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Chemical Structure| 3652-92-4 Chemical Structure| 3652-92-4

Structure of 3652-92-4

Chemical Structure| 3652-92-4

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Product Citations

Product Citations

Muniz, Collin N. ; Archer, Claire A. ; Applebaum, Jack S. ; Alagaratnam, Anushan ; Schaab, Jonas ; Djurovich, Peter I. , et al.

Abstract: Generating sustainable fuel from sunlight plays an important role in meeting the energy demands of the modern age. Herein, we report two-coordinate carbene-metal-amide (cMa, M = Cu(I) and Au(I)) complexes that can be used as sensitizers to promote the light-driven reduction of water to hydrogen. The cMa complexes studied here absorb visible photons (εvis > 103 M-1 cm-1), maintain long excited-state lifetimes (τ ~0.2-1 μs), and perform stable photoinduced charge transfer to a target substrate with high photoreducing potential (E+/* up to -2.33 V vs Fc+/0 based on a Rehm-Weller anal.). We pair these coinage metal complexes with a cobalt-glyoxime electrocatalyst to photocatalytically generate hydrogen and compare the performance of the copper- and gold-based cMa complexes. We also find that the two-coordinate complexes herein can perform photodriven hydrogen production from water without the addition of the cobalt-glyoxime electrocatalyst. In this "catalyst-free" system, the cMa sensitizer partially decomposes to give metal nanoparticles that catalyze water reduction This work identifies two-coordinate coinage metal complexes as promising abundant metal, solar fuel photosensitizers that offer exceptional tunability and photoredox properties.

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Product Details of [ 3652-92-4 ]

CAS No. :3652-92-4
Formula : C15H16N2
M.W : 224.30
SMILES Code : CN1C2=CC=CC=C2N(C)C1C3=CC=CC=C3
MDL No. :MFCD00186893
InChI Key :VDFIVJSRRJXMAU-UHFFFAOYSA-N
Pubchem ID :199049

Safety of [ 3652-92-4 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 3652-92-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3652-92-4 ]

[ 3652-92-4 ] Synthesis Path-Downstream   1~1

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