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Chemical Structure| 38694-47-2 Chemical Structure| 38694-47-2

Structure of 38694-47-2

Chemical Structure| 38694-47-2

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Product Details of [ 38694-47-2 ]

CAS No. :38694-47-2
Formula : C4H7BrO
M.W : 151.00
SMILES Code : O=CCCCBr
MDL No. :MFCD07780175

Safety of [ 38694-47-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H312-H315-H319-H332-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis of [ 38694-47-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 38694-47-2 ]
  • Downstream synthetic route of [ 38694-47-2 ]

[ 38694-47-2 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 38694-47-2 ]
  • [ 631-57-2 ]
  • [ 14631-43-7 ]
  • [ 1393708-93-4 ]
YieldReaction ConditionsOperation in experiment
34% With Candida antarctica lipase B; di-μ-oxo-di((S,S)-N,N'-bis((salicylaldehydo)ethylenediamine))dititanium(IV); water In toluene at 40℃; for 15 h; aq. buffer; Enzymatic reaction General procedure: Aldehyde (0.24 mmol) and (S,S)-[(salen)Ti(μ-O)]2 (5 mol percent) were dissolved in toluene (1 mL), and buffer (1 mL) and CALB (20 mg) were added. AcCN (3 equiv diluted to 250 μL with toluene) was added to the organic phase with a constant rate over 24-25 h using a syringe pump. The reaction was monitored by chiral GC using undecane (10 μL, 0.0473 mmol) as internal standard.
References: [1] Tetrahedron, 2012, vol. 68, # 37, p. 7680 - 7684.
 

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