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Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
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Chemical Structure| 31469-15-5 Chemical Structure| 31469-15-5

Structure of 31469-15-5

Chemical Structure| 31469-15-5

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Product Details of [ 31469-15-5 ]

CAS No. :31469-15-5
Formula : C8H18O2Si
M.W : 174.31
SMILES Code : C[Si](C)(OC(OC)=C(C)C)C
MDL No. :MFCD00010232
InChI Key :JNOGVQJEBGEKMG-UHFFFAOYSA-N
Pubchem ID :552336

Safety of [ 31469-15-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338
Class:3
UN#:3271
Packing Group:

Application In Synthesis of [ 31469-15-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 31469-15-5 ]
  • Downstream synthetic route of [ 31469-15-5 ]

[ 31469-15-5 ] Synthesis Path-Upstream   1~2

  • 1
  • [ 104-92-7 ]
  • [ 31469-15-5 ]
  • [ 6274-50-6 ]
References: [1] Journal of the American Chemical Society, 2003, vol. 125, # 37, p. 11176 - 11177.
[2] Journal of the American Chemical Society, 2004, vol. 126, # 16, p. 5182 - 5191.
  • 2
  • [ 43076-33-1 ]
  • [ 31469-15-5 ]
  • [ 154477-55-1 ]
YieldReaction ConditionsOperation in experiment
62% With zinc(II) fluoride; tri-tert-butyl phosphine In N,N-dimethyl-formamide at 80℃; for 2 h; EXAMPLE 8 Two grams of 3, 90 mg of P(tBu)3, 300 mg of Pd(dba)2, 250 mg of ZnF2 and 1.1 g of 5 were dissolved in 330 mL of DMF under argon. The mixture was heated to 80° for two hours, cooled to room temperature, diluted with ether and worked up as described in example 1. The resulting product was filtered through silica to provide 1.3 g (62percent) of 6.
References: [1] Patent: US2006/63808, 2006, A1, . Location in patent: Page/Page column 8; 10; 14.
 

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