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CAS No. : | 51054-99-0 | MDL No. : | MFCD17011773 |
Formula : | C9H10BrNO2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | HYSNMDQIDZNCAC-UHFFFAOYSA-N |
M.W : | 244.09 | Pubchem ID : | 15326674 |
Synonyms : |
|
Signal Word: | Danger | Class: | 3 |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | 1993 |
Hazard Statements: | H226-H302-H315-H319-H335 | Packing Group: | Ⅲ |
GHS Pictogram: |
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* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
50% | With potassium phosphate; tetrakis(triphenylphosphine) palladium(0); In N,N-dimethyl-formamide; at 150℃; for 1.5h;Microwave irradiation; | General procedure: To a solution of aryl halide 4a (48 mg, 0.35 mmol) in 2 mL dimethylformamide were added boronic ester 5 (106 mg, 0.385 mmol), Pd(PPh3)4 (20 mg, 5 mol %), and K3PO4 (242 mg, 1.11 mmol). The mixture was irradiated at 150 C for 90 min using a microwave reactor. The reaction mixture was then diluted with EtOAc, filtrated on a small pad of Celite, and concentrated under vacuum. The crude mixture was then purified by column chromatography (DCM/CyHex 7/3) to afford 63 mg of the corresponding phenanthrene 7a (72% yield). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
83% | With potassium phosphate; tetrakis(triphenylphosphine) palladium(0); In N,N-dimethyl-formamide; at 150℃; for 1.5h;Microwave irradiation; | General procedure: To a solution of aryl halide 4a (48 mg, 0.35 mmol) in 2 mL dimethylformamide were added boronic ester 5 (106 mg, 0.385 mmol), Pd(PPh3)4 (20 mg, 5 mol %), and K3PO4 (242 mg, 1.11 mmol). The mixture was irradiated at 150 C for 90 min using a microwave reactor. The reaction mixture was then diluted with EtOAc, filtrated on a small pad of Celite, and concentrated under vacuum. The crude mixture was then purified by column chromatography (DCM/CyHex 7/3) to afford 63 mg of the corresponding phenanthrene 7a (72% yield). |
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