Home Cart Sign in  
Chemical Structure| 3354-82-3 Chemical Structure| 3354-82-3

Structure of 3354-82-3

Chemical Structure| 3354-82-3

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 3354-82-3 ]

CAS No. :3354-82-3
Formula : C6H3Br3O3
M.W : 362.80
SMILES Code : OC1=C(C(O)=C(C(O)=C1Br)Br)Br
MDL No. :MFCD01706660
InChI Key :FVXWNUUQRAHIRN-UHFFFAOYSA-N
Pubchem ID :76885

Safety of [ 3354-82-3 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H312-H332
Precautionary Statements:P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P330-P362-P403+P233-P501

Application In Synthesis of [ 3354-82-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3354-82-3 ]

[ 3354-82-3 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 108-73-6 ]
  • [ 3354-82-3 ]
  • [ 6099-90-7 ]
  • [ 814-68-6 ]
  • [ 217825-79-1 ]
YieldReaction ConditionsOperation in experiment
With bromine; triethylamine; In n-heptane; dichloromethane; acetone; acetonitrile; Example 18 Preparation of tribromophloroglucinol triacrylate (Compound XXIV) <strong>[6099-90-7]Phloroglucinol dihydrate</strong> (10 g) was suspended in 150 mL of dichloromethane and bromine (12 mL in 50 mL of dichloromethane) was added dropwise over 2.5 hour period to the stirred suspension. The suspended phloroglucinol dissolved during the course of the bromine addition. After stirring for an additional 2 hours a two-phase solution was obtained. The pale orange dichloromethane supernatant solution was decanted from a small amount of a denser, dark red aqueous solution. The dichloromethane solution was rotary evaporated to a pinkish colored semicrystalline solid. The solid was dissolved in a 50 mL of acetone and 500 mL of heptane was slowly added with stirring to give beige crystals of tribromophloroglucinol (18.8 g, 84%). Ten grams of tribromophloroglucinol was dissolved in 150 mL of acetonitrile and the mixture was cooled to 0 C. Acryloyl chloride (8 mL) was added and the mixture was magnetically stirred. Triethyl amine (13 mL) was then added in a dropwise fashion and the reaction was maintained at 0 C. A precipitate formed upon addition of triethyl amine. After the triethyl amine addition, the reaction was stirred for one hour at 0 C. and 2 hours at room temperature. The reaction mixture was poured into ice water and a cream colored semicrystalline precipitate formed. The precipitate was collected by filtration, washed with water, and air dried. The solid was crystallized from hot heptanes to give 6.1 g (42%) of tribromophloroglucinol triacrylate as off-white needles.
 

Historical Records

Technical Information

Categories