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Chemical Structure| 4669-06-1

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Product Details of [ 4669-06-1 ]

CAS No. :4669-06-1
Formula : C20H15N
M.W : 269.34
SMILES Code : C1(NC2=CC=C3C=CC=CC3=C2)=C4C=CC=CC4=CC=C1
MDL No. :MFCD01632468
InChI Key :UNJZLNFHHINVOB-UHFFFAOYSA-N
Pubchem ID :257254

Safety of [ 4669-06-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H319
Precautionary Statements:P305+P351+P338

Application In Synthesis of [ 4669-06-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 4669-06-1 ]

[ 4669-06-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 4669-06-1 ]
  • [ 171408-84-7 ]
  • N2,N7-di(naphthalen-1-yl)-N2,N7-di(naphthalen-2-yl)-9,9'-spirobi[fluorene]-2,7-diamine [ No CAS ]
YieldReaction ConditionsOperation in experiment
74% With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In tetrahydrofuran; toluene; at 105℃; for 24h;Inert atmosphere; A mixture of 2,7-dibromo-9,9'-spirobifluorene (1, 1 g, 1 equiv.) , N-(naphthalene-2-yl)naphthalene-1-amine (A, 1.6 g, 2.5 equiv.), Pd(OAc)2 (0.1 g, 0.2 equiv.), t-Bu3P (50percent in toluene, 0.5 mL, 0.3 equiv.),NaOt-Bu in THF (2 M, 3.0 mL) and anhydrous toluene (100 mL) were mixed and then stirred underinert conditions at 105°C for 24 h. After completion of the reaction, the reaction mixture was extractedwith dichloromethane and water. The organic layer was dried over anhydrous magnesium sulphatethen filtered and concentrated by rotary evaporation. The crude residue was purified by silica gelcolumn chromatography by using a n-hexanedichloromethane solvent system to provide the desiredproduct HTM 1A. Yield: 74percent; yellow solid; 1H-NMR (CDCl3) delta 7.81?7.83 (d, J = 10 Hz, 2H), 7.75?7.77(d, J = 10 Hz, 2H), 7.69?7.71 (d, J = 10 Hz, 2H), 7.59?7.61 (d, J = 10 Hz, 2H), 7.55?7.57 (d, J = 10 Hz, 2H),7.44?7.49 (m, 4H), 7.37?7.39 (t, J = 9 Hz, 4H), 7.14?7.37 (m, 16H), 6.99?7.01 (t, J = 10 Hz, 2H), 6.89?6.91(d, J = 10 Hz, 2H), 6.79?6.81 (d, J = 10 Hz, 2H), 6.63 (s, 2H); 13C-NMR (CDCl3) delta 108.1, 109.4, 121.4,124.6, 125.0, 125.3, 127.5, 128.4, 133.7, 135.8, 140.1, 142.0, 142.4; GC-MS: 851.04 for C65H42N2 [M + H+].
 

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