Home Cart Sign in  
Chemical Structure| 41128-92-1 Chemical Structure| 41128-92-1

Structure of 41128-92-1

Chemical Structure| 41128-92-1

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 41128-92-1 ]

CAS No. :41128-92-1
Formula : C11H14O3
M.W : 194.23
SMILES Code : C1(OCC2=CC=CC=C2)COCOC1

Safety of [ 41128-92-1 ]

Application In Synthesis of [ 41128-92-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 41128-92-1 ]

[ 41128-92-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 41128-92-1 ]
  • [ 4740-78-7 ]
YieldReaction ConditionsOperation in experiment
100% With hydrogen;Pd/C; In ethyl acetate; at 20℃; for 12.0h; Example 171,3-Dioxan-5-ol (8h). To a mixture of 17 (100 mg, 0.55 mmol) and paraformaldehyde (17 mg, 0.55 mmol) in EtOAc (10 mL), boron trifluoride etherate (70 muL, 0.55 mmol) was added and the reaction mixture was stirred at 23 C. for 4 h. The organic phase was washed with a saturated solution of NaHCO3, dried and the solvent was removed. The residue was purified by flash-chromatography eluting with a 1:4 mixture of EtOAc and hexanes to afford 84 mg (78%) of O-benzyl-1,3-dioxan-5-ol as a colourless oil. The above compound was dissolved in EtOAc (3 mL), Pd/C was added and the resulting suspension was stirred at rt under a hydrogen atmosphere. After 12 h, the catalyst was filtered off, the filtrate was evaporated in vacuo and the residue (39 mg, 100%) was used in the next step without further purification: 1H NMR (CDCl3) delta 4.93 (d, J=6.3 Hz, 1H), 4.76 (d, J=6.3 Hz, 1H), 3.94-3.84 (m, 4H), 3.64-3.61 (m, 1H), 2.78 (bs, 1H). 13C NMR (CDCl3) delta 94.0, 71.7, 64.1.
 

Historical Records