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Chemical Structure| 42856-43-9 Chemical Structure| 42856-43-9

Structure of 42856-43-9

Chemical Structure| 42856-43-9

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Product Details of [ 42856-43-9 ]

CAS No. :42856-43-9
Formula : C12H13NO2
M.W : 203.24
SMILES Code : O=C(CCC1)N(CC2=CC=CC=C2)C1=O
MDL No. :MFCD00523377

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Application In Synthesis of [ 42856-43-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 42856-43-9 ]

[ 42856-43-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 42856-43-9 ]
  • [ 2905-56-8 ]
YieldReaction ConditionsOperation in experiment
90% With 1,1,3,3-Tetramethyldisiloxane; tris(pentafluorophenyl)borate; In 1,4-dioxane; at 110℃; for 16h;Inert atmosphere; Schlenk technique; General procedure: To the mixture of B(C6F5)3 (5.0mol%) and cyclic imides (1.0mmol) in dioxane, was added PhSiH3 (3.0mmol) slowly under an atmosphere of nitrogen. The reaction mixture was stirred and refluxed at 110C under an atmosphere of nitrogen. After the imide was consumed completely (detected by TLC) the mixture was added with aqueous ammonia (15mL) and extracted with CH2Cl2 (10mL×3). The combined organic phase was dried over Na2SO4, after removing the solvent under vacuum, the residue was purified by column chromatography to give the product.
 

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