[ CAS No. 28418-89-5 ] {[proInfo.proName]}

Name: 28418-89-5|5-Iodoisobenzofuran-1,3-dione|98%
Brand: Ambeed
SKU: A217698
Rating: 99 (25 reviews)

,{[proInfo.pro_purity]}

Cat. No.: {[proInfo.prAm]}

HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type	HazMat fee for 500 gram (Estimated)
Excepted Quantity	USD 0.00
Limited Quantity	USD 15-60
Inaccessible (Haz class 6.1), Domestic	USD 80+
Inaccessible (Haz class 6.1), International	USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic	USD 100+
Accessible (Haz class 3, 4, 5 or 8), International	USD 200+

2D 3D

Structure of 28418-89-5 * Storage: {[proInfo.prStorage]}

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

For Research Only 110K+ Compounds Competitive Price 1-2 Day Shipping

Quality Control of [ 28418-89-5 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 28418-89-5 ]

SDS Specification

Alternatived Products of [ 28418-89-5 ]

Product Details of [ 28418-89-5 ]

CAS No. :	28418-89-5	MDL No. :	MFCD07437960
Formula :	C₈H₃IO₃	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	HAXOVWANMPEGGM-UHFFFAOYSA-N
M.W :	274.01	Pubchem ID :	15263377
Synonyms :

Safety of [ 28418-89-5 ]

Signal Word:	Danger	Class:	8,6.1
Precautionary Statements:	P260-P264-P270-P271-P280-P301+P330+P331-P302+P352-P303+P361+P353-P304+P340-P305+P351+P338-P310-P403+P233-P405-P501	UN#:	2923
Hazard Statements:	H301-H311-H314-H331	Packing Group:	Ⅲ
GHS Pictogram:

Application In Synthesis of [ 28418-89-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 28418-89-5 ]
Downstream synthetic route of [ 28418-89-5 ]

[ 28418-89-5 ] Synthesis Path-Upstream 1~1

1
[ 28418-89-5 ]
[ 28418-88-4 ]
[ 36978-41-3 ]

Yield	Reaction Conditions	Operation in experiment
74.15%	at 30℃; for 8 h; Inert atmosphere	General procedure: In a 1000 ml three-necked flask, 18.3 g (0.1 mol) of 4-chlorophthalic anhydride and 18.3 g (0.1 mol) were added 3-chlorophthalic anhydride, 300 g of anisole as solvent, 0.13 g (0.001 mol) of nickel chloride as a catalyst, 0.198 g (0.001 mol) of C-1 as a catalyst ligand, and 0.03 g (0.0003 mol) of sodium bromide as a catalyst Auxiliary, 13 g (0.2 mol) of zinc powder was used as a reducing agent, and the reaction was stirred at 30 ° C for 8 hours under a nitrogen atmosphere. The reaction solution was filtered to remove insoluble solids in the reaction liquid. 300 g of methanol was added to the filtration mother liquor, and the product was precipitated, filtered, and dried to obtain 25.8 g of the product 2,3,3',4'-biphenyltetracarboxylic dianhydride, yield 87.7percent. The synthesis method was the same as in Example 1, except that the types of 4-substituted phthalic anhydride and 3-substituted phthalic anhydride were changed.

Reference： [1] Patent: CN108250169, 2018, A, . Location in patent: Paragraph 0010; 0055; 0065-0067

[ 28418-89-5 ] Synthesis Path-Downstream 1~31

1
[ 28418-89-5 ]
[ 57-13-6 ]
5-iodo-1,3-dioxo-isoindoline-2-carboxylic acid amide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	at 120 - 124℃; beim Erwaermen des Reaktionsprodukts mit Phosphorylchlorid;

Reference： [1]Chaudhari; Nargund [Journal of the University of Bombay, Science: Physical Sciences, Mathematics, Biological Sciences and Medicine, 1950, vol. 19/3A, p. 60]

3
[ 28418-89-5 ]
[ 98556-60-6 ]

Yield	Reaction Conditions	Operation in experiment
	With ammonia; water

Reference： [1]Sato; Oki [Bulletin of the Chemical Society of Japan, 1957, vol. 30, p. 958,960]

4
[ 6301-60-6 ]
[ 28418-89-5 ]

Reference： [1]Journal of Materials Chemistry A,2019,vol. 7,p. 14806 - 14815
[2]Journal of Organic Chemistry,1951,vol. 16,p. 1275
[3]Journal fur praktische Chemie (Leipzig 1954),1896,vol. <2> 53,p. 383

5
[ 908094-01-9 ]
[ 67-56-1 ]
[ 28418-89-5 ]
(4-Jod-2-methoxycarbonyl-phenyl)-diazomethyl-keton [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	(i), (ii) SOCl₂, (iii) /BRN= 102415/, Et₂O; Multistep reaction;

Reference： [1]Reichel,L.; Hampel,W. [Justus Liebigs Annalen der Chemie, 1968, vol. 715, p. 159 - 163]

6
[ 908094-01-9 ]
[ 67-56-1 ]
[ 28418-89-5 ]
(5-Jod-2-methoxycarbonyl-phenyl)-diazomethyl-keton [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	(i), (ii) SOCl₂, (iii) /BRN= 102415/, Et₂O; Multistep reaction;

Reference： [1]Reichel,L.; Hampel,W. [Justus Liebigs Annalen der Chemie, 1968, vol. 715, p. 159 - 163]

7
[ 28418-89-5 ]
[ 62-53-3 ]
5-iodo-2-phenylisoindoline-1,3-dione [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With pyridine; acetic anhydride 1) N,N-dimethylacetamide, 80 deg C, 2 h; 2) N,N-dimethylacetamide, 80 deg C, 16 h; Yield given. Multistep reaction;

Reference： [1]Perry, Robert J.; Wilson, B. David [Journal of Organic Chemistry, 1996, vol. 61, # 21, p. 7482 - 7485]

Yield	Reaction Conditions	Operation in experiment
	at 115 - 130℃;

Yield	Reaction Conditions	Operation in experiment
	/BRN= 135820/;

10
[ 5326-47-6 ]
[ 28418-89-5 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: NaNO₂; aqueous H₂SO₄; CuCN / Erwaermen des Reaktionsprodukts mit wss. H₂SO₄ 2: acetic acid anhydride; benzene

Reference： [1]Higgins et al. [Journal of Organic Chemistry, 1951, vol. 16, p. 1275]

11
[ 28418-89-5 ]
[ 1443502-83-7 ]