There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
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CAS No. : | 33375-06-3 | MDL No. : | MFCD00063015 |
Formula : | C9H9NO | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | JJSCUXAFAJEQGB-MRVPVSSYSA-N |
M.W : | 147.17 | Pubchem ID : | 7018262 |
Synonyms : |
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Signal Word: | Danger | Class: | 6.1 |
Precautionary Statements: | P233-P260-P261-P264-P270-P271-P280-P301+P310-P302+P352-P304-P304+P340-P305+P351+P338-P312-P321-P322-P330-P332+P313-P337+P313-P340-P361-P362-P363-P403-P403+P233-P405-P501 | UN#: | 2206 |
Hazard Statements: | H301-H311-H315-H319-H335 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In toluene 1.) 2 h, 100 deg C, MeOH, 2 h, reflux; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In dichloromethane at 20℃; for 0.333333h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
87% | In toluene at 80℃; for 2h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Stage #1: Pargyline; C36H29IN2O6 With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In N,N-dimethyl-formamide at 20℃; for 72h; Stage #2: 4-morpholino-4-yl-phenylamine With benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In dichloromethane; N,N-dimethyl-formamide at 20℃; for 24h; Stage #3: (1R)-1-phenylethyl isocyanate With dmap; triethylamine In tetrahydrofuran at 20℃; for 48h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
54% | In 1-methyl-pyrrolidin-2-one; at 150℃; for 0.333333h; | COMPOUND lah(R)-l-(l-Phenylethyl)-3-(4-(pyridin-4-yl)thiazol-2-yl)urea. This was prepared from 3a (0.126 g, 0.711 mmol) and (R)-(+)-alpha-methylbenzyl isocyanate (0.209 g, 1.42 mmol) in the same manner as described for laa. Chromatography on silica gel performed twice using the FlashMaster 3 purification station, afforded lah as a white solid (0.125 g, 0.385 mmol, 54%). 1H NMR (400 MHz, DMSO-d6) delta 10.51 (s, 1H), 8.56 (d, J= 5.8 Hz, 2H), 7.80 (s, 1H), 7.76 (d, J= 6.0 Hz, 2H), 7.36-7.31 (m, 4H), 7.26-7.24 (m, 1H), 7.02 (d, J = 7.7 Hz, 1H), 4.84 (quint, J= 7.3 Hz, 1H), 1.40 (d, J= 6.9 Hz, 6H); 13C NMR (400 MHz, DMSO-d6) delta 160.80, 153.72, 150.84, 146.77, 145.01, 141.64, 129.14, 127.61, 126.47, 120.48, 1 1 1.71 , 49.71 , 23.54; HPLC purity 99.22% {tR = 7.907 min, Flow lml/min,[(CH3CN/(0.1% TFA in H2O):30/70] ; purity 99.51% {tR = 8.653 min, Flow lml/min, [(MeOH/(0.1% TFA in H2O):50/50] ; HRMS (ESI +ve) m z calculated for C17H17N4OS (M + H)+ 3251 1 17, found 325.1 1 16.The enantiomeric excess was determined by HPLC using a Chiralcel OJ column[(/so-propanol/Hexane:50/50), Flow lml/min], tRi = 9.067 min, Area %> 0.404 (minor), 14.300 min, Area % 98.378 (major). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
at 20℃; for 1.5h; |