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Chemical Structure| 3508-62-1 Chemical Structure| 3508-62-1

Structure of 3508-62-1

Chemical Structure| 3508-62-1

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Product Details of [ 3508-62-1 ]

CAS No. :3508-62-1
Formula : C24H19NSi
M.W : 349.50
SMILES Code : C12=CC=CC=C1[Si](C3=CC=CC=C3)(C4=CC=CC=C4)C5=C(C=CC=C5)N2
MDL No. :MFCD30534256

Safety of [ 3508-62-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330

Application In Synthesis of [ 3508-62-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3508-62-1 ]

[ 3508-62-1 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 5394-23-0 ]
  • [ 3508-62-1 ]
  • C60H42N4Si2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
83% Diphenyl-5,10-dihydrodibenzo [b, e] [1,4] oxazole, 240 mg of 70% oil-dispersed sodium hydride and20 ml of tetrahydrofuran was added to a 50 ml single-necked round-bottomed flask and refluxed under argon for 30 minutes. Then 0.75 g of 4,7-Dichloro-1,10 phenanthroline, and then refluxed at 60 C for 24 hours, cooled to room temperature, saturated brine quenched, dichloromethaneThe extract was dried over anhydrous sodium sulfate, dried over anhydrous sodium sulfate, filtered and dried. The product was 2.18 in a ratio of methanol: methylene chloride at a volume ratio of 1:30.G. White solid, yield 83%
  • 2
  • [ 5394-23-0 ]
  • [ 3508-62-1 ]
  • C60H42N4Si2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
79% Diphenyl-5,10-dihydrodibenzo [b, e] [1,4] oxazole, 240 mg of 70% oil-dispersed sodium hydride and20 ml of tetrahydrofuran was added to a 50 ml single-necked round bottom flask and refluxed under argon for 30 minutes. After adding 0.75 g of 3,8-Dichloro-1,10 phenanthroline, and then refluxed at 60 C for 24 hours, cooled to room temperature, saturated brine quenched, dichloromethaneThe extract was dried over anhydrous sodium sulfate, dried over anhydrous sodium sulfate, filtered and dried. The product was 2.07 in a ratio of methanol: methylene chloride 1:20 by volume.G. White solid, yield 79%
  • 3
  • [ 2050-48-8 ]
  • [ 3508-62-1 ]
  • 5,5'-(sulfonylbis(4,1-phenylene))bis(10,10-diphenyl-5,10-dihydrodibenzo[b,e][1,4]azasiline) [ No CAS ]
YieldReaction ConditionsOperation in experiment
46% With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate; In toluene; at 110℃; for 24h; Well-dried 100 mL three-necked round bottom flask charged with 4,4'-sulfonylbis (bromobenzene) (0.7 g, 1.86 mmol), 10,10-diphenyl-5,10-dihydrodibenzo [b, e] [1,4] azasiline (1.43 g, 4.1 mmol), Na-t-butoxide (0.36 g, 3.72mmol), tris (tertbutyl) phosphine (0.04 g, 0.19 mmol) and Pd2(dba)3 (0.09 g) were dissolved in 20 ml of toluene was stirred for 24 hours at 110C . After completion of the reaction was poured into water, and extracted three times with chloroform. The extracted organic layer was dried using MgSO4, the solvent was removed using a rotary evaporator, and separated by column chromatography using EA / n-Hexane (1/3) to obtain the compound 1.7 g (yield = 46%).
  • 4
  • [ 25032-74-0 ]
  • [ 3508-62-1 ]
  • bis(3-(10,10-diphenyldibenzo[b,e][1,4]azasilin-5(10H)yl)phenyl)methanone [ No CAS ]
YieldReaction ConditionsOperation in experiment
35% With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate; In toluene; at 110℃; for 24h; Well-dried 100 mL three-necked round bottom flask charged with bis (3-bromophenyl) methanone (1 g, 2.94 mmol), 10,10-diphenyl-5,10-dihydrodibenzo [b, e] [1,4] azasiline (2.26 g, 6.47 mmol), Na-t-butxide (0.57 g, 5.9mmol), tris (tertbutyl) phosphine (0.06 g, 0.29 mmol) And Pd2(dba)3 (0.13 g, 0.15 mmol) were dissolved in 15 ml of toluene and it was stirred for 24 hours at 110C . After completion of the reaction was poured into water, and extracted three times with chloroform. The extracted organic layer was dried using MgSO4, the solvent was removed using a rotary evaporator, and separated by column chromatography using EA / n-Hexane (1/3) to obtain the compound 2 g (yield = 35%).
 

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