 6.73 s (2H),7.10-7.37 m (12H), 7.57-7.60 m (1H), 7.95 br.s (2H).13C NMR spectrum (100 MHz, CDCl3), deltaC, ppm: 33.7,112.1, 112.9, 116.7, 118.9, 122.2, 125.6, 127.3, 127.8,129.6, 132.8, 139.0, 146.7.
 

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